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This study investigated dual-fuel operation with a light duty Diesel engine over a wide engine load range. Ethanol was hereby injected into the intake duct, while Diesel was injected directly into the cylinder. At low loads, high ethanol shares are critical in terms of combustion stability and emissions of unburnt hydrocarbons. As the load increases, the rates of heat release become problematic with regard to noise and mechanical stress. At higher loads, an advanced injection of Diesel was found to be beneficial in terms of combustion noise and emissions. For all tests, engine-out NOx emissions were kept within the EU-6.1 limit.

Due to increasing environmental awareness, standards for pollutant and CO2 emissions are getting stricter in most markets around the world. In important markets such as Europe, also the emissions during real road driving, so called “Real Driving Emissions” (RDE), are now part of the type approval process for passenger cars. In addition to the proceeding hybridization and electrification of vehicles, the complexity and degrees of freedom of conventional powertrains with internal combustion engines (ICE) are also continuing to increase in order to comply with stricter exhaust emission standards. Besides the different requirements placed on vehicle emissions, the drivability capabilities of passenger vehicles desired by customers, are essentially important and vary between markets.

In this study the fuel influence of several bio-fuel candidates on homogeneous engine combustion systems with direct injection is investigated. The results reveal Ethanol and 2-Butanol as the two most knock-resistant fuels. Hence these two fuels enable the highest efficiency improvements versus RON95 fuel ranging from 3.6% - 12.7% for Ethanol as a result of a compression ratio increase of 5 units. Tetrahydro-2-methylfuran has a worse knock resistance and a decreased thermal efficiency due to the required reduction in compression ratio by 1.5 units. The enleanment capability is similar among all fuels thus they pose no improvements for homogeneous lean burn combustion systems despite a significant reduction in NOX emissions for the alcohol fuels as a consequence of lower combustion temperatures.

For gasoline engines controlled autoignition provides the vision of enabling the fuel consumption benefit of stratified lean combustion systems without the drawback of additional NOx aftertreatment. In this study the potential of certain biofuels on this combustion system was assessed by single-cylinder engine investigations using the exhaust strategy "combustion chamber recirculation" (CCR). For the engine testing sweeps in the internal EGR rate with different injection strategies as well as load sweeps were performed. Of particular interest was to reveal fuel differences in the achievable maximal load as well as in the NOx emission behavior. Additionally, experiments with a shock tube and a rapid compression machine were conducted in order to determine the ignition delay times of the tested biofuels concerning controlled autoignition-relevant conditions.

Gasoline particulate filters (GPF) recently entered the market, and are already regarded a state-of-the-art solution for gasoline exhaust aftertreatment systems to enable EU6d-TEMP fulfilment and beyond. Especially for coated GPF applications, the prognosis of the emission conversion performance over lifetime poses an ambitious challenge, which significantly influences future catalyst diagnosis calibrations. The paper presents key-findings for the different GPF application variants. In the first part, experimental GPF ash loading results are presented. Ash accumulates as thin wall layers and short plugs, but does not penetrate into the wall. However, it suppresses deep bed filtration of soot, initially decreasing the soot-loaded backpressure. For the emission calibration, the non-linear backpressure development complicates the soot load monitoring, eventually leading to compromises between high safety against soot overloading and a low number of active regenerations.

In the recent years diesel engine developers and manufacturers achieved a great progress in reducing the most important diesel engine pollutants, NOX and particulates. But nevertheless big efforts in diesel engine development are necessary to meet with the more stringent future emission regulations. To improve the knowledge about particle formation and emission an insight in the cylinder is necessary. By using the fast gas sampling technique samples from the cylinder were taken as a function of crank angle and analyzed regarding the soot particle size distribution and the particle mass. The particle size distribution was measured by a conventional SMPS. Under steady state conditions the influence of aromatic and oxygen content in the fuel on in-cylinder particle size distribution and particle mass inside a modern 4V-CR-DI-diesel-engine were determined. After injection and ignition, mainly small soot particles were formed which grow and in the later combustion phase coagulate.

Within the Cluster of Excellence “Tailor-Made Fuels from Biomass” (TMFB) at the RWTH Aachen University, two novel biogenic fuels, namely 1-octanol and its isomer dibutyl ether (DBE), were identified and extensively analyzed in respect of their suitability for combustion in a Diesel engine. Both biofuels feature very different properties, especially regarding their ignitability. In previous works of the research cluster, promising synthesis routes with excellent yields for both fuels were found, using lignocellulosic biomass as source material. Both fuels were investigated as pure components in optical and thermodynamic single cylinder engines (SCE). For 1-octanol at lower part load, almost no soot emission could be measured, while with DBE the soot emissions were only about a quarter of that with conventional Diesel fuel. At high part load (2400 min-1, 14.8 bar IMEP), the soot reduction of 1-octanol was more than 50% and for DBE more than 80 % respectively.

