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Our concern was with the phenomenon of the fuel flow rate change in the injector due to deposit formation in the direct injection gasoline engine. The fundamental factors in the deposit formation on the nozzle were investigated, and engine dynamometer tests were performed. It was clarified that the residual fuel in the nozzle hole should be kept in a liquid state so that deposit precursors could be washed away by fuel injections. As a consequence, the nozzle temperature had to be below the 90 vol. % distillation temperature of the fuel, which was the most important index to suppress the deposit formation.

The catalyst of the crystalline ceramics known as a perovskite-type oxide was designed and controlled at the atomic level in order to create a new function for self-regeneration of precious metals in a usage ambience without auxiliary treatment. We have already reported that a catalyst with Pd supported on the perovskite-type oxide has higher activity than a catalyst with Pd supported on alumina. It was also found that Pd supported on the perovskite catalyst is finely dispersed [1, 2 and 3] The object of this study was to investigate the mechanism of self-regeneration by using hyper-analytical facilities. XAFS analysis, at SPring-8 (8 GeV), revealed that Pd is in six-fold coordinations with oxygen in a perovskite crystal, which indicating that Pd occupies the B site of the unit formula of ABO3 in the perovskite crystal structure under oxidation atmosphere.

The cause of the exhaust smoke and its reduction methods in a small DI Diesel engine with a small-orifice-diameter nozzle and common rail F.I.E. were investigated under high-speed and high-load condition, using both in-cylinder observations and Three-dimensional numerical analyses. The following points were clarified during this study. At these conditions, fuel sprays are easily pushed away by a strong swirl, and immediately flow out to the squish area by a strong reverse squish. Therefore, the air in the cavity is not effectively used. Suppressing the airflow in a piston cavity, using such ideas as enlarging the piston cavity diameter or reducing the port swirl ratio, decreases the excessive outflow of the fuel-air mixture into the squish area, and allows the full use of air in the whole cavity. Hence, exhaust smoke is reduced.

Countries and regions around the world are tightening emissions regulations in reaction to the increasing awareness of environmental conservation. At the same time, growing concerns about the depletion of raw materials as vehicle ownership continues to increase is prompting automakers to look for ways of decreasing the use of platinum-group metals (PGMs) in the exhaust systems. This research has developed a new catalyst with strong robustness against fluctuations in the exhaust gas and excellent nitrogen oxide (NOx) conversion performance. This catalyst incorporates rhodium (Rh) clusters with a particle size of several nanometers, and stabilized CeO2-ZrO2 solid-solution (CZ) with a pyrochlore crystal structure as a high-volume oxygen storage capacity (OSC) material with a slow O2 storage rate.

In conventional gasoline engine vehicles, three-way catalysts are used to simultaneously remove HC, CO and NOx from the exhaust gas. The effectiveness of the catalyst to remove these harmful species depends strongly on the oxygen concentration in the exhaust gas. Deterioration of three-way catalyst results in a reduction in its purification activity and OSC (oxygen storage capacity). In this investigation, additive elements were used to enhance the durability and OSC of the catalyst support material. An optimized formulation of a CeO2-ZrO2 and a ZrO2 material was developed to have excellent durability, improved OSC, enhanced interaction between precious metals and support materials, and increase thermal stability. Using these newly developed support materials, catalysts with increased performance was designed.

Growing concerns about the depletion of raw materials as vehicle ownership continues to increase is prompting automakers to look for ways of decreasing the use of platinum-group metals (PGMs) in the exhaust systems. This research has developed a new catalyst with strong robustness against fluctuations in the exhaust gas and excellent nitrogen oxide (NOx) conversion performance. One of the key technologies is a new OSC material that has low surface area (SA) and high OSC performance. We enhanced the pyrochlore- ceria/zirconia (CZ) which has a very small SA. In order to enhance the heat resistance and promote the OSC reaction, we selected and optimized the additive element. This material showed high OSC performance especially in the temperature range of 400 degrees or less. Another key technology is washcoat structure that has high gas diffusivity by making connected pore in the washcoat (New pore forming technology).

In order to reduce the energy consumption of the automotive air conditioning system, adsorption heat pump (AHP) system is one of the key technologies. We have been developing compact AHP system utilizing the exhaust heat from the engine coolant system (80-100 °C), which can meet the requirements in the automotive application. However, AHP systems have not been practically used in automotive applications because of its low volumetric power density of the adsorber. The volumetric power density of the adsorber is proportional to sorption rate, packing density and latent heat. In general, the sorption rate is determined by mass transfer resistance in primary particle of an adsorbent and heat and mass transfer resistance in packed bed. In order to improve the volumetric power density of the adsorber, it is necessary to increase the production of the sorption rate and the packing density.

