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There have been strong demands recently for reductions in the fuel consumption and exhaust emissions of diesel engines from the standpoints of conserving energy and curbing global warming. A great deal of research is being done on new emission control technologies using direct-injection (DI) diesel engines that provide high thermal efficiency. This work includes dramatic improvements in the combustion process. The authors have developed a new combustion concept called Modulated Kinetics (MK), which reduces smoke and NOx levels simultaneously by reconciling low-temperature combustion with pre-mixed combustion [1, 2]. At present, research is under way on the second generation of MK combustion with the aim of improving emission performance further and achieving higher thermal efficiency [3]. Reducing heat rejection in the combustion chamber is effective in improving the thermal efficiency of DI diesel engines as well as that of MK combustion.

To reduce NOx emissions from diesel engines, the urea-SCR (selective catalytic reduction) system has been introduced commercially. In urea-SCR, the freezing point of the urea aqueous solution, the deoxidizer, is −11°C, and the handling of the deoxidizer under cold weather conditions is a problem. Further, the ammonia escape from the catalyst and the generation of N2O emissions are also problems. To overcome these disadvantages of the urea-SCR system, the addition of a hydrocarbon deoxidizer has attracted attention. In this paper, a micro-reactor SCR system was developed and attached to the exhaust pipe of a single cylinder diesel engine. With the micro-reactor, the catalyst temperature, quantity of deoxidizer, and the space velocity can be controlled, and it is possible to use it with gas and liquid phase deoxidizers. The catalyst used in the tests reported here is Ag(1wt%)-γAl2O3.

The effects of fuel properties on diesel engine exhaust emission characteristics are investigated using eleven kinds of fuel with varying levels of sulfur and aromatic contents. Exhaust emissions from three engines are measured over the new Japanese 13-mode cycle as well as the U.S. transient test procedure. Engine test results show that reducing the fuel sulfur content decreases particulate levels. This effect is more pronounced for engines that emit more SOF. Enriching the aromatic content with dicyclic and other polycyclic compounds increases particulate, NOx, CO, and THC emissions. This particulate increase is due to the increase of SOF. Accordingly, low sulfur fuel should be produced without increasing the aromatic content, otherwise the SOF increase will offset the particulate reduction effect of the low sulfur fuel.

HCCI (Homogeneous Charge Compression Ignition) combustion results in very low NOx emissions, however, it is not without problems. One of them is that the heavy load operation range is limited by knock, due to an exceptionally high heat release rate. Knock increases the heat loss to the cylinder walls and piston, reducing thermal efficiency. To help solve these problems, direct (in-cylinder) water injection has been suggested to lower the local temperatures that seem to cause knock in HCCI. Water injection was adapted in an HCCI engine fueled with DME and Propane. Results showed that the indicated thermal efficiency was improved by about 2% (λ = 3.0, NA), and the operation range was expanded from 460kPa to 700kPa (NA) maintaining a low NOx level.

According to previous papers on the combustion process in LHR diesel engines the combustion seems to deteriorate in LHR diesel engines. However it has been unclear whether this was caused by the high temperature gas or high temperature combustion chamber walls. This study was intended to investigate the effect of gas temperature on the rate of heat release through the heat release analysis and other measurements using a rapid compression-expansion machine. Experiments conducted at high gas temperatures which was achieved by the employment of oxygen-argon-helium mixture made it clear that the combustion at a high gas temperature condition deteriorated actually and this was probably due to the poorer mixing rate because of the increase in gas viscosity at a high gas temperature condition.

Smokeless and ultra low NOx combustion without knocking in a dual-fuel diesel engine with induced LPG as the main fuel was established with a uniquely developed piston cavity divided by a lip in the sidewall. A small quantity of diesel fuel was directly injected at early compression stroke into the lower part of the cavity as an ignition source for this confined area, and this suppressed explosively rapid combustion just after ignition and spark-knock like combustion at later stage. A combination of the divided cavity, EGR, and intake air throttling was effective to simultaneously eliminate knocking, and reduce THC and NOx significantly.

Nitrogen oxide (NOx) and particulate matter (PM) emissions of diesel vehicles are regarded as a source of air pollution, and there is a global trend to enforce more stringent regulations on these exhaust gas constituents in the early years of the 21st century. On the other hand, the excellent thermal efficiency of diesel engines is certainly a welcome attribute from the standpoints of conserving energy and curbing global warming. Recently, many research institutes around the world have been using high-efficiency direct-injection (DI) diesel engines to research emission control technologies. The authors have also been engaged in such research [1,2]. As a result of this work, we have developed a new combustion concept, called Modulated Kinetics (MK), that reduces NOx and smoke simultaneously due to low-temperature and premixed combustion characteristics, respectively, without increasing fuel consumption [3,4].

Thermodynamic characteristics of premixed compression ignition combustions were clarified quantitatively by heat balance estimation. Heat balance was calculated from temperature, mole fractions of intake and exhaust gases, mass and properties of fuels. Heat balance estimation was conducted for three types of combustion; a conventional diesel combustion, a homogeneous charge compression ignition (HCCI) combustion; fuel is provided and mixed with air in an intake pipe in this case, and an extremely early injection type PREmixed lean DIesel Combustion (PREDIC). The results show that EGR should be applied for premixed compression ignition combustion to complete combustion at lower load conditions and to control ignition timing at higher load conditions. With an application of EGR, both HCCI and PREDIC showed low heat loss characteristics at lower load conditions up to 1/2 load.

Diesel combustion and exhaust gas emissions under transient operation (when fuel amounts abruptly increased) were investigated under a wide range of operating conditions with a newly developed gas sampling system. The relation between gas emissions and piston wall temperatures was also investigated. The results indicated that after the start of acceleration NOx, THC and smoke showed transient behaviors before reaching the steady state condition. Of the three gases, THC was most affected by piston wall temperature; its concentration decreased as the wall temperature increased throughout the acceleration except immediately after the start of acceleration. The number of cycles, at which gas concentrations reach the steady-state value after the start of acceleration, were about 1.2 times the cycle constant of the piston wall temperature for THC, and 2.3 times for smoke.