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This paper will discuss the fundamentals of the Bosch rate of injection meter which has been the standard measurement tool for the last 25 years and a newly developed tool which uses the Zuech constant volume technique. A fundamental and experimental comparison is presented. Using a high pressure accumulator type injector, each of the injection systems produced almost identical injection rate shapes. The integrated values of these traces (injection quantity) were within a few percent of the physically measured quantities.

It has previously been shown experimentally and computationally that the process of Homogeneous Charge Compression Ignition (HCCI) is very dependent on the pre-combustion gas temperature field. This study looks in detail at how temperature fields can evolve by comparing results of two combustion chamber designs, a piston with a square bowl and a disk shaped piston, and relates these temperature fields to measured HCCI combustion durations. The contributions of combustion chamber surface area and turbulence levels to the gas temperature evolution are considered over the crank angle range from intake valve closure to top-dead-center. This is a CFD study, whose results were transformed into traditional analysis methods of convective heat transfer (q=h*A*ΔT) and boundary layers.

This computational study compares predictions and experimental results for the use of direct injected iso-octane fuel during the negative valve overlap (NVO) period to achieve HCCI combustion. The total fuel injection was altered in two ways. First the pre-DI percent, (the ratio of direct injected fuel during the NVO period “pre-DI” to the secondary fuel supplied at the intake manifold “PI”), was varied at a fixed pre-DI injection timing, Secondly the timing of the pre-DI injection was varied while all of the fuel was supplied during the NVO period. A multi-zone, two-dimensional CFD simulation with chemistry was performed using KIVA-3V release 2 implemented with the CHEMKIN solver. The simulations were performed during the NVO period only.

Multi-dimensional computational efforts using comprehensive and skeletal kinetics have been made to investigate the cool flame region in HCCI combustion. The work was done in parallel to an experimental study that showed the impact of the negative temperature coefficient and the cool flame on the start of combustion using different fuels, which is now the focus of the simulation work. Experiments in a single cylinder CFR research engine with n-butane and a primary reference fuel with an octane number of 70 (PRF 70) were modeled. A comparison of the pressure and heat release traces of the experimental and computational results shows the difficulties in predicting the heat release in the cool flame region. The behavior of the driving radicals for two-stage ignition is studied and is compared to the behavior for a single-ignition from the literature. Model results show that PRF 70 exhibits more pronounced cool flame heat release than n-butane.

We have developed a methodology for predicting combustion and emissions in a Homogeneous Charge Compression Ignition (HCCI) Engine. The methodology judiciously uses a fluid mechanics code followed by a chemical kinetics code to achieve great reduction in the computational requirements; to a level that can be handled with current computers. In previous papers, our sequential, multi-zone methodology has been applied to HCCI combustion of short-chain hydrocarbons (natural gas and propane). Applying the same procedure to long-chain hydrocarbons (iso-octane) results in unacceptably long computational time. In this paper, we show how the computational time can be made acceptable by developing a segregated solver. This reduces the run time of a ten-zone problem by an order of magnitude and thus makes it much more practical to make combustion studies of long-chain hydrocarbons.

We have developed a model of the diesel fuel injection process for application to analysis of low temperature non-sooting combustion. The model uses a simplified mixing correlation and detailed chemical kinetics to analyze a parcel of fuel as it moves along the fuel jet, from injection to evaporation and ignition. The model predicts chemical composition and soot precursors, and is applied at conditions that result in low temperature non-sooting combustion. Production of soot precursors is the first step toward production of soot, and modeling precursor production is expected to give insight into the overall evolution of soot inside the engine. The results of the analysis show that the model has been successful in describing many of the observed characteristics of low temperature combustion.

A detailed comparison of cylinder pressure derived combustion performance and engine-out emissions is made between an all-metal single-cylinder light-duty diesel engine and a geometrically equivalent engine designed for optical accessibility. The metal and optically accessible single-cylinder engines have the same nominal geometry, including cylinder head, piston bowl shape and valve cutouts, bore, stroke, valve lift profiles, and fuel injection system. The bulk gas thermodynamic state near TDC and load of the two engines are closely matched by adjusting the optical engine intake mass flow and composition, intake temperature, and fueling rate for a highly dilute, low temperature combustion (LTC) operating condition with an intake O2 concentration of 9%. Subsequent start of injection (SOI) sweeps compare the emissions trends of UHC, CO, NOx, and soot, as well as ignition delay and fuel consumption.

