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A methodology is presented with which aggregate emissions from the in-use automobile population can be calculated for any given calendar year. The data base needed for such a calculation is discussed, and areas in which further research is needed are pointed out. Results of a series of calculations are then presented showing the effect on aggregate emissions of various control strategies. The effects of an inspection/maintenance and retrofit program, different vehicle population growth rates, catalyst deterioration in use, and various schedules of new car emission standards for post-1975 vehicles are presented. It is shown that the rate at which old, higher-polluting vehicles are retired from the in-use vehicle population is the major factor in determining the rate at which aggregate emissions will decrease in the 1970s, with the precise level of post-1975 standards only becoming important in the 1980s.

A spark-ignition engine friction model developed by Patton et al. in the late 1980s was evaluated against current engine friction data, and improved. The model, which was based on a combination of fundamental scaling laws and empirical results, includes predictions of rubbing losses from the crankshaft, reciprocating, and valvetrain components, auxiliary losses from engine accessories, and pumping losses from the intake and exhaust systems. These predictions were based on engine friction data collected between 1980 and 1988. Some of the terms are derived from lubrication theory. Other terms were derived empirically from measurements of individual friction components from engine teardown experiments. Recent engine developments (e.g., improved oils, surface finish on piston liners, valve train mechanisms) suggested that the model needed updating.

Engine oil consumption is recognized to be a significant source of pollutant emissions. Unburned or partially burned oil in the exhaust gases contributes directly to hydrocarbon and particulate emissions. In addition, chemical compounds present in oil additives poison catalytic converters and reduce their conversion efficiency. Oil consumption can increase significantly during critical non-steady operating conditions. This study analyzes the oil consumption behavior during ramp transients in load by combining oil consumption measurements, in-cylinder measurements, and computer-based modeling. A sulfur based oil consumption method was used to measure real-time oil consumption during ramp transients in load at constant speed in a production spark ignition engine. Additionally in-cylinder liquid oil behavior along the piston was studied using a one-point Laser-Induced-Fluorescence (LIF) technique.

Today's diesel PM reduction systems are mainly based on catalyzed particulate filter(CPF) systems. However, most of their reaction kinetics remain unresolved. Among others, the soot oxidation rate over catalyst is particularly important in the evaluation of the performance of the catalysts and the efficient control of CPF regeneration. This study, therefore, investigated the oxidation rate of carbon black (Printex-U) over various Pt supported catalysts using a flow reactor setup simulating diesel exhaust conditions. Compared to non-catalyzed soot oxidation, the oxidation rate of carbon black over Pt catalysts was to an extent shifted towards low temperatures. This activity enhancement of soot oxidation over a catalyst can be attributed principally to NO to NO2 conversion because NO2 oxidizes soot with much lower activation energy (Ea=60kJ/mol) than O2 (Ea=177kJ/mol).

NO2 is an effective soot oxidizer operating at lower temperatures than O2. The effect of pure NO2 on soot oxidation was evaluated and compared with the gas treated by plasma, which initially consisted of NO, O2, and hydrocarbons. The cutout of a commercial DPF was used and the pressure difference across the DPF was monitored for an hour. The concentration of NO/NO2, CO, CO2 at the outlet of the DPF was measured as a function of time. CO and CO2 concentration was measured periodically by gas chromatography. The experiment was performed at 230, 250, 300, 350°C. When NO2 only was used as an oxidizing agent, there was a close relationship between the decrease of the pressure difference across the DPF, the CO and CO2 concentration at the outlet of the DPF, and the back conversion of NO2 to NO.

The purpose of this work was to develop an understanding of how liquid fuel transported into the cylinder of a port-fuel-injected gasoline-fueled SI engine contributes to hydrocarbon (HC) emissions. To simulate the liquid fuel flow from the valve seat region into the cylinder, a specially designed fuel probe was developed and used to inject controlled amounts of liquid fuel onto the port wall close to the valve seat. By operating the engine on pre-vaporized Indolene, and injecting a small amount of liquid fuel close to the valve seat while the intake valve was open, we examined the effects of liquid fuel entering the cylinder at different circumferential locations around the valve seat. Similar experiments were also carried out with closed valve injection of liquid fuel at the valve seat to assess the effects of residual blowback, and of evaporation from the intake valve and port surfaces.

The details of a model which predicts friction mean effective pressure (fmep) for spark-ignition engines are described. The model, which was based on a combination of fundamental scaling laws and empirical results, includes predictions of rubbing losses from the crankshaft, reciprocating, and valvetrain components, auxiliary losses from engine accessories, and pumping losses from the intake and exhaust systems. For some predictions, it was possible to derive terms which were proportional to fmep based on lubrication theory. For other predictions, phenomenological terms which described the results of the processes rather than the processes themselves were used. Each of the predictions was “calibrated” using fmep data from published sources. The sum of these predictions gave reliable estimates of spark-ignition engine fmep and serves as a useful tool for understanding how the major engine design and operating variables affect individual component friction.

