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This paper quantifies the potential of electric propulsion systems to reduce petroleum use and greenhouse gas (GHG) emissions in the 2030 U.S. light-duty vehicle fleet. The propulsion systems under consideration include gasoline hybrid-electric vehicles (HEVs), plug-in hybrid vehicles (PHEVs), fuel-cell hybrid vehicles (FCVs), and battery-electric vehicles (BEVs). The performance and cost of key enabling technologies were extrapolated over a 25-30 year time horizon. These results were integrated with software simulations to model vehicle performance and tank-to-wheel energy consumption. Well-to-wheel energy and GHG emissions of future vehicle technologies were estimated by integrating the vehicle technology evaluation with assessments of different fuel pathways. The results show that, if vehicle size and performance remain constant at present-day levels, these electric propulsion systems can reduce or eliminate the transport sector's reliance on petroleum.

Transport policy research seeks to predict and substantially reduce the future transport-related greenhouse gas emissions and fuel consumption to prevent negative climate change impacts and protect the environment. However, making such predictions is made difficult due to the uncertainties associated with the anticipated developments of the technology and fuel situation in road transportation, which determine the total fuel use and emissions of the future light-duty vehicle fleet. These include uncertainties in the performance of future vehicles, fuels' emissions, availability of alternative fuels, demand, as well as market deployment of new technologies and fuels. This paper develops a methodology that quantifies the impact of uncertainty on the U.S. transport-related fuel use and emissions by introducing a stochastic technology and fleet assessment model that takes detailed technological and demand inputs.

Modern natural gas-to-liquids (GTL) conversion processes (Fischer-Tropsch liquid fuels (FTL)) offers an attractive means for making synthetic liquid fuels. Military diesel and jet fuels are procured under Commercial Item Description (CID) A-A-52557 (based on ASTM D 975) and MIL-DTL-83133/MIL-DTL-5624 (JP-8/JP-5), respectively. The Single Fuel Forward (single fuel in the battlefield) policy requires the use of JP-8 or JP-5 (JP-8/5). Fuel properties crucial to fuel system/engine performance/operation are identified for both old and new tactical/non-tactical vehicles. The 21st Century Truck program is developing technology for improved safety, reduced harmful exhaust emissions, improved fuel efficiency, and reduced cost of ownership of future military and civilian ground vehicles (in the heavy duty category having gross vehicle weights exceeding 8500 pounds).[1]

A spark-ignition engine friction model developed by Patton et al. in the late 1980s was evaluated against current engine friction data, and improved. The model, which was based on a combination of fundamental scaling laws and empirical results, includes predictions of rubbing losses from the crankshaft, reciprocating, and valvetrain components, auxiliary losses from engine accessories, and pumping losses from the intake and exhaust systems. These predictions were based on engine friction data collected between 1980 and 1988. Some of the terms are derived from lubrication theory. Other terms were derived empirically from measurements of individual friction components from engine teardown experiments. Recent engine developments (e.g., improved oils, surface finish on piston liners, valve train mechanisms) suggested that the model needed updating.

A set of experiments was performed to investigate the effects of relative air-fuel ratio, inlet boost pressure, and compression ratio on engine knock behavior. Selected operating conditions were also examined with simulated hydrogen rich fuel reformate added to the gasoline-air intake mixture. For each operating condition knock limited spark advance was found for a range of octane numbers (ON) for two fuel types: primary reference fuels (PRFs), and toluene reference fuels (TRFs). A smaller set of experiments was also performed with unleaded test gasolines. A combustion phasing parameter based on the timing of 50% mass fraction burned, termed “combustion retard”, was used as it correlates well to engine performance. The combustion retard required to just avoid knock increases with relative air-fuel ratio for PRFs and decreases with air-fuel ratio for TRFs.

Engine oil consumption is recognized to be a significant source of pollutant emissions. Unburned or partially burned oil in the exhaust gases contributes directly to hydrocarbon and particulate emissions. In addition, chemical compounds present in oil additives poison catalytic converters and reduce their conversion efficiency. Oil consumption can increase significantly during critical non-steady operating conditions. This study analyzes the oil consumption behavior during ramp transients in load by combining oil consumption measurements, in-cylinder measurements, and computer-based modeling. A sulfur based oil consumption method was used to measure real-time oil consumption during ramp transients in load at constant speed in a production spark ignition engine. Additionally in-cylinder liquid oil behavior along the piston was studied using a one-point Laser-Induced-Fluorescence (LIF) technique.

This paper explores the benefits that would be achieved if gasoline marketers produced and offered a higher-octane gasoline to the U.S. consumer market as the standard grade. By raising octane, engine knock constraints are reduced, so that new spark-ignition engines can be designed with higher compression ratios and boost levels. Consequently, engine and vehicle efficiencies are improved thus reducing fuel consumption and greenhouse gas (GHG) emissions for the light-duty vehicle (LDV) fleet over time. The main objective of this paper is to quantify the reduction in fuel consumption and GHG emissions that would result for a given increase in octane number if new vehicles designed to use this higher-octane gasoline are deployed. GT-Power simulations and a literature review are used to determine the relative brake efficiency gain that is possible as compression ratio is increased.

