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Recently, dimethyl ether (DME) has been attracting much attention as a clean alternative fuel, since the thermal efficiency of DME powered diesel engine is comparable to diesel fuel operation and soot free combustion can be achieved. In this experiment, the effect of ambient pressure on DME spray was investigated with observation of droplet size such as Sauter mean diameter (SMD) by the shadowgraph and image processing method. The higher ambient pressure obstructs the growth of DME spray, therefore faster breakup was occurred, and liquid column was thicker with increasing the ambient pressure. Then engine performances and exhaust emissions characteristics of DME diesel engine were investigated with various compression ratios. The minimum compression ratio for the easy start and stable operation was obtained at compression ratio of about 12.

A feasibility study of an LPG DI diesel engine has been carried out to study the effectiveness of two selected cetane enhancing additives: Di-tertiary-butyl peroxide (DTBP) and 2-Ethylhexyl nitrate (EHN). When more than either 5 wt% DTBP or 3.5 wt% 2EHN was added to the base fuel (100 % butane), stable engine operation over a wide range of engine loads was possible (BMEPs of 0.03 to 0.60 MPa). The thermal efficiency of LPG fueled operation was found to be comparable to diesel fuel operation at DTBP levels over 5 wt%. Exhaust emissions measurements showed that NOx and smoke levels can be significantly reduced using the LPG+DTBP fuel blend compared to a light diesel fuel at the same experimental conditions. Correlations were derived for the measured ignition delay, BMEP, and either DTBP concentration or cetane number. When propane was added to a butane base fuel, the ignition delay became longer.

Serious problems occur in an exhaust gas recirculation system due to an adhesive hard deposit. It is important to clarify the mechanism of the hard deposit formation to suppress it. In this study, the effect of exhaust gas composition on hard deposit formation was investigated. The amount of the hard deposit formed under various operating conditions while keeping the total hydrocarbon concentration constant was different. The component analyses of the exhaust gas and the hard deposit clarified that polycyclic aromatic hydrocarbon in the exhaust gas strongly affected the hard deposit formation.

Three-way catalysts are used in gasoline vehicles for simultaneous purifying nitrogen oxide, carbon monoxide, and hydrocarbon in recent years. However, the reduction of ammonia emission generated in the three-way catalyst is pressing issue. In EURO 7, ammonia will also be subject to the Real Driving Emissions regulation, and its emissions must be reduced. Previous studies have shown that ammonia emissions are higher under fuel-rich conditions, suggesting that differences in driving behavior have a significant impact on ammonia emissions in real-world driving, which includes various driving environments. In this study, driving tests were conducted on a direct- injection gasoline vehicle equipped with a three-way catalyst and Portable Emission Measurement System and Sensor-based Emission Measurement System to investigate the actual ammonia emissions on actual roads.

Dimethyl Ether (DME) is a promising new alternative fuel for compression ignition DI engines. However, some problems arise from the poor lubricity of DME. Breakdown of the film bearing between needle and sleeve of the injector can lead to mechanical wear and leakage, a problem that is not mitigated easily. For example, the application of returning the leakage to fuel tank could raise a back pressure on the injection needle. This pressure can affect injection rate and consequently engine performance. In this study, fuels based on various DME to gas oil (diesel fuel) ratios were investigated, in part. Physical and chemical properties of DME and gas oil are shown to lead to mutual solubility at any ratio. Blended fuels have a higher lubricity compared with pure’ DME and a better injection spray compared with pure gas oil.

Exhaust gas recirculation (EGR) is widely used in diesel engines to reduce nitrogen oxide emissions. To meet the strict emission regulations, e.g., Real Driving Emissions, the EGR system is required to be used at temperatures lower than the present ones. However, under cool conditions, an adhesive deposit forms on the EGR valve or cooler because of the particulate matter and other components present in the diesel exhaust. This causes sticking of the EGR valve or degradation of the heat-exchange performance, which are serious problems. In this study, the EGR deposit formation mechanism was investigated based on spatially- and time-resolved scanning electron microscopy (SEM) observation. The deposit was formed in a custom-made sample line using real exhaust emitted from a diesel engine. The exhaust including soot was introduced into the sample line for 24 h (maximum duration), and the formed deposit was observed using SEM.

In this study, the main properties of two types of gas-to-liquid (GTL) fuels were investigated. Then, performance and emission characteristics of a compression ignition engine fueled with GTLs were investigated by comparison with diesel fuel. GTL1 was composed of 100% paraffin by volume, and GTL2 was composed of 99.8% paraffin and 0.2% aromatics by volume. Most GTL fuel properties were comparable to those of diesel fuel, while both fuels have a higher cetane number and lower sulphur. A diesel engine could be operated with GTL fueling without any special engine modifications. Our tests showed that with the high cetane number of GTLs, the ignition delay was shorter, and combustion started earlier than with diesel fuel. With GTL1 operation, THC and soot emissions were lower than with diesel fuel operation, and even lower with GTL2 fueling.