According to the principle of pH measurement, an on-board type engine oil deterioration sensor has been developed. The developed sensor is composed of a Pb and oxidized stainless steel electrodes. The sensor signal shows a good linear relationship to the quasi-pH value of the oil. Especially in the region where the oil deterioration proceeds, the remaining basic additives in the oil is easily estimated from the sensor signal.

Fretting fatigue mechanism of rapidly solidified powder aluminum alloy has been studied by model tests and analysis using fracture mechanics. The factors which influences upon fretting scar formation and fatigue crack propagation were the main concerns in the present work. In order to investigate the mechanism of fretting scar formation in detail, fretting wear tests in which small amplitude oscillatory movement occurred in the contact region were carried out. Test results showed that the size of fretting scar increased with increasing tangential force coefficient. Characteristics of fretting fatigue crack propagation were analyzed using fracture mechanics. The fatigue limits under fretting conditions were estimated by connecting the applied stress intensity factor range calculated from applied cyclic stress and tangential force, with the threshold stress intensity factor range of small crack.

The properties of diesel fuels were investigated in terms of particulate emissions to clarify the specification of such a diesel fuel for minimizing particulate emissions. Diesel fuels were analyzed using thin layer chromatography (TLC), and gas chromatography/mass spectrometry (GC/MS). These analysis revealed the entire composition of hydrocarbons in diesel fuels according to molecular formula. The entire composition of hydrocarbons in diesel fuels could be expressd on a three-dimensional graph: the X-axis as carbon number, the Y-axis as H/C ratio and the Z-axis as the amount of hydrocarbons of identical molecular formula. By using the graph, the properties reported so far were investigated. Also, simplified images of the fuel sprayed into a cylinder and its flame were derived from the observational results previously reported.

In direct-injection (DI) gasoline engines, spray characteristics greatly affect engine combustion. For the rapid development of new gasoline direct-injectors, it is necessary to predict the spray characteristics accurately by numerical analysis based on the injector nozzle geometry. In this study, two-phase flow inside slit nozzle injectors is calculated using the volume of fluid method in a three-dimensional CFD. The calculation results are directly applied to the boundary conditions of spray calculations, of which the submodels are recently developed to predict spray formation process in direct injection gasoline engines. The calculation results are compared with the experiments. Good agreements are obtained for typical spray characteristics such as spray shape, penetration and Sauter mean diameter at both low and high ambient pressures. Two slit nozzle injectors of which the slit thickness is different are compared.

A new clean diesel combustion concept has been proposed and its excellent performance with respect to gas emissions and fuel economy were demonstrated using a single cylinder diesel engine. It features the following three items: (1) low-penetrating and highly dispersed spray using a specially designed injector with very small and numerous orifices, (2) a lower compression ratio, and (3) drastically restricted in-cylinder flow by means of very low swirl ports and a lip-less shallow dish type piston cavity. Item (1) creates a more homogeneous air-fuel mixture with early fuel injection timings, while preventing wall wetting, i.e., impingement of the spray onto the wall. In other words, this spray is suitable for premixed charge compression ignition (PCCI) operation, and can decrease both nitrogen oxides (NOx) and soot considerably when the utilization range of PCCI is maximized.

Diamond-like carbon (DLC) films are of significant interest for the automobile field, because they possess the potential to improve friction properties under various sliding conditions. Among the various DLC films, the authors focus on silicon-containing DLC (DLC-Si) films, which exhibit extremely low friction coefficient under dry sliding conditions in an ambient air atmosphere. The aim of this study is to examine the influence of silicon content in DLC-Si films on the friction property of the films, and to clarify the low friction mechanism of the films. The friction test was conducted under dry sliding conditions. It was found that the films have an exceedingly low friction coefficient (about 0.05) ranging in silicon content from 4 at% to 17 at%. In order to examine the low friction mechanism of the films, surface analyses were done on the wear surface of DLC-Si films slid against bearing steel.