A model has been developed for a divided-chamber automotive diesel engine which describes the intake, compression, combustion and expansion, and exhaust processes in sufficient detail to permit calculations of pressure, fuel-air ratio distribution, heat release distribution, NO formation, soot mass loading, and soot oxidation processes. The novel feature of this model is the use of a stochastic mixing approach during the combustion and expansion processes to describe the nonuniform fuel-air ratio distribution within the engine. In this approach, the fuel-air ratio distribution during the combustion and emissions formation processes can be followed as it evolves with time. Experimental data generated on a single-cylinder divided-chamber diesel engine were used to verify the accuracy of the model predictions. Agreement between experimental data and predicted values of engine performance and NOx emissions levels was good.

In this study, compositions, size distributions and activation energy in oxidation of diesel PM were investigated. Benzene (C6H6) was mixed to diesel fuel as a promoter of PM formation, and further, ferrocene (Fe(C5H5)2) was added as a promoter for oxidation processes during in-cylinder combustion and after-treatment. The effect of those additions on the PM characteristics was discussed on the basis of measured results such as SOF and dry-soot ratio in PM, primary and aggregate particle size distributions of PM, activation energy of PM oxidation, and PM components with elemental analysis. As a result, it was shown that ferrocene had special effect on the PM size distribution and the activation energy.

An experimental study was performed in a firing SI engine at conditions representative of the warmup phase of operation in which liquid gasoline films were established at various locations in the combustion chamber and the resulting impact on hydrocarbon emissions was assessed. Unique about this study was that it combined, in a firing engine environment, direct visual observation of the liquid fuel films, measurements of the temperatures these films were subjected to, and the determination from gas analyzers of burned and unburned fuel quantities exiting the combustion chamber - all with cycle-level resolution or better. A means of deducing the exhaust hydrocarbon emissions that were due to the liquid fuel films in the combustion chamber was developed. An increase in exhaust hydrocarbon emissions was always observed with liquid fuel films present in the combustion chamber.

Experiments to study the effects of oxygenated fuels on emissions and combustion were performed in a single-cylinder direct-injection (DI) diesel engine. A matrix of oxygen containing fuels assessed the impact of weight percent oxygen content, oxygenate chemical structure, and oxygenate volatility on emissions. Several oxygenated chemicals were blended with an ultra-low sulfur diesel fuel and evaluated at an equivalent energy release and combustion phasing. Additional experiments investigated the effectiveness of oxygenated fuels at a different engine load, a matched fuel/air equivalence ratio, and blended with a diesel fuel from the Fischer-Tropsch process. Interactions between emissions and critical engine operating parameters were also quantified. A scanning mobility particle sizer (SMPS) was used to evaluate particle size distributions, in addition to particulate matter (PM) filter and oxides of nitrogen (NOx) measurements.

An experimental study was performed to develop a more fundamental understanding of the effects of secondary air injection (SAI) on exhaust gas emissions and catalyst light-off characteristics during cold start of a modern SI engine. The effects of engine operating parameters and various secondary air injection strategies such as spark retardation, fuel enrichment, secondary air injection location and air flow rate were investigated to understand the mixing, heat loss, and thermal and catalytic oxidation processes associated with SAI. Time-resolved HC, CO and CO₂ concentrations were tracked from the cylinder exit to the catalytic converter outlet and converted to time-resolved mass emissions by applying an instantaneous exhaust mass flow rate model. A phenomenological model of exhaust heat transfer combined with the gas composition analysis was also developed to define the thermal and chemical energy state of the exhaust gas with SAI.

Experiments were conducted to determine the effects of substantial spark retard on combustion, hydrocarbon (HC) emissions, and exhaust temperature, under cold engine conditions. A single-cylinder research engine was operated at 20° C fluid temperatures for various spark timings and relative air/fuel ratios. Combustion stability was observed to decrease as the phasing of the 50% mass fraction burned (MFB) occurred later in the expansion stroke. A thermodynamic burn rate analysis indicated combustion was complete at exhaust valve opening with -20° before top dead center (BTDC) spark timings. Chemical and thermal energy of the exhaust gas was tracked from cylinder-exit to the exhaust runner. Time-resolved HC concentrations measured in the port and runner were mass weighted to obtain an exhaust HC mass flow rate. Results were compared to time averaged well downstream HC levels.

The high concentration of particulate matter (PM) in diesel exhaust gas causes significant soot deposition on the wall of EGR cooler, and reduces the heat transfer performance of the EGR cooler and the reduction rate of NOx. The deposition of PM tends to be occurred more severely with "heavy wet PM," which is more frequently at the LTC (low temperature combustion) engine. The objective of this work is to evaluate the effects of soluble organic fraction (SOF) on deposit characteristics of the EGR cooler. To measure reliable mean particle concentration values and surrogate SOFs, the soot generator with SOF vaporizer was used. As for two surrogate SOFs, n-dodecane and diesel lube oil, deposit mass increased when they were injected. Especially from the experiment results, it was found that the lube oil effect was more significant than the n-dodecane effect and lube oil also had a stronger effect on reduction of thermal conductivity by filling pores in deposits.