A urea-selective catalytic reduction (SCR) system is used for the reduction of NOx emitted from diesel engines. Although this SCR catalyst can reduce NOx over a wide temperature range, improvements in NOx conversion at relatively low temperatures, such as under cold-start or low-load engine conditions, are necessary. A close-coupled SCR (cc-SCR), which was set just after the engine exhaust manifold, was developed to address this issue. The temperature of the SCR catalyst increases rapidly owing to the higher exhaust temperatures, and NOx conversion is then enhanced under cold-start conditions. However, since the diesel oxidation catalyst is not installed before the SCR catalyst, hydrocarbon (HC) emissions pass directly through the SCR catalyst and poison it, leading to lower NOx conversion. Therefore, the mechanism of NOx conversion reduction on HC-poisoned SCR catalysts are required to be studied.

In this study, advantages of GTL fueled DI diesel engine were observed, then, some cautionary areas, notably the aptitude for sealing materials, were investigated. Some advantages of using GTL as a diesel engine fuel include reduction of soot emission levels, power output and fuel consumption with GTL to conventional diesel fuel operation is equivalent, super-low sulfur content of GTL and its liquid state at normal temperature and pressure. However, there are some problems with putting GTL fuel on the market, such as lubricity, aptitude for sealing materials, high cetane index and high pour point. It is necessary to use additives to improve GTL's lubricity, and selecting the most appropriate type of lubricity improver is also important. The influence of GTL on the swelling properties of standard rubber materials seem basically the same, but it is necessary to notice on used rubbers.

One way to reduce CO2 in the atmosphere is to use biodiesel fuel (BDF) [1]. BDF has the advantage of low smoke combustion, since its molecules contain oxygen. Meanwhile, BDF has the drawbacks of high viscosity and a high pour point that make it difficult to use at low temperatures. Dimethyl ether (DME) can be made from biomass, as well as from natural gas or coal; therefore, it is regarded as one of the biomass fuels. DME has low viscosity and a low boiling point, and smoke-free combustion can be obtained, since it has no carbon-carbon bond [2]. On the other hand, it has the disadvantage of low lubricity due to its low viscosity. When these fuels are blended together, the weaknesses of the fuels can be overcome. The objective of this research is to show that blending these two fuels is an effective way of bringing biomass-derived fuels into practical use.

Exhaust gas recirculation (EGR) is widely used in diesel engines to reduce nitrogen oxide (NOx) emissions. However, a lacquer is formed on the EGR valve or EGR cooler due to particulate matter and other components present in diesel exhaust, causing serious problems. In this study, the mechanism of lacquer deposition is investigated using attenuated total reflection Fourier transform infrared spectrometry (ATR-FTIR) and scanning electron microscopy (SEM). Deposition of temperature-dependent lacquers was evaluated by varying the temperature of a diamond prism between 80 and 120 °C in an ATR-FTIR spectrometer integrated into a custom-built sample line, which branched off from the exhaust pipe of a diesel engine. Lacquers were deposited on the diamond prism at 100 °C or less, while no lacquer was deposited at 120 °C. Time-dependent ATR-FTIR spectra were obtained for approximately 2 h from the beginning of the experiment.

For developing complicated after-treatment equipment for diesel-engine vehicles, such as urea-selective catalytic reduction (urea-SCR) systems, construction of a reaction model that can accurately predict ammonia (NH3) formation from urea is required. Hydrolysis of isocyanic acid (HNCO) is an important intermediate reaction in NH3 formation from urea. In our previous studies [1], a new rate constant for HNCO hydrolysis over fresh Cu-ZSM5 was derived using the measurements of the reaction rate of HNCO hydrolysis with high-purity HNCO formed from cyanuric acid. In this study, the reaction rates of the HNCO hydrolysis and NH3-SCR reactions were measured over a hydrothermally aged Cu-ZSM5 catalyst. A steady-state flow reactor equipped with a Fourier transform infrared spectrometer (FTIR) was employed to obtain the reaction rate of the HNCO hydrolysis and NH3-SCR reactions.

To meet the strict emission regulations for diesel engines, an advanced processing device such as a Urea-SCR (selective catalytic reduction) system is used to reduce NOx emissions. The Real Driving Emissions (RDE) test, which is implemented in the European Union, will expand the range of conditions under which the engine has to operate [1], which will lead to the construction of a Urea-SCR system capable of reducing NOx emissions at lower and higher temperature conditions, and at higher space velocity conditions than existing systems. Simulations are useful in improving the performance of the urea-SCR system. However, it is necessary to construct a reliable NOx reduction model to use for system design, which covers the expanded engine operation conditions. In the urea-SCR system, the mechanism of ammonia (NH3) formation from injected aqueous urea solution is not clear. Thus, it is important to clarify this mechanism to improve the NOx reduction model.