The influence of oil related emissions became more important in the past due to reduced engine-out emissions of combustion engines. Additionally the efficiency of exhaust gas after treatment components is influenced by oil derived components. A balancing of relevant engine oil components (Ca, Mg, Zn, P, S, Mo, B, Fe, Al, Cu) is presented in this paper. The oil components deposited in the combustion chamber, in the exhaust system as well as in the aftertreatment devices were determined and quantified. Therefore a completely cleaned DI Diesel engine with oxidation catalyst, Diesel particulate filter (DPF) and NOx adsorber catalyst (LNT) was operated in different operating conditions for 500 h in a development test cell. The operation included lean/rich cycling for NOx trap regeneration. After finishing the 500 h test procedure the engine was completely disassembled and all deposits were analyzed.

Within this paper, the two possible alternative and biomass-based fuel candidates Di-n-butyl ether (DNBE) and 1-octanol are investigated with regard to their utilization in a diesel-type engine. In order to asses the fuels emission-reduction potential, both have been tested in a single cylinder engine (SCE) and a high pressure chamber (HPC) in comparison to conventional EN590 diesel at various load points. Due to its reduced reactivity 1-octanol features a longer ignition delay and thus higher degrees of homogenization at start of combustion, whereas DNBE ignites rather rapidly in both the HPC and the engine leading to a predominantly mixing controlled combustion. Thus, both fuels feature completely different combustion characteristics. However, compared to diesel, both fuels contribute to a significant reduction in Filter Smoke Number (FSN) up to a factor of 15.

This paper describes an alternative catalyst aging process using a hot gas test stand for thermal aging. The solution presented is characterized by a burner technology that is combined with a combustion enhancement, which allows stoichiometric and rich operating conditions to simulate engine exhaust gases. The resulting efficiency was increased and the operation limits were broadened, compared to combustion engines that are typically used for catalyst aging. The primary modification that enabled this achievement was the recirculation of exhaust gas downstream from catalyst back to the burner. The burner allows the running simplified dynamic durability cycles, which are the standard bench cycle that is defined by the legislation as alternative aging procedure and the fuel shut-off simulation cycle ZDAKW. The hot gas test stand approach has been compared to the conventional engine test bench method.

Dielectric barrier discharge (DBD) offers the advantage to excite and dissociate molecules in the exhaust gas stream. Those dissociated and excited species are oxidizing or reducing harmful exhaust gas components. The advantage of a plasma chemical system in comparison to a catalytic measure for exhaust gas treatment is the instantaneous activity at ambient temperature from the starting of the engine. The investigations reviewed in this paper are dealing with the plasma chemical oxidation of hydrocarbons in the exhaust gas stream during cold start conditions. The article concerns the design and development of a plasma-system in order to decrease the hydrocarbon emissions from engine start till catalyst light off. Vehicle results in the New European Driving Cycle show a hydrocarbon conversion of more than 42% in the first 11 seconds from engine start. In this period nearly all types of hydrocarbon were reduced.

The HSDI Diesel engine contributes substantially to the decrease of fleet fuel consumption thus to the reduction of CO2 emissions. This results in the rising market acceptance which is supported by desirable driving performance as well as greatly improved NVH behavior. In addition to the above mentioned requirements on driving performance, fuel economy and NVH behavior, continuously increasing demands on emissions performance have to be met. From today's view the Diesel particulate trap presents a safe technology to achieve the required reduction of the particle emission of more than 95%. However, according to today's knowledge a further, substantial NOx engine-out emission reduction for the Diesel engine is counteracts with the other goal of reduced fuel consumption. To comply with current and future emission standards, Diesel engines will require DeNOx technologies.

The increasingly stringent limits on pollutant emissions from internal combustion engine-powered vehicles require the optimization of advanced combustion systems by means of virtual development and simulation tools. Among the gaseous emissions from spark-ignition engines, the unburned hydrocarbon (HC) emissions are the most challenging species to simulate because of the complexity of the multiple physical and chemical mechanisms that contribute to their emission. These mechanisms are mainly three-dimensional (3D) resulting from multi-phase physics - e.g., fuel injection, oil-film layer, etc. - and are difficult to predict even in complex 3D computational fluid-dynamic (CFD) simulations. Phenomenological models describing the relationships between the physical-chemical phenomena are of great interest for the modeling and simplification of such complex mechanisms.

