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Condensation of fuel vapor on the cold surfaces within the combustion chamber is investigated as a possible mechanism for increased HC emissions from SI engines during cold start. A one-dimensional, transient, mass diffusion analysis is used to examine the condensation of single-species fuels on the surfaces of the combustion chamber as the pressure within the cylinder rises during compression and combustion, and re-vaporization during expansion, blowdown, and exhaust. The effects of wall temperature, fuel volatility, and engine load and speed on this mechanism are also discussed. This analysis shows that low-volatility fuel components can condense on the surfaces of the combustion chamber when the surface temperatures are sufficiently low. This condensed fuel may re-vaporize during the power and exhaust strokes, or it may remain in the combustion chamber until surface temperatures rise, perhaps tens of seconds later.

A 1998 Toyota Corona passenger car with a direct injection spark ignition (DISI) engine was tested over the Federal Test Procedure (FTP) driving cycle. Speciated engine-out hydrocarbon emissions were measured. Seven fuels were used for these tests: five blended fuels and two pure hydrocarbon fuels. One of the blended fuels was CARB Phase 2 reformulated gasoline which was used as the reference fuel. The remaining four blended fuels were made from refinery components to meet specified distillation profiles. The pure hydrocarbon fuels were iso-octane and toluene - an alkane and an aromatic with essentially identical boiling points. The five blended fuels can be grouped to examine the effects of fuel volatility and MTBE. Additionally, correlations were sought between the fuel properties and the Specific Reactivity, the exhaust “toxics”, and the pass-through of unburned fuel species.

A 1998 Toyota Corona passenger car with a direct injection spark ignition (DISI) engine was tested via a variety of driving cycles using California Phase 2 reformulated gasoline. A comparable PFI vehicle was also evaluated. The standard driving cycles examined were the Federal Test Procedure (FTP), Highway Fuel Economy Test, US06, simulated SC03, Japanese 10-15, New York City Cycle, and European ECE+EDU. Engine-out and tailpipe emissions of gas phase species were measured each second. Hydrocarbon speciations were performed for each phase of the FTP for both the engine-out and tailpipe emissions. Tailpipe particulate mass emissions were also measured. The results are analyzed to identify the emissions challenges facing the DISI engine and the factors that contribute to the particulates, NOx, and hydrocarbon emissions problems of the DISI engine.

A recently developed in-cylinder fuel injection probe was used to deposit a small amount of liquid fuel on various surfaces within the combustion chamber of a 4-valve engine that was operating predominately on liquefied petroleum gas (LPG). A fast flame ionization detector (FFID) was used to examine the engine-out emissions of unburned and partially-burned hydrocarbons (HCs). Injector shut-off was used to examine the rate of liquid fuel evaporation. The purpose of these experiments was to provide insights into the HC formation mechanism due to in-cylinder wall wetting. The variables investigated were the effects of engine operating conditions, coolant temperature, in-cylinder wetting location, and the amount of liquid wall wetting. The results of the steady state tests show that in-cylinder wall wetting is an important source of HC emissions both at idle and at a part load, cruise-type condition. The effects of wetting location present the same trend for idle and part load conditions.

Combustion chamber pressure measurement in engines via a passage is an old technique that is still widely used in engine research. This paper presents improved passage designs for an off-set electrode spark plug designed to accept a pressure transducer. The spark plug studied was the Champion model 304-063A. Two acoustic models were developed to compute the resonance characteristics. The new designs have a resonance frequency in a range higher than the fundamental frequency expected from knock so that the signal can be lowpass filtered to remove the resonance and not interfere with pressure signal components associated with combustion phenomena. Engine experiments verified the spark plug resonance behavior. For the baseline engine operating condition approximately 50 of 100 cycles had visible passage resonance in the measured pressure traces, at an average frequency of 8.03 kHz.

The results of continuing investigations of a new type of ignitor, the railplug, are reported. Previous studies have shown that railplugs can produce a high velocity jet of plasma. Additionally, railplugs have the potential of assuring ignition under adverse conditions, such as cold start of an IDI diesel engine, because the railplug plasma can force ignition in the combustion chamber rather than relying on autoignition under cold start conditions. In this paper, engine data are presented to demonstrate the improved cold starting capability obtainable with railplugs. Data acquired using a railplug are compared to results obtained using no assist and using glow plugs. The engine used for this investigation will not start without glow plugs (or some starting aid) at temperatures below O°C, and the manufacturer's specification of the cold start limit for this engine using glow plugs is -24°C. Railplugs are able to initiate combustion at -29°C in one to two seconds with no preheating.

