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Technical Paper

Analysis of the Deterioration of Nylon-66 Immersed in GTL Diesel Fuel Part 1. Analysis and Test of Nylon and GTL Diesel Fuel Before and After Immersion

2006-10-16
2006-01-3326
The effect of GTL diesel fuel on organic materials used in fuel delivery systems of vehicles was investigated. Specimens made from 16 kinds of organic materials were immersed in GTL diesel fuels synthesized at Refinery-A and Refinery-B (referred to as GTL-A and GTL-B, respectively) and then subjected to tensile testing. The tensile test results revealed that elongation of the nylon sample immersed in GTL-A was extremely small, about 4% of that of untreated nylon. In the light of this finding, the GTL diesel fuels and nylons before and after immersion test were analyzed in detail using about 20 analysis methods to determine the cause for poor elongation. The following points were found. (1) GTL-A consisted of low molecular-weight paraffins. (2) GTL-A had low molecular-weight i-paraffins. (3) The nylon immersed in GTL-A contained low molecular-weight paraffins. (4) The paraffins in the nylon immersed in GTL-A were richer in i-paraffins than the original GTL-A.
Technical Paper

Combustion Improvement of CNG Engines by Hydrogen Addition

2011-08-30
2011-01-1996
This research aimed to identify how combustion characteristics are affected by the addition of hydrogen to methane, which is the main components of natural gas, and to study a combustion method that takes advantage of the properties of the blended fuel. It was found that adding hydrogen did not achieve a thermal efficiency improvement effect under stoichiometric conditions because cooling loss increased. The same result was obtained under EGR stoichiometric conditions. In contrast, under lean burn conditions, higher thermal efficiency and lower NOx than with methane combustion was achieved by utilizing the wide flammability range of hydrogen to expand the lean limit. Although NOx can be decreased easily by the addition of large quantities of hydrogen, the substantially lower energy density of the fuel causes a substantial reduction in cruising range. Consequently, this research improved the combustion of a CNG engine by increasing the tumble ratio to 1.8.
Technical Paper

Development of Fuel Cell Hybrid Vehicle in TOYOTA

2011-05-17
2011-39-7238
The outline of the TOYOTA FCHV-adv is described in this paper. The TOYOTA FCHVadv achieved an approximately 25 percent improvement in vehicle fuel efficiency and about 1.9 times the amount of usable hydrogen in comparison with the previous model. These improvements have enabled almost 2.5 times longer practical cruising range, more than 500 km. The freeze start capabilities of the FCHV-adv were improved by modifying the FC stack and control system. As a result, the FCHV-adv has been capable of starting at a temperature of -30°C. In the future, TOYOTA intends to improve durability and reduce costs.
Technical Paper

Development of High-Pressure Hydrogen Storage System for the Toyota “Mirai”

2015-04-14
2015-01-1169
The new Toyota FCV “Mirai” has reduced the weight, size, and cost of the high-pressure hydrogen storage system while improving fueling performance. The four 70 MPa tanks used on the 2008 Toyota FCHV-adv were reduced to two new larger diameter tanks. The laminated structure of the tanks was optimized to reduce weight, and a high-strength low-cost carbon fiber material was newly developed and adopted. The size of the high-pressure valve was reduced by improving its structure and a high-pressure sensor from a conventional vehicle was modified for use in a high-pressure hydrogen atmosphere. These innovations helped to improve the weight of the whole storage system by approximately 15% in comparison with Toyota FCHV-adv, while reducing the number of component parts by half and substantially reducing cost. The time required to fuel the FCV was greatly reduced by chilling the filling gas temperature at the hydrogen filling station to −40°C (as per SAE J2601).
Technical Paper

Study of High Efficiency Zero-Emission Argon Circulated Hydrogen Engine

2010-04-12
2010-01-0581
The potential of high efficiency zero-emission engines fueled by hydrogen, which is regarded as a promising form of energy for the future, is being researched. The argon circulated hydrogen engine [ 1 ] is one system theoretically capable of achieving both high efficiency and zero emissions, and its feasibility for use in vehicles has been studied. Specifically, tests were performed to verify the following issues. It was examined whether stable hydrogen combustion could be achieved under an atmosphere of argon and oxygen, which has a high specific heat ratio, and whether the substantial thermal efficiency improvement effect of the argon working gas could be achieved. An argon circulation system was also studied whereby steam, which is the combustion product of the hydrogen and oxygen emitted from the engine, is separated by condensation to enable the remaining argon to be re-used.
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