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The diesel dual fuel engine emits CH4 in the exhaust gas. This makes the exhaust gas more difficult to treat comparing to the exhaust gas from the conventional engine since CH4 requires high exhaust temperature to oxidize. In addition, another parameter such as exhaust flow rate, specie concentrations, especially CO, C3H8, and H2O have tremendous impact on Diesel Oxidation Catalyst performance on reducing CH4. This research is aimed to propose a kinetic model based on Langmuir Hinshelwood mechanisms that includes several terms such as CH4, C3H8, CO, O2, and H2O concentrations in order to gain a better understanding on the catalytic reaction and to provide a simulation with an accurate prediction. The model’s kinetic parameters are determined from the experiment by using synthetic gas. The composition of synthetic gas is simulated to be similar to the real exhaust gas from diesel dual fuel engines.

Towards the effort of using natural gas as an alternative fuel for a diesel engine, the concept of Diesel Dual Fuel (DDF) engine has been shown as a strong candidate. Typically, DDF's engine-out emission species such as soot and nitrogen oxides are decreased while carbon monoxide and hydrocarbons are increased. The aftertreatment system is required in order to reduce these pollutant emissions from DDF engines. Additionally, DDF engine exhaust has a wide temperature span and is rich in oxygen, which makes HC emissions, especially methane (CH₄), difficult to treat. Until now, it is widely accepted that the key parameter influencing methane oxidation in a catalytic converter is high exhaust temperature. However, a comprehensive understanding of what variables in real DDF engine exhausts most influencing a catalytic converter performance are yet to be explored.

Diesel Dual Fuel (DDF) operation is a promising alternative engine operating mode. Previous research studies have reported a DDF engine operating under low load conditions suffers from high HC emissions, mostly Methane. The current study investigated the use of a multiple direct injection strategy for improvement of low-load DDF operation in a commonrail direct injection single-cylinder diesel engine. Natural gas was supplied at 70% of energy replacement ratio. Results indicated that depending on engine conditions, a double-pulse injection had potential for combustion control and provided an effective way to reduce NOx and methane emissions. Moreover, the double-pulse injection helped improve the combustion stability, reduce the pressure rise rate, and decrease the maximum cylinder pressure, compared to DDF operation with a single pulse injection.