Homogeneous Charge Compression Ignition (HCCI) combustion is a process dominated by chemical kinetics of the fuel-air mixture. The hottest part of the mixture ignites first, and compresses the rest of the charge, which then ignites after a short time lag. Crevices and boundary layers generally remain too cold to react, and result in substantial hydrocarbon and carbon monoxide emissions. Turbulence has little effect on HCCI combustion, and may be most important as a factor in determining temperature gradients and boundary layer thickness inside the cylinder. The importance of thermal gradients inside the cylinder makes it necessary to use an integrated fluid mechanics-chemical kinetics code for accurate predictions of HCCI combustion. However, the use of a fluid mechanics code with detailed chemical kinetics is too computationally intensive for today's computers.

A procedure has been developed to build system level predictive models that incorporate physical laws as well as information derived from experimental data. In particular a soot model was developed, trained and tested using experimental data. It was seen that the model could fit available experimental data given sufficient training time. Future accuracy on data points not encountered during training was estimated and seen to be good. The approach relies on the physical phenomena predicted by an existing system level phenomenological soot model coupled with ‘weights’ which use experimental data to adjust the predicted physical sub-model parameters to fit the data. This approach has developed from attempts at incorporating physical phenomena into neural networks for predicting emissions. Model training uses neural network training concepts.

An engine cycle simulation code with detailed chemical kinetics has been developed to study Homogeneous Charge Compression Ignition (HCCI) combustion with hydrogen as the fuel. In order to attain adequate combustion duration, resulting from the self-accelerating nature of the chemical reaction, fuel and temperature inhomogeneities have been brought to the calculation by considering the combustion chamber to have various temperature and fuel distributions. Calculations have been done under various conditions including both perfectly homogeneous and inhomogeneous cases, changing the degree of inhomogeneity. The results show that intake gas temperature is more dominant on ignition timing of HCCI than equivalence ratio and that there is a possibility to control HCCI by introducing appropriate temperature inhomogeneity to in-cylinder mixture.

We have developed a methodology for predicting combustion and emissions in a Homogeneous Charge Compression Ignition (HCCI) Engine. This methodology combines a detailed fluid mechanics code with a detailed chemical kinetics code. Instead of directly linking the two codes, which would require an extremely long computational time, the methodology consists of first running the fluid mechanics code to obtain temperature profiles as a function of time. These temperature profiles are then used as input to a multi-zone chemical kinetics code. The advantage of this procedure is that a small number of zones (10) is enough to obtain accurate results. This procedure achieves the benefits of linking the fluid mechanics and the chemical kinetics codes with a great reduction in the computational effort, to a level that can be handled with current computers.

The diesel/natural gas engine configuration provides a potential alternative solution for PM and NOx emissions reduction from typical diesel engine operations. However, their engine operations suffer from high NMHC/methane emissions and poor engine performance, especially at light loads. By increasing the diesel pilot quantity, the performance and reduction of NMHC/methane emissions can be improved but the emission levels are still very high. Clearly, a typical DOC is not good enough to treat NMHC/methane emissions. Methane has been known as one of most stable species that is difficult to catalytically oxidize in lean burn environment and low exhaust temperatures. An aftertreatment system exclusively designed for treating methane emissions from DDF operations is therefore necessary. The current work is aimed to establish an effective computational tool in order to study the newly proposed catalytic converter system concept on treating methane from DDF operations.

Engine operation with blended SRC-II and pyridine doped diesel fuel were compared relative to regular #2 diesel fuel in a 4-stroke, turbocharged, direct injection, high speed commercial diesel engine. The brake specific fuel consumption, (M-Joule/hp-hr), turbocharging, combustion characteristics and smoke did not change between blended SRC-II and regular #2 diesel fuel. This was expected since the sample fuels were blended to be of the same cetane number. The maximum torque, hydrocarbon and NOx emissions were higher for blended SRC-II. There was essentially no difference in the NOx measurements of the pyridine doped fuel and regular #2 diesel fuel. The NOx emission increase for the blended SRC-II is believed to be caused by the increased aromatic content of the blended SRC-II and not the fuel nitrogen conversion.

A Texaco L-163S TCCS (Texaco Controlled Combustion System) engine was operated with pure methanol to investigate the origin and mechanism of unburned fuel (UBF) and formaldehyde emissions. The effects of engine load, speed and coolant temperature on the exhaust emissions were studied using both continuous and time-resolved sampling methods. Within the range studied, increasing the engine load resulted in a decrease of the exhaust UBF emissions and an increase in the formaldehyde emissions. Engine speed had little effect on both UBF and formaldehyde emissions. Decreasing the engine coolant temperature from 85°C to 45°C caused the exhaust UBF emissions to approximately double and the formaldehyde emission to increase approximately 20 percent. It is hypothesized that both fuel impingement and spray tailing are responsible for the high UBF emissions. In-cylinder formation of formaldehyde was found to be the major source of the exhaust aldehyde emissions in this experiment.

