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The present paper concentrates on the option of catalytic autothermal reforming of gasoline for fuel cell applications. Major parameters of this process are the “Steam to Carbon Ratio” S/C and the air to fuel ratio λ. Computations assuming thermodynamic equilibrium in the autothermal reactor outlet (ATR) were carried out to attain information about their proper choice, as failure in adjusting the parameters within narrow limits has severe consequences on the reforming process. In order to quantify velocity distribution just ahead the catalyst and to evaluate mixing uniformity we designed an ATR featuring an optical access: Thus flow visualization using PIV (Particle Image Velocimetry) and LIF (Laser Induced Fluorescence) technique is possible. Preliminary PIV-results are presented and compared with CFD computations (Computational Fluid D ynamics).

A detailed understanding of the complex chemistry-turbulence interaction is gaining an increasing importance for further improvement of IC engine performance. Multidimensional optical diagnostic techniques have become a versatile tool for engine development. Sophisticated automatic data post-processing will achieve an increasing significance for efficient data reduction in such optical experiments. The focus of this paper is the detection of flame fronts using different image processing algorithms. In a further step of the data reduction, the extraction of the length of the flame front and the area of the burnt gases is presented. A strategy relying on a sensitivity analysis is discussed which allows an objective choice of parameters necessary for the application of the mathematical algorithms.

This paper reports on the development of novel time resolved spectroscopic imaging techniques for the study of spark ignition phenomena in combustion cells and an SI-engine. The techniques are based on planar laser induced fluorescence imaging (PLIF) of OH radicals, on fuel tracer PLIF, and on chemiluminescence. The techniques could be achieved at repetition rates reaching several hundreds of kilo-Hz and were cycle resolved. These techniques offer a new path along which engine related diagnostics can be undertaken, providing a wealth of information on turbulent spark ignition.

In this work, the potential of laser-induced ignition to improve combustion initiation and heat release in a direct-injection engine is investigated by a combined experimental and numerical investigation. Laser ignition is studied in fuel/air mixtures with homogeneous equivalence ratio fields. The results provide knowledge about minimum ignition energies and the ignition limits of laser-induced ignition. Furthermore, in mixtures with nominally identical conditions, statistical variations of the ignition success are observed experimentally. These variations can be explained, based on numerical simulations, by fluctuations in the strain rate in the turbulent in-cylinder flow. Additionally, laser ignition in engines with a spray-guided combustion mode, with strongly inhomogeneous fuel/air mixtures, was investigated.