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The effects of injector deposits, combustion chamber deposits (CCD), and intake valve deposits (IVD) on exhaust emissions, fuel economy and engine performance have long been recognized in engine and fuel/detergent design. Because important elements of the engine design such as injector position, exhaust gas recirculation (EGR) ratio, and air fuel ratio (AFR) differ from those in port fuel injection (PFI) engines, direct injection spark-ignition (DISI) engines require specific evaluation methods. However, little data is available regarding engine deposits in the more recently produced DISI engines.

A fundamental understanding of the relationship between chemical composition and combustion quality may provide an improved means of assessing fuel combustion characteristics. As such, a fuel parameter based on the average molecular structure of multi-component fuels, including petroleum-derived fuels and alternative fuels such as bio-fuel, is applied to predict both ignition and anti-knock quality. This parameter is derived from proton nuclear magnetic resonance (1H-NMR) analysis indicating hydrogen type distribution of fuel molecules. The predicted cetane number (PCN) calculated by the equation developed with 1H-NMR in this study shows a good correlation to the cetane number for a wide range of fuels.

Performances of gasoline engine fueled by gasoline into cylinder and pure hydrogen or simulated reformer gas (H2, CO, CO2, and CH4) into intake manifold were evaluated in view of improvement of thermal efficiency of spark ignition engine. Commercial spark ignition direct injection gasoline engine was modified to install injection system of commercial CNG vehicle. Test engine can be controlled by homogeneous and stratified charged combustion for gasoline. Thermal efficiency of the engine operated with gasoline and hydrogen or reformer gas is much higher than that with gasoline under low and mid load conditions. Especially the improvement of thermal efficiency with gasoline and hydrogen on lean burn condition is less than 40% that with gasoline on stichometric condition under low load condition. The operating range of the engine operated with hydrogen is limited due to knocking, but the range is extended by the addition of gasoline.

Characteristics of diesel combustion with low cetane number fuels with similar distillation temperatures to ordinary diesel fuel, including fuels with cetane number 32 and 39 (LC32, LC39), and a blend of n-cetane (n-hexadecane) and iso-cetane (2, 2, 4, 4, 6, 8, 8-heptamethylnonane) with cetane number 32 (CN32), were investigated. The effects of cooled exhaust gas recirculation (EGR) and pilot injection on characteristics of combustion and exhaust gas emissions with these fuels were examined in a naturally aspirated, single cylinder, diesel engine equipped with a common-rail fuel injection system. Even with the low cetane number fuels, quiet combustion with low levels of exhaust gas emissions comparable to ordinary diesel fuel was established by suitable control of intake oxygen levels and pilot injections.

The addition of soybean methyl ester (SME) to diesel fuel has significantly reduced HC and PM emissions, but it increases the NOx emission slightly when measured with exhaust emission evaluation mode for heavy-duty DI diesel engines or D-13 mode in Japan. Also, under partial load conditions, the SME addition increases the PM emission due to an increase in the SOF emission. However, the addition of lighter fractions or kerosene to diesel fuel reduces NOx and PM emissions but increases HC and CO emissions measured by D-13 mode. In addition, under full load conditions, the lighter fuel seldom reduces PM emission. Therefore, the exhaust emissions emitted from the blends of SME, kerosene, and cetane improver to low sulfur diesel fuel are evaluated using the latest DI diesel engine with a turbo-charger and inter-cooler. The clean fuel reduces over 20% of PM under a wide range of engine conditions including D-13 mode without an increase in NOx, HC, and CO emissions.

Crosscheck tests of fast electrical mobility spectrometers, Differential Mobility Spectroscopy (DMS) and Engine Exhaust Particle Sizer(EEPS), were conducted to evaluate the accuracy of fine particle measurement. Two kinds of particles were used as test particles for the crosscheck test of instruments: particles emitted from diesel vehicles and diluted in a full dilution tunnel, and particles generated by CAST. In the steady state tests, it was confirmed that the average concentration of each instrument was within the range of ±2σ from the average concentration of all the same type of instruments. In the transient tests, it is verified that the instruments have almost equal sensitivity. For application of the fast electrical mobility spectrometers to evaluation of particle number and size distributions, it is essential to develop a calibration method using reference particle counters and sizers (CPC, SMPS, etc.) and maintenance methods appropriate for each model.

Newly designed laboratory measurement system, which reproduces particle number size distributions of both nuclei and accumulation mode particles in exhaust emissions, was developed. It enables continuous measurement of nano particle emissions in the size range between 5 and 1000 nm. Evaluations of particle number size distributions were conducted for diesel vehicles with a variety of emission aftertreatment devices and for gasoline vehicles with different combustion systems. For diesel vehicles, Diesel Oxidation Catalyst (DOC), urea-Selective Catalytic Reduction (urea-SCR) system and catalyzed Diesel Particulate Filter (DPF) were evaluated. For gasoline vehicles, Lean-burn Direct Injection Spark Ignition (DISI), Stoichiometric DISI and Multi Point Injection (MPI) were evaluated. Japanese latest transient test cycles were used for the evaluation: JE05 mode driving cycle for heavy duty vehicles and JC08 mode driving cycle for light duty vehicles.