A new diffusing-oriented spray stratified combustion system for direct injection gasoline engines is proposed in this study. A reflector with multi-impingement wall head attached ahead of multi-hole injector nozzle is used in this system as a strategy of breaking up the fuel spray and directing it in a desired direction to form a perfect atomization and stratification of fuel air mixture. A comparatively rich fuel-air mixture is always formed over a wide range of engine operation conditions in the vicinity of spark plug due to the fuel spray oriented by the special surface shape of impingement wall, and the finely atomized fuel spray is formed in the other areas of combustion chamber due to the impacting of fuel spray against the impingement wall. Therefore, it is possible to achieve stable and fast burn of lean fuel air mixture. The combustion system is preliminary investigated on a single cylinder four-stroke DI gasoline engine which is shifted from a DI diesel engine.

The effect of combustion chamber wall-wetting on the emissions of unburned and partially-burned hydrocarbons (HCs) from gasoline-fueled SI engines was investigated experimentally. A spark-plug mounted directional injection probe was developed to study the fate of liquid fuel which impinges on different surfaces of the combustion chamber, and to quantify its contribution to the HC emissions from direct-injected (DI) and port-fuel injected (PFI) engines. With this probe, a controlled amount of liquid fuel was deposited on a given location within the combustion chamber at a desired crank angle while the engine was operated on pre-mixed LPG. Thus, with this technique, the HC emissions due to in-cylinder wall wetting were studied independently of all other HC sources. Results from these tests show that the location where liquid fuel impinges on the combustion chamber has a very important effect on the resulting HC emissions.

Piston wetting can be isolated from the other sources of HC emissions from DISI engines by operating the engine predominantly on a gaseous fuel and using an injector probe to impact a small amount of liquid fuel on the piston top. This results in a marked increase in HC emissions. All of our prior tests with the injector probe used California Phase 2 reformulated gasoline as the liquid fuel. In the present study, a variety of pure liquid hydrocarbon fuels are used to examine the influence of fuel volatility and structure. Additionally, the exhaust hydrocarbons are speciated to differentiate between the emissions resulting from the gaseous fuel and those resulting from the liquid fuel. It is shown that the HC emissions correspond to the Leidenfrost effect: fuels with very low boiling points yield high HCs and those with a boiling point near or above the piston temperature produce much lower HCs.

Off-cycle emissions from seven different types of 1994 light-duty vehicles were examined The test fleet consisted of 19 individual vehicles including a passenger car, two makes of light light-duty trucks, and five types of heavy light-duty trucks The driving cycles used for these tests were the US06(hard acceleration, high speed) cycle and the 20 °F FTP (the “Cold FTP”) Conventional FTPs were done for comparison Each vehicle was usually operated on at least two of the following CNG, LPG, Federal Phase 1 reformulated gasoline (FP1 RFG), and a low sulfur certification gasoline For both the conventional FTP and the US06 cycles, the alternative fuels produce statistically significant benefits in Ozone Forming Potential and exhaust toxics but the NOx emissions are not statistically different from those when operating on FP1 RFG with at least 90% confidence During Cold FTP tests, the emissions of CO and of toxics when operating on FP1 RFG are not statistically different from those when operating on a low sulfur certification gasoline In contrast the alternative fuels produce statistically significant benefits in the emissions of both CO and toxics compared to either of the gasolines during Cold FTP tests The Reactivity Adjustment Factor calculated from the present conventional FTP results for CNG agrees closely with the CARB value However, the present RAF for LPG is about half CARB s value, which is believed to be a consequence of the low propene in Texas LPG compared to the high propene in California LPG The effects of the test type on the emissions are also discussed

Multi-dimensional numerical simulation of the combustion process in spark ignition engines were performed using the Coherent Flame Model (CFM) which is based on the flamelet assumption. The CFM uses a balance equation for the flame surface area to simulate flame surface advection, diffusion, production and destruction in a turbulent reacting flow. There are two model constants in CFM, one associated with the modeling of flame surface production and the other with the modeling of flame surface destruction. Previous experimental results on two test engines charged with propane-air mixtures were used to compare with the computations for different engine speeds, loads, equivalence ratios and spark plug locations. Predicted engine cylinder pressure histories agree well with the experimental results for various operating conditions after the model constants were calibrated against a reference operating condition.