Current and future emission legislations require a significant reduction of engine-out emissions for Diesel engines. For a further reduction of engine-out emissions, different measures are necessary such as: Especially an advanced emission and closed-loop combustion control has gained increased significance during the past years.

In order to reduce engine out CO2 emissions it is a main subject to find new alternative fuels out of renewable sources. For this paper, several fuels were selected which can be produced out of biomass or with hydrogen which is generated directly via electrolysis with electricity from renewable sources. All fuels are compared to conventional diesel fuel and two diesel surrogates. It is well known that there can be a large effect of fuel properties on mixture formation and combustion, which may result in a completely different engine performance compared to the operation with conventional diesel fuels. Mixture formation and ignition behavior can also largely affect the pollutant formation. The knowledge of the combustion behavior is also important to design new engine geometries or implement new calibrations for an existing engine. The fuel properties of the investigated fuels comprise a large range, for example in case of the derived cetane number, from below 30 up to 100.

An improved plasma reactor has been designed, built and evaluated. It is characterized by a reduced power per area ratio, relative to previous designs, and includes several improvements to run the whole system safely in a car. The new reactor design includes a concentric inner high voltage electrode, a grounded outer electrode, a shielded high-voltage and high temperature resistant electrical connection. A generator controller has been developed for better control of operating conditions as required during the engine cold start phase. The new generator/reactor system was installed in the exhaust pipe of a gasoline direct injection engine. HC emissions could be reduced up to 30 % in the first 40 seconds of a cold start test. In addition to HC treatment the dielectric barrier discharge has also been investigated as a method for regenerating a diesel particulate trap.

Cyclic fluctuations of the in-cylinder processes in a Direct Injection Spark Ignition (DISI) engine may strongly affect the engine operation causing misfires or variations in the indicated mean effective pressure (imep). Particularly misfires prevent compliance with current or future exhaust emission legislations. Nevertheless, the origin of cyclic fluctuations is not well understood since fluctuations of in-cylinder air flow, fuel injection and wall interaction have to be considered. This paper focusses on a detailed experimental analysis of the origin of cyclic fluctuations in a DISI engine with an air guided combustion process by means of advanced Laser Induced Exciplex Fluorescence (LIEF) measurements. It reveals that cycle-to-cycle variations primarily originate from the air/fuel ratio at the spark plug.

With Post Euro 6 emission standards in discussion, stricter particulate number (PN) targets as well as a decreased PN cut-off size from 23 to 10 nm are expected. Sub-23 nm particulates are considered particularly harmful to human health, but are not yet taken into account in the current vehicle certification process. Not considering sub-23 nm particulates during the development process could lead to significant additional efforts for Original Equipment Manufacturers (OEM) to comply with future Post Euro 6 PN emission limits. It is therefore essential to increase knowledge about the formation and filtration of particulates below 23 nm. In the present study, a holistic Gasoline Particulate Filter (GPF) characterization has been carried out on an engine test bench under varying boundary conditions and on a burner bench with a novel ash loading methodology.

The requirement of reducing worldwide CO₂ emissions and engine pollutants are demanding an increased use of bio-fuels. Ethanol with its established production technology can contribute to this goal. However, due to its resistive auto-ignition behavior the use of ethanol-based fuels is limited to the spark-ignited gasoline combustion process. For application to the compression-ignited diesel combustion process advanced ignition systems are required. In general, ethanol offers a significant potential to improve the soot emission behavior of the diesel engine due to its oxygen content and its enhanced evaporation behavior. In this contribution the ignition behavior of ethanol and mixtures with high ethanol content is investigated in combination with advanced ignition systems with ceramic glow-plugs under diesel engine relevant thermodynamic conditions in a high pressure and temperature vessel.

To comply with the new regulations on particulate matter emissions, the manufacturers of light-duty as well as heavy-duty vehicles more commonly use diesel particulate filters (DPF). The regeneration of DPF depends to a significant extent on the properties of the soot stored. Within the Cluster of Excellence "Tailor-Made Fuels from Biomass (TMFB)" at RWTH Aachen University, the Institute for Combustion Engines carried out a detailed investigation program to explore the potential of future biofuel candidates for optimized combustion systems. The experiments for particulate measurements and analysis were conducted on a EURO 6-compliant High Efficiency Diesel Combustion System (HECS) with petroleum-based diesel fuel as reference and a today's commercial biofuel (i.e., FAME) as well as a potential future biomass-derived fuel candidate (i.e., 2-MTHF/DBE). Thermo gravimetric analyzer (TGA) was used in this study to evaluate the oxidative reactivity of the soot.