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This paper provides an overview of the dual EGO sensor method for OBD-II catalyst efficiency monitoring. The processes governing the relationship between catalyst oxygen storage, HC conversion efficiency, and rear EGO sensor response are reviewed in detail. A simple physical model relating catalyst oxygen storage capacity and rear EGO sensor response is constructed and used in conjunction with experimental data to provide additional insight into the operation of the catalyst monitor. The effect that the catalyst washcoat formulation has in determining the relationship between catalyst oxygen storage capacity and HC conversion efficiency and its impact on the catalyst monitor is also investigated. Lastly, the effects of catalyst failure mode, fuel sulfur, and the fuel additive MMT on the catalyst monitor's ability to properly diagnose catalyst function are discussed.

Engine and aftertreatment models have been developed in support of gasoline direct injection (GDI) engine development and aftertreatment system design. A brief overview of the engine models that were used to project emissions and fuel economy performance for the GDI engine is presented. Additionally, the construction and validation of a NOx trap aftertreatment model is described in considerable detail. The insights and increased understanding which have been gained regarding the trade-offs between engine out emission targets, aftertreatment performance, and emission constrained fuel economy benefits for direct injection gasoline engines are reviewed and discussed.

This paper summarizes some of the research which has been carried out at Ford Motor Co. in the area of NOx traps. Results from a large body of experimental work are reviewed and used to provide insight into the fundamental processes which govern NOx trap performance. In particular, the key parameters which control thermal durability and sulfur poisoning of the NOx trap are discussed in detail. In addition, a theoretical model of the NOx trap is described and used in the analysis and interpretation of the experimental results.

A study was performed on a lean NOx trap in which the loading of a ceria-containing mixed oxide in the washcoat was varied. After a mild stabilization of the traps, the time required to purge the NOx trap generally increased with increasing amount of mixed oxide. The purge NOx release also increased with increasing mixed oxide level but was greatly diminished after thermal aging. The sulfur tolerance of the NOx trap improved as the mixed oxide content was increased from 0% to 37%. The sample with 0% mixed oxide was more difficult to desulfate than the other samples due to poor water-gas-shift capability. After thermal aging, the NOx reduction efficiency on a 60 second lean/5 second rich cycle was highest for the samples with 0% to 37% mixed oxide at evaluation temperatures of 400°C to 500°C.