Today's diesel PM reduction systems are mainly based on catalyzed particulate filter(CPF) systems. However, most of their reaction kinetics remain unresolved. Among others, the soot oxidation rate over catalyst is particularly important in the evaluation of the performance of the catalysts and the efficient control of CPF regeneration. This study, therefore, investigated the oxidation rate of carbon black (Printex-U) over various Pt supported catalysts using a flow reactor setup simulating diesel exhaust conditions. Compared to non-catalyzed soot oxidation, the oxidation rate of carbon black over Pt catalysts was to an extent shifted towards low temperatures. This activity enhancement of soot oxidation over a catalyst can be attributed principally to NO to NO2 conversion because NO2 oxidizes soot with much lower activation energy (Ea=60kJ/mol) than O2 (Ea=177kJ/mol).

Gasoline/ethanol fuel blends have significant synergies with Spark Ignited Direct Injected (SI DI) engines. The higher latent heat of vaporization of ethanol increases charge cooling due to fuel evaporation and thus improves knock onset limits and efficiency. Realizing these benefits, however, can be challenging due to the finite time available for fuel evaporation and mixing. A methodology was developed to quantify how much in-cylinder charge cooling takes place in an engine for different gasoline/ethanol blends. Using a turbocharged SI engine with both Port Fuel Injection (PFI) and Direct Injection (DI), knock onset limits were measured for different intake air temperatures for both types of injection and five gasoline/ethanol blends. The superior charge cooling in DI compared to PFI for the same fuel resulted in pushing knock onset limits to higher in-cylinder maximum pressures. Knock onset is used as a diagnostic of charge cooling.

Spark Ignited Direct Injection (SI DI) of fuel extends engine knock limits compared to Port Fuel Injection (PFI) by utilizing the large in-cylinder charge cooling effect due to fuel evaporation. The use of gasoline/ethanol blends in direct injection (DI) is therefore especially advantageous due to the high heat of vaporization of ethanol. In addition to the thermal benefit due to charge cooling, ethanol blends also display superior chemical resistance to autoignition, therefore allowing the further extension of knock limits. Unlike the charge cooling benefit which is realized mostly in SI DI engines, the chemical benefit of ethanol blends exists in Port Fuel Injected (PFI) engines as well. The aim of this study is to separate and quantify the effect of fuel chemistry and charge cooling on knock. Using a turbocharged SI engine with both PFI and DI, knock limits were measured for both injection types and five gasoline-ethanol blends.

This paper assesses the potential improvement of automotive powertrain technologies 25 years into the future. The powertrain types assessed include naturally-aspirated gasoline engines, turbocharged gasoline engines, diesel engines, gasoline-electric hybrids, and various advanced transmissions. Advancements in aerodynamics, vehicle weight reduction and tire rolling friction are also taken into account. The objective of the comparison is the potential of anticipated improvements in these powertrain technologies for reducing petroleum consumption and greenhouse gas emissions at the same level of performance as current vehicles in the U.S.A. The fuel consumption and performance of future vehicles was estimated using a combination of scaling laws and detailed vehicle simulations. The results indicate that there is significant potential for reduction of fuel consumption for all the powertrains examined.

The purpose of this work was to develop an understanding of how liquid fuel transported into the cylinder of a port-fuel-injected gasoline-fueled SI engine contributes to hydrocarbon (HC) emissions. To simulate the liquid fuel flow from the valve seat region into the cylinder, a specially designed fuel probe was developed and used to inject controlled amounts of liquid fuel onto the port wall close to the valve seat. By operating the engine on pre-vaporized Indolene, and injecting a small amount of liquid fuel close to the valve seat while the intake valve was open, we examined the effects of liquid fuel entering the cylinder at different circumferential locations around the valve seat. Similar experiments were also carried out with closed valve injection of liquid fuel at the valve seat to assess the effects of residual blowback, and of evaporation from the intake valve and port surfaces.

The goal of this paper is to quantitatively assess the implications of congressionally mandated biofuel targets on requirements for ethanol blending, distribution, and usage in spark ignition engines in the U.S. light-duty vehicle fleet. The “blend wall” is a term that refers to the maximum amount of ethanol that can be blended into the gasoline pool without exceeding the legal volumetric blend limit of 10%. Beyond the blend wall, the additional ethanol fuel must be used in higher blends of ethanol like E85. Once the blend wall is reached, the existing fleet of flex fuel vehicles (FFVs) will be required to use E85 for some percentage of vehicle miles traveled (VMT) in order to achieve the Renewable Fuel Standard (RFS) targets.

The details of a model which predicts friction mean effective pressure (fmep) for spark-ignition engines are described. The model, which was based on a combination of fundamental scaling laws and empirical results, includes predictions of rubbing losses from the crankshaft, reciprocating, and valvetrain components, auxiliary losses from engine accessories, and pumping losses from the intake and exhaust systems. For some predictions, it was possible to derive terms which were proportional to fmep based on lubrication theory. For other predictions, phenomenological terms which described the results of the processes rather than the processes themselves were used. Each of the predictions was “calibrated” using fmep data from published sources. The sum of these predictions gave reliable estimates of spark-ignition engine fmep and serves as a useful tool for understanding how the major engine design and operating variables affect individual component friction.

