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In this work, constant volume combustion is studied using a zero-dimensional FORTRAN code, which is a wide-ranging chemical kinetic simulation that allows a closed system of gases to be described on the basis of a set of initial conditions. The model provides an engine- or reactor-like environment in which the engine simulations allow for a variable system volume and heat transfer both to and from the system. The combustion chamber is divided into two zones as burned and unburned ones, which are separated by an assumed thin flame front in the combustion model used for this work. Equilibrium assumptions have been adopted for the modeling of the thermal ionization, where Saha's equation was derived for singly ionized molecules. The investigation is focused on the thermal ionization of NO as well as for other species. The outputs generated by the model are temperature profiles, species concentration profiles, ionization degree and an electron density for each zone.

The intention of the presented work was to develop a new simulation tool that fits into a CFD (computational fluid dynamics) workflow and provides information about the soot particle size distribution. Additionally it was necessary to improve and use state-of-the-art measurement techniques in order to be able to gain more knowledge about the behavior of the soot particles and to validate the achieved simulation results. The work has been done as a joint research financed by the European Community under FP5.