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Hamilton Sundstrand Space Systems International (HSSSI) is currently under contract with NASA MSFC to design, fabricate and deliver the Water Processor Assembly (WPA) for the International Space Station (ISS). As part of this effort HSSSI has developed an oxidation catalyst for the catalytic reactor assembly in the WPA. This paper discusses full-scale development reactor testing and the status of the life testing of the oxidation catalyst used in the reactor.

The demands of future NASA exploration and scientific missions in space force the reevaluation of some of the basic assumptions and approaches that underlie current extravehicular activity (EVA) systems. Developing designs that can simultaneously achieve the advanced capabilities and the reductions in system mass and mission expendables targeted by NASA has proven to be a formidable challenge. The constraints of human needs, space environments, and current EVA system architectures demand technical capabilities beyond current expectations to achieve system goals. Under NASA Institute for Advanced Concepts (NIAC) sponsorship, Hamilton Sundstrand has been studying a new system paradigm to achieve the EVA system goals. The Chameleon Suit concept employs an active pressure suit that directly interacts between human systems and space environments.

Previous studies have shown that a multi-axis ankle joint accommodating abduction and adduction as well as ankle flexion/extension and rotation could be practically incorporated into a pressure suit. Several candidate configurations were manufactured and the performance of the enhanced ankle joints evaluated. Experience has suggested that these enhancements could be of significant benefit for planetary exploration missions requiring extensive walking over uneven terrain. During 1999, prototype pressure suit boots incorporating a multi-axis ankle joint configuration were manufactured. Their effect on balance stability and locomotion capabilities across slopes and over uneven surfaces in a pressurized spacesuit were evaluated in a series of 1-g experiments. This paper describes the enhanced test boots, the test procedure, and the results. Design refinements and further testing are recommended.

The TIMES system was evaluated to determine its ability to process reverse osmosis (RO) brine as one of the Advanced Water Processor steps. Since preliminary testing performed in 1998 showed that the membrane typically used in the process (Nafion 117) offered a very poor ammonia rejection, a search for an alternate membrane exhibiting high ammonia rejection capability was initiated under NASA-JSC funding. This investigation has resulted in the selection of a PolyVinylAlcohol (PVA) composite membrane as a replacement. When processing RO brine and untreated human urine as feeds, the Pervap 2201 membrane showed a 96% ammonia rejection over a large range of ammonia concentration. The water permeation rates in both laboratory-scale and pilot scale testings were also similar to the Nafion. The water permeance of the Pervap 2201 was approximately 7.5 kg/h/m2/atm (1.1 lb/h/m2/psi).

The Conductivity Sensor designed for use in the Node 3 Water Processor Assembly (WPA) was based on the existing Space Shuttle application for the fuel cell water system. However, engineering analysis has determined that this sensor design is potentially sensitive to two- phase fluid flow (gas/liquid) in microgravity. The source for this sensitivity is the fact that free gas will become lodged between the sensor probe and the wall of the housing without the aid of buoyancy in 1-g. Once gas becomes lodged in the housing, the measured conductivity will be offset based on the volume of occluded gas. A development conductivity sensor was flown on the NASA Microgravity Plane (KC-135) to measure the offset, which was determined to range between 0 and 50%. This range approximates the offset experienced in 1-g gas sensitivity testing.

The ISS (International Space Station) ITCS (Internal Thermal Control System) includes two internal coolant loops that utilize an aqueous based coolant for heat transfer. A silver salt biocide had previously been utilized as an additive in the coolant formulation to control the growth and proliferation of microorganisms within the coolant loops. Ground-based and in-flight testing demonstrated that the silver salt was rapidly depleted, and did not act as an effective long-term biocide. Efforts to select an optimal alternate biocide for the ITCS coolant application have been underway and are now in the final stages. An extensive evaluation of biocides was conducted to down-select to several candidates for test trials and was reported on previously.

The International Space Station (ISS) IATCS (Internal Active Thermal Control System) includes two internal coolant loops that use an aqueous based coolant for heat transfer. A silver salt biocide was used initially as an additive in the coolant formulation to control the growth and proliferation of microorganisms in the coolant loops. Ground-based and in-flight testing has demonstrated that the silver salt is rapidly depleted and not effective as a long-term biocide. Efforts are now underway to select an alternate biocide for the IATCS coolant loop with greatly improved performance. An extensive evaluation of biocides was conducted to select several candidates for test trials.

Catalytic oxidation is an effective means of controlling the build up of ammonia and other trace gas contaminants within closed spaces. However, it sometimes leads to the formation of noxious gases that need to be removed in post-treatment systems. In addition, ammonia removal is an issue when regeneration of water from wastewater is considered since ammonia is a byproduct of urea decomposition. For example, the VPCAR (Vapor Phase Catalytic Ammonia Reduction) advanced water processor system includes an oxidation reactor for the destruction of ammonia and of other volatile organics that are not separated out in the evaporator due to their volatility. The oxidation of ammonia may produce nitrogen, nitrogen oxides (NO and NO2), nitrous oxide (N2O) and water vapor. The Spacecraft Maximum Allowable Concentration (SMAC) for NO and NO2 are respectively 4.5 and 0.5 ppm whereas the Threshold Limit Value (TLV) for N2O is 25 ppm.