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There have been strong demands recently for reductions in the fuel consumption and exhaust emissions of diesel engines from the standpoints of conserving energy and curbing global warming. A great deal of research is being done on new emission control technologies using direct-injection (DI) diesel engines that provide high thermal efficiency. This work includes dramatic improvements in the combustion process. The authors have developed a new combustion concept called Modulated Kinetics (MK), which reduces smoke and NOx levels simultaneously by reconciling low-temperature combustion with pre-mixed combustion [1, 2]. At present, research is under way on the second generation of MK combustion with the aim of improving emission performance further and achieving higher thermal efficiency [3]. Reducing heat rejection in the combustion chamber is effective in improving the thermal efficiency of DI diesel engines as well as that of MK combustion.

Experimental investigations were previously conducted with a direct-injection diesel engine with the aim of reducing exhaust emissions, especially nitrogen oxides (NOx) and particulate matter (PM). As a result of that work, a combustion concept, called Modulated Kinetics (MK) combustion, was developed that reduces NOx and smoke simultaneously through low-temperature combustion and premixed combustion to achieve a cleaner diesel engine. In subsequent work, it was found that applying a low compression ratio was effective in expanding the MK combustion region on the high-load side. The MK concept was then combined with an exhaust after-treatment system and applied to a test vehicle. The results indicated the attainment of ULEV emission levels, albeit in laboratory evaluations. In the present work, the combination of the MK combustion concept and certain fuel properties has been experimentally investigated with the aim of reducing exhaust emissions further.

In recent years, catalyst systems such as a lean NOx trap (LNT) catalyst system and a urea selective catalytic reduction (SCR) system have been developed to obtain cleaner diesel emissions. At Nissan, we developed an emission control system for meeting Tier 2 Bin 5 requirements in 2003. On the basis of that technology, a new HC-NOx trap catalyst system has now been developed that complies with the SULEV standards without increasing the catalyst volume and precious metal loading. Compliance with the SULEV standards requires a further reduction of HC (NMHC) emissions by 84% and NOx by 60% compared with the emission performance Tier 2 Bin 5 compliant catalyst system. Consequently high conversion performance for both HCs and NOx is needed. An investigation of HC emission behavior under the FTP75 mode showed that a reduction of cold-phase HCs was critical for meeting the standard. Large quantities of HCs above C4 are emitted in the cold state.

To reduce NOx emissions from diesel engines, the urea-SCR (selective catalytic reduction) system has been introduced commercially. In urea-SCR, the freezing point of the urea aqueous solution, the deoxidizer, is −11°C, and the handling of the deoxidizer under cold weather conditions is a problem. Further, the ammonia escape from the catalyst and the generation of N2O emissions are also problems. To overcome these disadvantages of the urea-SCR system, the addition of a hydrocarbon deoxidizer has attracted attention. In this paper, a micro-reactor SCR system was developed and attached to the exhaust pipe of a single cylinder diesel engine. With the micro-reactor, the catalyst temperature, quantity of deoxidizer, and the space velocity can be controlled, and it is possible to use it with gas and liquid phase deoxidizers. The catalyst used in the tests reported here is Ag(1wt%)-γAl2O3.

The effects of fuel properties on diesel engine exhaust emission characteristics are investigated using eleven kinds of fuel with varying levels of sulfur and aromatic contents. Exhaust emissions from three engines are measured over the new Japanese 13-mode cycle as well as the U.S. transient test procedure. Engine test results show that reducing the fuel sulfur content decreases particulate levels. This effect is more pronounced for engines that emit more SOF. Enriching the aromatic content with dicyclic and other polycyclic compounds increases particulate, NOx, CO, and THC emissions. This particulate increase is due to the increase of SOF. Accordingly, low sulfur fuel should be produced without increasing the aromatic content, otherwise the SOF increase will offset the particulate reduction effect of the low sulfur fuel.