In this paper we report the results of experiments done during the transient operation of a single cylinder Cummins NH engine. The data taken include cycle resolved pressure, combustion chamber surface temperatures and ignition delay. The data was taken during a special type of engine operation in which the engine was repeatedly hopped from one load to another. In this way cycle to cycle variations could be averaged out by ensemble averaging individual cycles after the step load change. For analysis of the heat transfer a unique finite difference temperature probe was developed to delineate the 3-D heat transfer effects in place of the standard 1-D assumptions and a new analysis technique was developed to calculate the instantaneous heat flux during the transient. Analysis of the data indicates that the combustion reaches an equivalent steady state condition within 2000 engine cycles after the load change.

The diesel dual fuel engine emits CH4 in the exhaust gas. This makes the exhaust gas more difficult to treat comparing to the exhaust gas from the conventional engine since CH4 requires high exhaust temperature to oxidize. In addition, another parameter such as exhaust flow rate, specie concentrations, especially CO, C3H8, and H2O have tremendous impact on Diesel Oxidation Catalyst performance on reducing CH4. This research is aimed to propose a kinetic model based on Langmuir Hinshelwood mechanisms that includes several terms such as CH4, C3H8, CO, O2, and H2O concentrations in order to gain a better understanding on the catalytic reaction and to provide a simulation with an accurate prediction. The model’s kinetic parameters are determined from the experiment by using synthetic gas. The composition of synthetic gas is simulated to be similar to the real exhaust gas from diesel dual fuel engines.

A single cylinder CFR research engine has been run in HCCI combustion mode for a range of temperatures and fuel compositions. The data indicate that the best HCCI operation, as measured by a combination of successful combustion with low ISFC, occurs at or near the rich limit of operation. Analysis of the pressure and heat release histories indicated the presence, or absence, and impact of the fuel's NTC ignition behavior on establishing successful HCCI operation. The auto-ignition trends observed were in complete agreement with previous results found in the literature. Furthermore, analysis of the importance of the fuel's octane sensitivity, through assessment of an octane index, successfully explained the changes in the fuels auto-ignition tendency with changes in engine operating conditions.

This research work has focused on measuring the effect of fuel/air mixing on performance and emissions for a homogeneous charge compression ignition engine running on propane. A laser instrument with a high-velocity extractive probe was used to obtain time-resolved measurements of the fuel concentration both at the intake manifold and from the cylinder for different levels of fuel-air mixing. Cylinder pressure and emissions measurements have been performed at these mixing levels. From the cylinder pressure measurements, the IMEP and peak cylinder pressure were found. The fuel-air mixing level was changed by adding the fuel into the intake system at different distances from the intake valve (40 cm and 120 cm away). It was found that at the intake manifold, the fuel and air were better mixed for the 120 cm fuel addition location than for the 40 cm location.

The heat release type models have been classified as zero-dimensional because they have no spatial resolution and therefore don't contain any information on the fluid mechanics in them. They have been a significant contribution because they incorporate the rate processes occurring in the engine and are an aid in the analysis of the data. Because they are thermodynamic models it is necessary to define the control volumes on which the thermodynamic analysis is to be performed. The different control volume descriptions, called one, two and three zone models, and the analysis of the combustion event using these models is discussed. Finally a description of second law zero-dimensional models is given. These models have similar limitations as the First Law models; no spatial resolution and a control volume definition is required. These models are useful because they enable one to analyze the magnitude of the losses that occur in the different processes which comprise the engine cycle.

Deviations between transient and steady state operation of a modern light duty diesel engine were identified by comparing rapid load transitions to steady state tests at the same speeds and fueling rates. The validity of approximating transient performance by matching the transient charge air flow rate and intake manifold pressure at steady state was also assessed. Results indicate that for low load operation with low temperature combustion strategies, transient deviations of MAF and MAP from steady state values are small in magnitude or short in duration and have relatively little effect on transient engine performance. A new approximation accounting for variations in intake temperature and excess oxygen content of the EGR was more effective at capturing transient emissions trends, but significant differences in magnitudes remained in certain cases indicating that additional sources of variation between transient and steady state performance remain unaccounted for.