Bioethanol is being used as an alternative fuel throughout the world based on considerations of reduction of CO2 emissions and sustainability. It is widely known that ethanol has an advantage of high anti-knock quality. In order to use the ethanol in ethanol-blended gasoline to control knocking, the research discussed in this paper sought to develop a fuel separation system that would separate ethanol-blended gasoline into a high-octane-number fuel (high-ethanol-concentration fuel) and a low-octane-number fuel (low-ethanol-concentration fuel) in the vehicle. The research developed a small fuel separation system, and employed a layout in which the system was fitted in the fuel tank based on considerations of reducing the effect on cabin space and maintaining safety in the event of a collision. The total volume of the components fitted in the fuel tank is 6.6 liters.

Time series analysis of diesel exhaust gas emissions under transient operation was carried out using a uniquely developed gas sampling system to efficiently collect all exhaust gas throughout transient cycles. The effects of fuel properties and other engine operation parameters on the exhaust emissions under transient runs when fuel amounts abruptly increase were analyzed. The results showed that THC increased abruptly to 2 or 6 times the final steady-state concentration immediately after the start of acceleration and then decreased to the steady-state values after 70∼200 cycles. At acceleration, NOx increased abruptly to about 80 % of the final NOx concentration, and then increased gradually to reach the final values after 60∼500 cycles. The behaviors of THC and NOx during transient operation can be described by exponential functions of the elapsed cycle numbers and the final emission concentrations.

Diesel combustion and exhaust gas emissions under transient operation (when fuel amounts abruptly increased) were investigated under a wide range of operating conditions with a newly developed gas sampling system. The relation between gas emissions and piston wall temperatures was also investigated. The results indicated that after the start of acceleration NOx, THC and smoke showed transient behaviors before reaching the steady state condition. Of the three gases, THC was most affected by piston wall temperature; its concentration decreased as the wall temperature increased throughout the acceleration except immediately after the start of acceleration. The number of cycles, at which gas concentrations reach the steady-state value after the start of acceleration, were about 1.2 times the cycle constant of the piston wall temperature for THC, and 2.3 times for smoke.

Amidst the rising demand to reduce CO2 and other greenhouse gas emissions in recent years, gasoline homogeneous-charge compression ignition (HCCI) has gained attention as a technology that achieves both low NOx emissions and high thermal efficiency by means of lean combustion. However, gasoline HCCI has low robustness toward intracylinder temperature variations, therefore the problems of knocking and misfiring tend to occur during transient operation. The authors verified the transient operation control of HCCI by using a 4-stroke natural aspiration (NA) gasoline engine provided with direct injection (DI) and a variable valve timing and a lift electronic control system (VTEC) for intake air and exhaust optimized for HCCI combustion. This report describes stoichiometry spark ignition (SI) to which external exhaust gas recirculation (EGR) was introduced, HCCI ignition switch control, and changes in the load and number of engine revolutions in the HCCI region.

In order to clarify future automobile technologies and fuel qualities to improve air quality, second phase of Japan Clean Air Program (JCAPII) had been conducted from 2002 to 2007. Predicting improvement in air quality that might be attained by introducing new emission control technologies and determining fuel qualities required for the technologies is one of the main issues of this program. Unregulated material WG of JCAPII had studied unregulated emissions from gasoline and diesel engines. Eight gaseous hydrocarbons (HC), four Aldehydes and three polycyclic aromatic hydrocarbons (PAHs) were evaluated as unregulated emissions. Specifically, emissions of the following components were measured: 1,3-Butadiene, Benzene, Toluene, Xylene, Ethylbenzene, 1,3,5-Trimethyl-benzene, n-Hexane, Styrene as gaseous HCs, Formaldehyde, Acetaldehyde, Acrolein, Benzaldehyde as Aldehydes, and Benzo(a)pyrene, Benzo(b)fluoranthene, Benzo(k)fluoranthene as PAHs.

Diesel-like combustion of an emulsified blend of water and diesel fuel in a constant volume chamber vessel was visualized with high speed color video, further analyzing with a 2-D two color method and shadowgraph images. When the temperature at the fuel injection is 900 K, here while the combustion with unblended diesel fuel in the vessel is similar to ordinary diesel combustion with diffusive combustion, combustion with the emulsified fuel is similar to premixed diesel combustion with a large premixed combustion and very little diffusive combustion. With the emulsified fuel the flame luminosity and temperature are lower, the luminous flame and high temperature regions are smaller, and the duration of the luminous flame is shorter than with diesel fuel. This is due to promotion of premixing with increases in the ignition delay and decreases in the combustion temperature with the water vaporization.