In order to improve corrosion resistance and thermal efficiency of the air conditioner evaporator, a coating which provides hydrophilicity was formed over the chromate coating. In addition, there has been greater demand for air with fewer smells. This report describes the cause of “dusty odor” and a method to reduce it. The dusty odor is caused by a little corrosion of the substrate aluminum. Hydrophilic coating film dissolves little by little in condensed water, and substrate aluminum is exposed. A method to prevent the odor was developed by forming a coating giving hydrophilicity and durability to the evaporator surface.

NOx reduction activity in an oxidizing exhaust gas was significantly improved by discharging non-thermal plasma and catalysts (plasma assisted catalysis). We investigated effective catalyst for plasma assisted catalysis in view of hydrocarbon-selective catalytic reduction(HC-SCR). Plasma assist was effective for γ-alumina and alkali or alkaline earth metals loaded zeolite and γ-alumina showed the highest NOx conversion among these catalysts. On the other hand, Plasma assist was not effective for Cu-ZSM-5 and Pt loaded catalyst. The NOx conversion for the plasma assisted γ-alumina decreased by formation of a deposit on the catalyst below 400°C. It is shown that indium loading on γ-alumina improved the NOx reduction activity and suppressed the degradation of the NOx reduction activity at 300°C with plasma assist.

The drag reduction mechanism in newly developed low aerodynamic drag model car is investigated through numerical simulation. In order to deal with the computational domain around a three-dimensional complicated vehicle body, the method of overlaid grid system is employed. The results of computational case study on the body shape demonstrate that the lateral tapering near the rear end and the spats around the wheels bring better flow properties for drag reduction, such as the pressure recovery in the wake.

A new stratified charge combustion system has been developed for direct injection gasoline engines. The special feature of this system is employment of a thin fan-shaped fuel spray formed by a slit nozzle. The stratified mixture is produced by the combination of this fan-spray and a shell-shaped piston cavity. Both under-mixing and over-mixing of fuel in the stratified mixture is reduced by this system. This combustion system does not require distinct charge motion such as tumble or swirl, which enables intake port geometry to be simplified to improve full load performance. The effects of the new system on engine performance at part load are improved fuel consumption and reduced smoke, CO and HC emissions, obviously at medium load and medium engine speed. HC emissions at light load are also improved even with high EGR conditions.

The schlieren visualization of in-cylinder processes from the side of an engine cylinder is useful to understand the phenomena which change along the cylinder axis. A transparent collimating cylinder, TCC, permits schlieren observation inside the cylinder through its transparent wall. In this study, a single cylinder visualization engine with the TCC was applied to a direct-injection gasoline engine. A fuel spray, mixture formation and combustion were observed with a simultaneous measurement of in-cylinder pressure. The shape of the fuel spray and subsequent mixture formation process are drastically changed with the injection timing. The images of luminous flame were also taken with the schlieren images during the combustion period. Stable combustion, misfire and abnormal combustion are discussed with the comparison between the observed results and in-cylinder pressure analysis.

More than twenty years have passed since we invented polymer-clay nanocomposites (PCN), in which only a few wt.-% of silicate is randomly and homogeneously dispersed in the polymer matrix. When molded, these nanocomposites show superior properties compared to pristine polymers such as tensile strength, tensile modulus, heat distortion temperature, gas barrier property, and so on. The number of papers on PCN has increased rapidly in recent years, reaching over 500 only in 2005. As the pioneers of the new technology, we will review its history highlighting our works. Epoch-making events of PCN are as follows: In 1985, The first PCN, nylon 6-clay hybrid (NCH), was invented. In 1987, NCH was first presented at the ACS Fall Meetings. In 1989, NCH was presented at the MRS Fall Meetings, firing PCN. In 1989, Toyota launched cars equipped with a NCH part. In 1996, Clay was found to cause a memory effect in liquid crystals.

A series calculation methodology from the injector nozzle internal flow to the in-cylinder fuel spray and mixture formation in a diesel engine was developed. The present method was applied to a valve covered orifice (VCO) nozzle with the recent common rail injector system. The nozzle internal flow calculation using an Eulerian three-fluid model and a cavitation model was performed. The needle valve movement during the injection period was taken into account in this calculation. Inside the nozzle hole, cavitation appears at the nozzle hole inlet edge, and the cavitation region separates into two regions due to a secondary flow in the cross section, and it is distributed to the nozzle exit. Unsteady change of the secondary flow caused by needle movement affects the cavitation distribution in the nozzle hole, and the spread angle of the velocity vector at the nozzle exit.