As a CO2 removing and recovering technology, the solid amine utilized as a vacuum desorbing type was developed. The evaluation experiments to measure fundamental characteristics of this material was conducted using the dry air and as the results, the high adsorbing rate, 10 wt% for short period and 7 wt% for long period was obtained and also 7 wt% of adsorbing rate can be expected for the operation of desorption temperature of 80 °C. High accuracy thermobalance device so called thermogravimetric analyzer was utilized to measure adsorption and desorption values of CO2.

HCCI (Homogeneous Charge Compression Ignition) combustion results in very low NOx emissions, however, it is not without problems. One of them is that the heavy load operation range is limited by knock, due to an exceptionally high heat release rate. Knock increases the heat loss to the cylinder walls and piston, reducing thermal efficiency. To help solve these problems, direct (in-cylinder) water injection has been suggested to lower the local temperatures that seem to cause knock in HCCI. Water injection was adapted in an HCCI engine fueled with DME and Propane. Results showed that the indicated thermal efficiency was improved by about 2% (λ = 3.0, NA), and the operation range was expanded from 460kPa to 700kPa (NA) maintaining a low NOx level.

According to previous papers on the combustion process in LHR diesel engines the combustion seems to deteriorate in LHR diesel engines. However it has been unclear whether this was caused by the high temperature gas or high temperature combustion chamber walls. This study was intended to investigate the effect of gas temperature on the rate of heat release through the heat release analysis and other measurements using a rapid compression-expansion machine. Experiments conducted at high gas temperatures which was achieved by the employment of oxygen-argon-helium mixture made it clear that the combustion at a high gas temperature condition deteriorated actually and this was probably due to the poorer mixing rate because of the increase in gas viscosity at a high gas temperature condition.

Smokeless and ultra low NOx combustion without knocking in a dual-fuel diesel engine with induced LPG as the main fuel was established with a uniquely developed piston cavity divided by a lip in the sidewall. A small quantity of diesel fuel was directly injected at early compression stroke into the lower part of the cavity as an ignition source for this confined area, and this suppressed explosively rapid combustion just after ignition and spark-knock like combustion at later stage. A combination of the divided cavity, EGR, and intake air throttling was effective to simultaneously eliminate knocking, and reduce THC and NOx significantly.

Nitrogen oxide (NOx) and particulate matter (PM) emissions of diesel vehicles are regarded as a source of air pollution, and there is a global trend to enforce more stringent regulations on these exhaust gas constituents in the early years of the 21st century. On the other hand, the excellent thermal efficiency of diesel engines is certainly a welcome attribute from the standpoints of conserving energy and curbing global warming. Recently, many research institutes around the world have been using high-efficiency direct-injection (DI) diesel engines to research emission control technologies. The authors have also been engaged in such research [1,2]. As a result of this work, we have developed a new combustion concept, called Modulated Kinetics (MK), that reduces NOx and smoke simultaneously due to low-temperature and premixed combustion characteristics, respectively, without increasing fuel consumption [3,4].

A new multidimensional calculation method has been developed to simulate the warm-up characteristics of close-coupled catalytic converter systems. First, a one-dimensional gas exchange simulation and a three-dimensional exhaust gas flow calculation are combined to simulate the pulsation gas flow caused by the gas exchange process. The gas flow calculation and a heat transfer calculation are then combined to simulate heat transfer in the exhaust manifold and the catalyst honeycomb under pulsation flow. The predicted warm-up characteristics of the systems examined agreed well with the experimental data. In this simulation, CPU time was reduced greatly through the use of new calculation methods. Finally, the warm-up process of close-coupled catalysts is analyzed in detail with this simulation method. The design requirements for improving warm-up characteristics have been made clear.

A low-temperature, premixed combustion concept, called Modulated Kinetics (MK) combustion, has been developed that reduces emissions of nitrogen oxide (NOx) and smoke simultaneously. This new combustion concept requires heavy exhaust gas recirculation (EGR) to reduce the NOx emission and combustion noise. However, there is an interaction between the effects of controlling exhaust gas recirculation (EGR) and the variable geometry turbocharger (VGT). This makes controlling both the EGR rate and air mass flow rate more difficult under transient operating conditions. Therefore, the authors investigated a cooperative control of EGR and VGT in an effort to control the accuracy of both the EGR rate and the air mass flow rate. This paper presents an approach through the application of a control system CAD program and rapid prototyping tools to improve transient operating states by referring to a model-based EGR and VGT control algorithm.