Characteristics of soot oxidation were investigated with a carbon black (Printex-U). A flow reactor system which can simulate the condition of diesel particulate filter and diesel exhaust gas (1 bar, O2 0 ∼ 10%, NO2 200 ∼ 900ppm) was designed and used with the temperature programmed oxidation (TPO) and constant temperature oxidation (CTO) techniques. The temperature increase rate was 5°C/min for TPO experiments. From the experiments, the apparent activation energy for carbon oxidation with nitrogen dioxide was determined as 60 ± 3 kJ/mol with the first order of carbon in the range of 10∼90% oxidation and the temperature range of 250∼500°C. This value was exceedingly lower than the activation energy of oxygen oxidation which was 177 ± 1 kJ/mol. When oxygen exists with nitrogen dioxide, the reaction rate increased with the concentration of oxygen. Its rate of increase was faster for low oxygen concentration and slower for high concentration.

Plasma-catalyst (Ag, Au/Al2O3) systems were applied to NOx reduction in a model lean-burn engine exhaust gas. Also, DeNOx test of real diesel exhaust gas was performed by plasma-Ag/Al2O3 system. In the case of model exhaust gas, the catalytic activity for NOx reduction was enhanced by the assistance of plasma in the wide temperature range. The NOx conversion efficiency of plasma-Ag/Al2O3 was 40∼90% under the condition of C3 H6 3200ppm (C1/NOx = 5.96) and 10% O2 over the temperature range of 250∼400°C. The plasma-Au/Al2 O3 system showed remarkable low temperature NOx reduction activity at 100∼250°C. The real engine full flow test was performed for 70% of the full load and at engine speed of 1500rpm. NOx removal of 46% from the diesel exhaust gas was achieved by the plasma-Ag/Al2O3 catalyst system at 364°C(C1/NOx = 6). In the case of higher C1/NOx = 10, the NOx conversion increased up to 73% at 381°C. Also, DeNOx engine tests were performed for full load of 1500, 2000 and 2500rpm.

The oxidation of soot (carbon black) which is assisted by Pt/CeO2 catalyst is studied using a flow reactor system simulating the condition of diesel exhaust. In this study, the temperature programmed oxidation (TPO) scheme is mainly used for different NO and O2 concentrations and soot oxidation rate is evaluated by monitoring both CO and CO2 concentrations. Pt/CeO2 catalyst lowers the temperature of the peak CO/CO2 concentrations significantly when there is either NO or O2. Oxidation starts at 200°C and the peak CO2 concentration is observed at 360°C, which depends on the amount of catalyst and NO concentration. The effect of catalyst on NO2 recycling is also investigated. For this purpose, two different types of sample have been prepared. For the mixed case, 10mg of carbon black is mixed with 50mg of Pt/CeO2 catalyst under conditions of loose contact. For the unmixed case, the catalyst layer is placed on top of soot layer without mixing.

Two features to facilitate chemical reactions at low temperature, non-thermal plasma and the weak dependency of photocatalyst on temperature, have been exploited by many researchers to effectively decompose hydrocarbon emissions emitted until the light-off of a three-way catalyst in spark ignition engines. To develop a realizable emissions reduction reactor, as part of such effort, this study investigates for the three model gases, propylene, n-butane and acetylene: 1) the conversion efficiency of the emissions reduction reactor, which utilizes the effect of dissociation, ionization-by-collision of the non-thermal plasma and the photocatalytic effect of TiO2, and 2) the concentrations of the products such as acetaldehyde, acetic acid, polymerized hydrocarbons and NO2. The operating parameters to obtain the plasma energy density ranging from 7.8 to 908 J/L were varied.

In the study of internal combustion engines, gas temperatures within the system are of significant importance. The adverse conditions under firing operation, however, make measurements by any means very difficult. This current study seems to have gone the farthest to date for velocity of sound gas temperature measurements in internal combustion engine applications. An ultrasound signal is sent by a transmitting transducer, through the gas medium, and into the receiving transducer. The received signal is recorded, and the gas temperature determined from the time of flight. In-cylinder and exhaust manifold gas temperatures under fired conditions are presented, and are all consistent. Impacts of operating parameters like mixture equivalence ratio and coolant temperature are investigated.

In this research, an optical system for the detection of the flame propagation under the non-knocking and knocking conditions is developed and applied to a mass produced four cylinder SI engine. The normal flames are measured and analyzed under the steady state operating conditions at various engine speeds. For knocking cycles, the flame front propagations before and after knock occurrence are simultaneously taken with cylinder pressure data. In non-knocking and knocking cycles, flame propagation shows cycle-by-cycle variations, which are quite severe especially in the knocking cycles. The normal flame propagations are analyzed at various engine speeds, and show that the flame front on the exhaust valve side becomes faster as the engine speed increases. According to the statistical analysis, knock occurence location and flame propagation process after knock can be categorized into five different types.