A computer simulation of the four-stroke spark-ignition engine cycle has been developed for studies of the effects of variations in engine design and operating parameters on engine performance, efficiency and NO emissions. The simulation computes the flows into and out of the engine, calculates the changes in thermodynamic properties and composition of the unburned and burned gas mixtures within the cylinder through the engine cycle due to work, heat and mass transfers, and follows the kinetics of NO formation and decomposition in the burned gas. The combustion process is specified as an input to the program through use of a normalized rate of mass burning profile. From this information, the simulation computes engine power, fuel consumption and NO emissions. Predictions made with the simulation have been compared with data from a single-cylinder CFR engine over a range of equivalence ratios, spark-timings and compression ratios.

For gasoline engine, thermal efficiency can be improved by using lean burn. However, combustion instability occurs when gasoline engine is operated on lean condition. Hydrogen has features that can be used for improving combustion stability of gasoline engine. In this paper, an experimental study of hydrogen effect on lean limit was carried out using a four-cylinder 2.0L turbo gasoline direct injection engine. The engine torque was fixed at 110Nm on 1600RPM, 2000RPM and 2400RPM. The results showed that lean limit was extended and brake thermal efficiency was improved by hydrogen addition. Especially, at lower engine speed, the large improvement of lean limit was achieved. However, improvement of brake thermal efficiency was achieved at high speed. HC and CO2 emissions were decreased and NO emissions increased with hydrogen addition. CO emissions were slightly reduced with hydrogen addition.

Effect of various hydrocarbons on the plasma DeNOx process in simulated diesel engine operating conditions is investigated experimentally and theoretically. This paper shows the results of an extensive series of experiments on the NOx conversion effect of various hydrocarbons (methane, ethene, propene, propane) in the plasma. The effects of energy density, temperature, and the initial concentrations of hydrocarbon and oxygen are discussed and the results for each hydrocarbon are compared with one another. The energy required to convert one NO molecule is measured 13.8eV, 16.1eV, 23.2eV, 45.6eV for propene, ethene, propane, methane, respectively when energy density of 25.4J/L is delivered to the mixture of 10% O2, base N2 with 440ppm NO and 500ppm hydrocarbon at 473K, while it is 143.2eV without hydrocarbon. The best NOx conversion effect of propene among the mentioned hydrocarbons is due to the highest reaction rates of propene with O and OH.

An experimental study was performed to develop a more fundamental understanding of the effects of secondary air injection (SAI) on exhaust gas emissions and catalyst light-off characteristics during cold start of a modern SI engine. The effects of engine operating parameters and various secondary air injection strategies such as spark retardation, fuel enrichment, secondary air injection location and air flow rate were investigated to understand the mixing, heat loss, and thermal and catalytic oxidation processes associated with SAI. Time-resolved HC, CO and CO₂ concentrations were tracked from the cylinder exit to the catalytic converter outlet and converted to time-resolved mass emissions by applying an instantaneous exhaust mass flow rate model. A phenomenological model of exhaust heat transfer combined with the gas composition analysis was also developed to define the thermal and chemical energy state of the exhaust gas with SAI.

Experiments were conducted to determine the effects of substantial spark retard on combustion, hydrocarbon (HC) emissions, and exhaust temperature, under cold engine conditions. A single-cylinder research engine was operated at 20° C fluid temperatures for various spark timings and relative air/fuel ratios. Combustion stability was observed to decrease as the phasing of the 50% mass fraction burned (MFB) occurred later in the expansion stroke. A thermodynamic burn rate analysis indicated combustion was complete at exhaust valve opening with -20° before top dead center (BTDC) spark timings. Chemical and thermal energy of the exhaust gas was tracked from cylinder-exit to the exhaust runner. Time-resolved HC concentrations measured in the port and runner were mass weighted to obtain an exhaust HC mass flow rate. Results were compared to time averaged well downstream HC levels.

Characteristics of soot oxidation were investigated with a carbon black (Printex-U). A flow reactor system which can simulate the condition of diesel particulate filter and diesel exhaust gas (1 bar, O2 0 ∼ 10%, NO2 200 ∼ 900ppm) was designed and used with the temperature programmed oxidation (TPO) and constant temperature oxidation (CTO) techniques. The temperature increase rate was 5°C/min for TPO experiments. From the experiments, the apparent activation energy for carbon oxidation with nitrogen dioxide was determined as 60 ± 3 kJ/mol with the first order of carbon in the range of 10∼90% oxidation and the temperature range of 250∼500°C. This value was exceedingly lower than the activation energy of oxygen oxidation which was 177 ± 1 kJ/mol. When oxygen exists with nitrogen dioxide, the reaction rate increased with the concentration of oxygen. Its rate of increase was faster for low oxygen concentration and slower for high concentration.