As a research of low temperature regeneration of DPF, combustion mechanism of diesel particulate matter (PM) trapped in DPF was investigated. For the assumption of PM combustion mechanism, the relationship between PM combustion characteristics and the physical properties of PM particles was investigated by using thermal and spectroscopic analysis methods. Experimental PM samples were produced under typical engine operating conditions using three representative fuels, two commercial diesel fuels containing aromatics (JIS-2 and Class 1) and a paraffin fuel that was prepared in a gas-to-liquid (GTL) process and did not contain any aromatics. Based upon these characteristics and combustion test results of the PM samples, a mechanism of the PM combustion was assumed. And the crystallinity of PM particles and existence of some surface functional groups containing oxygen are thought to be the important factors to lower the temperature of PM combustion., independent of the fuel type.

Thermodynamic characteristics of premixed compression ignition combustions were clarified quantitatively by heat balance estimation. Heat balance was calculated from temperature, mole fractions of intake and exhaust gases, mass and properties of fuels. Heat balance estimation was conducted for three types of combustion; a conventional diesel combustion, a homogeneous charge compression ignition (HCCI) combustion; fuel is provided and mixed with air in an intake pipe in this case, and an extremely early injection type PREmixed lean DIesel Combustion (PREDIC). The results show that EGR should be applied for premixed compression ignition combustion to complete combustion at lower load conditions and to control ignition timing at higher load conditions. With an application of EGR, both HCCI and PREDIC showed low heat loss characteristics at lower load conditions up to 1/2 load.

Three-dimensional computation has been applied to analyze combustion and emission characteristics in direct-injection diesel engines. A computational code called TurboKIVA was used to investigate the effects of the swirl ratio, one of the fundamental factors related to combustion control, on combustion characteristics and NOx and soot emissions. The code was first modified to calculate soot formation and oxidation and the precise behavior of fuel drops on the combustion chamber wall. As a result of improving calculation accuracy, good agreement was obtained between the measured and predicted pressure, heat release rate and NOx and soot emissions. Using this modified version of TurboKIVA, the effects of the swirl ratio on NOx and soot emissions were investigated. The computational results showed that soot emissions were reduced with a higher swirl ratio. However, a further increase in the swirl ratio produced greater soot emissions.

Diesel combustion and exhaust gas emissions under transient operation (when fuel amounts abruptly increased) were investigated under a wide range of operating conditions with a newly developed gas sampling system. The relation between gas emissions and piston wall temperatures was also investigated. The results indicated that after the start of acceleration NOx, THC and smoke showed transient behaviors before reaching the steady state condition. Of the three gases, THC was most affected by piston wall temperature; its concentration decreased as the wall temperature increased throughout the acceleration except immediately after the start of acceleration. The number of cycles, at which gas concentrations reach the steady-state value after the start of acceleration, were about 1.2 times the cycle constant of the piston wall temperature for THC, and 2.3 times for smoke.

Experimental investigations were conducted with a direct-injection diesel engine to improve exhaust emission, especially nitrogen oxide (NOx) and particulate matter (PM), without increasing fuel consumption. As a result of this work, a new combustion concept, called Modulated Kinetics (MK) combustion, has been developed that reduces NOx and smoke simultaneously through low-temperature combustion and premixed combustion, respectively. The characteristics of a new combustion concept were investigated using a single cylinder DI diesel engine and combustion photographs. The low compression ratio, EGR cooling and high injection pressure was applied with a multi-cylinder test engine to accomplish premixed combustion at high load region. Combustion chamber specifications have been optimized to avoid the increase of cold-start HC emissions due to a low compression ratio.