Diesel engines have better fuel economy over comparable gasoline engines and are useful for the reduction of CO2 emissions. However, to meet stringent emission standards, the technology for reducing NOx and particulate matter (PM) in diesel engine exhaust needs to be improved. A conventional selective catalytic reduction (SCR) system consists of a diesel oxidation catalyst (DOC), diesel particulate filter (DPF), and urea-SCR catalyst. Recently, more stringent regulations have led to the development of SCR systems with a larger volume and increased the cost of such systems. In order to solve these problems, an SCR catalyst-coated DPF (SCR/DPF) is proposed. An SCR/DPF system has lower volume and cost compared to the conventional SCR system. The SCR/DPF catalyst has two functions: combustion of PM and reduction of NOx emissions.

Dimethyl ether (DME) is a promising alternative fuel for compression ignition (CI) engines. DME features good auto ignition characteristics and soot-free combustion. In order to develop an injection system suitable for DME, it is necessary to understand its fuel properties. Sound speed is an important fuel property that affects the injection characteristics. However, the measurement data under high-pressures corresponding to those in fuel injection systems are lacking. The critical temperature of DME is lower than that of diesel fuel, and is close to the injection condition. It is important to understand the behavior of the sound speed around the critical point, since the sound speed at critical point is extremely low. In this study, sound speed in DME in a wide pressure and temperature range of 1 MPa to 80 MPa, 298.15 K to 413.15 K, including the vicinity of the critical point, was measured. The sound speed in DME decreases as either the pressure falls or the temperature rises.

In this study, the NO emission characteristics of a dimethyl ether fueled compression ignition (CI) engine were studied, and a suitable combustion control concept was developed. A three-zone thermo-chemical model was used to understand the basic NO formation characteristics with dimethyl ether. The experimental study was carried out using a small direct-injection diesel engine. Comparison of the experimental and calculated results showed that the dimethyl ether / air mixing process was relatively slow compared with diesel fuel, which is the main reason for the relatively high NO emissions with dimethyl ether operation, in spite of its lower adiabatic flame temperature. To reduce the high temperature period, turbulence was introduced into the combustion chamber by a high-turbulence combustion system, which reduced NO emissions. It became clear that acceleration of the mixing process is an important factor for NO reduction with dimethyl ether spray combustion.

In recent years, particulate matter (PM) emitted from direct-injection gasoline vehicles is becoming an increasingly concerning problem. In addition, it is often reported that ammonia (NH3) is emitted from gasoline vehicles equipped with a three-way catalyst. These emissions might be largely emitted especially when driving in on-road driving conditions. In this study, we investigated the emissions, NOx, NH3, and PM/PN (particulate number) of a light-duty direct-injection gasoline vehicle when driving on actual roads. Using a small direct-injection gasoline vehicle equipped with a three-way catalyst, experiment was conducted 8 times on the same route, and these emissions were measured. In this study, vehicle specific power (VSP) was introduced, which can be calculated using vehicle parameters, vehicle speed, and road gradient. The effects of parameters acquired through on-board diagnostics (OBD) port and VSP on emissions were investigated.

In this study, spray images of LPG Blended Fuels (LBF) for DI diesel engines were observed using a constant volume chamber at high ambient temperature and pressure, and the spray characteristics of the fuel were investigated. The LBF spray started to vaporize at the injector tip and the outer downstream regions of the spray, like diesel fuel, because of the high temperature at these areas. There were more vaporized areas compared to diesel fuel. Sufficient fuel injection volume and volatility of LBF resulted in good fuel-air mixture, then, THC emissions decreased compared to diesel fuel at high load engine test conditions. Butane spray image could not be observed at the injector tip. It seems that the high temperature of the injector tip caused the butane spray to vaporize rapidly. Spray tip penetration with LBF and butane were equal or greater than with diesel fuel. The high volatility of LBF and butane had no noticeable effect on spray penetration.

In this study, engine performances and exhaust emissions characteristics of compression ignition engine fueled with GTL were investigated by comparison with diesel fuel. Diesel engine could be operated fueled with GTL without any special modify for the test engine. With the high cetane number of GTL, the ignition lag was shorter, and the combustion started earlier than that of diesel fuel. Brake thermal efficiency operated with GTL increased at middle load conditions due to incomplete combustion emission such as CO and THC were lower than that of diesel fuel operation. NOx emission with GTL was comparable to diesel fuel, and there was a little decrease at high load. With GTL, soot emission was lower than with diesel fuel at above middle load condition. It seemed to be a reason of soot reduction that there was little sulphur contained in GTL.