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Automotive engines produce pollutant species which has the potential to damage human health as well as the environment. The toxicity potential of these species depends on the concentration, route, and exposure time. Toxicity studies are required in the current scenario due to increased pollution levels by vehicles used for transportation. This study is a review focused on the toxicity analysis of particulate, elemental (particle associated as soot), and organic carbon (organic fraction, PAHs) emission from the internal combustion engine with conventional and alternative fuels like biodiesel and alcohol. The study is focused on the formation, characterization, and quantification of particulate matter, elemental and organic carbon, and their effect on human health. The other part of the study is focused on mutagenicity (mutation in DNA) and cytotoxicity (cell toxicity) of the particulate emitted from the engines.

Engine design and selection of fuels for automotive applications are required to minimize noise and exhaust emissions without compromising fuel economy. The knocking combustion investigation is essential as it directly affects the performance and durability as well as the thermal efficiency of the engine. Several fuel additives were suggested in the previous studies to mitigate the knocking combustion in spark ignition (SI) engines. The present study reviews the effect of antiknock fuel additives such as ethanol, methanol, prenol, n-butanol, furan mixtures, etc., on knocking behavior in SI engines. Additionally, this paper aims to present a systematic review of the studies conducted to investigate the effect of EGR on the knocking in SI engines. The EGR is often considered an effective means to suppress knocking in SI engines. The thermal effect of EGR in controlling the knocking is well known as EGR affects the temperature and pressure history of the combustion chamber.

Cyclic variations are inherent in the combustion of internal combustion engines. However, extreme cyclic combustion variations limit the operation of spark-ignition (SI) engines, particularly at highly lean and diluted charge operation. Lean charge operation is desired due to its expected benefits in fuel efficiency and engine-out NOx and HC emissions. Studies suggested the existence of the low-dimensional deterministic nature of cyclic variations, which is essential from the perspective of designing a high-frequency controller. The lean limit of a SI engine operation may be extended by controlling the deterministic component of cyclic variations to meet the future strict emissions and fuel economy regulations. This paper presents a review of the evolution of the experimental and analytical understanding of cyclic combustion variations of spark-ignition engines.

The potential for simultaneous reduction of soot and NOx emissions and higher fuel conversion efficiency has already been demonstrated for reactivity-controlled compression ignition (RCCI) engines. The RCCI engine has a relatively higher peak pressure rise rate (PPRR) and cyclic variations compared to the conventional diesel engine. The upper and lower operating load boundaries of the RCCI engine are restricted by higher PPRR and cyclic variations, respectively. The cyclic variations in the air-fuel ratio are one of the main factors which govern the variations in combustion parameters. The cyclic variations in combustion need to be controlled for stable engine operation. The present study estimates the cyclic air-fuel ratio from the measured in-cylinder pressure data for the RCCI engine. The RCCI experiments are performed on a modified single-cylinder compression ignition (CI) engine equipped with a development ECU.

Homogeneous charge compression ignition (HCCI) is an advanced combustion concept that is developed as an alternative to diesel engines with higher thermal efficiency along with ultralow NOx and PM emissions. To study the performance of this novel technique, experiments were performed in a two cylinder engine, in which one cylinder is modified to operate in HCCI mode while other cylinder operates in conventional CI mode. The quality of homogeneous mixture of air and fuel is the key feature of HCCI combustion. Low volatility of diesel is a major hurdle in achieving HCCI combustion because it is difficult to make a homogeneous mixture of air and fuel. This problem is resolved by external mixture preparation technique in uses a dedicated diesel vaporizer with an electronic control system. All the injection parameters such as fuel quantity, fuel injection timing, injection delay etc., are controlled by the injection driver circuit.

In this study, macroscopic spray characteristics of Waste cooking oil (WCO), Jatropha oil, Karanja oil based biodiesels and baseline diesel were compared under simulated engine operating condition in a constant volume spray chamber (CVSC). The high pressure and high temperature ambient conditions of a typical diesel engine were simulated in the CVSC by performing pre-ignition before the fuel injection. The spray imaging was conducted under absence of oxygen in order to prevent the fuels from igniting. The ambient pressure and temperature for non-evaporating condition were 3 MPa and 300 K. Meanwhile, the spray tests were performed under the ambient pressure and temperature of 4.17 MPa and 804 K under evaporating condition. The fuels were injected by a common-rail injection system with injection pressure of 80 MPa. High speed Mie-scattering technique was employed to visualize the evaporating sprays.

Premixed charge compression ignition (PCCI) combustion is an advanced combustion technique, which has the potential to be operated by alternative fuels such as alcohols. PCCI combustion emits lower oxides of nitrogen (NOx) and particulate matter (PM) and results thermal efficiency similar to conventional compression ignition (CI) engines. Due to extremely high heat release rate (HRR), PCCI combustion cannot be used at higher engine loads, which make it difficult to be employed in production grade engines. This study focused on development of an advanced combustion engine, which can operate in both combustion modes such as CI combustion as well as PCCI combustion mode. This Hybrid combustion system was controlled by an open engine control unit (ECU), which varied the fuel injection parameters for mode switching between CI and PCCI combustion modes.

Vegetable oils are produced from numerous oil seed crops. While all vegetable oils have high energy content, most require some processing to assure safe use in internal combustion engines. Some of these oils already have been evaluated as substitutes for diesel fuels. However, several operational and durability problems of using straight vegetable oils in diesel engines are reported in the literature, caused by of their higher viscosity and low volatility compared to mineral diesel. In the present research, experiments were designed to study the effect of reducing Jatropha oil's viscosity by blending it with mineral diesel and thereby eliminating the effect of high viscosity and poor volatility on combustion characteristics of the engine. Experimental investigations have been carried out to examine the combustion characteristics of an indirect injection transportation diesel engine running with diesel, and jatropha oil blends with diesel.

The methyl esters of vegetable oils, known as biodiesel are becoming increasingly popular because of their low environmental impact and potential as a green alternative fuel for diesel engine and they would not require significant modification of existing engine hardware. Methyl ester of rice bran oil (ROME) is derived through transesterification process. Previous research has shown that ROME has comparable performance, lower bsfc in comparison to diesel. There was reduction in the emissions of CO, HC, and smoke but NOx emissions increased. Experimental investigations have been carried out to examine the combustion characteristics in a direct injection transportation diesel engine running with diesel, and 20% blend of rice bran methyl ester with diesel.

This study examines the cycle-to-cycle variations (combustion instability) in the dual-fuel stationary compression ignition engine. The variations in the consecutive engine cycles are characterized under different load, gasoline/methanol-diesel premixing ratio (rp) and diesel injection timing (SOI). To investigate the combustion instability in dual-fuel CI-engine, gasoline and methanol are used as a low reactivity fuel (LRF) and is fed in the modified intake manifold during the suction stroke. The tests are performed for different fuel rp using developed port-fuel injector controller in the laboratory. The combustion instability is analyzed using the statistical method and Wavelet Transform (WT). Results indicate that combustion instability is more prone to lower and medium engine load, and variations are significantly higher for the high substitution fraction of LRF. The upper limit of fuel rp is restricted by higher variations in the combustion parameters.

The Homogeneous charge compression ignition (HCCI) is the third alternative for the combustion in the reciprocating engine. HCCI a hybrid of well-known spark ignition (SI) and compression ignition (CI) engine concepts and has potential of combining the best features of both. A two cylinder, four stroke, direct injection diesel engine was modified to operate one cylinder on the compression ignition by detonation of homogeneous mixture of ethanol and air. The homogeneous mixture of the charge is prepared by port injection of ethanol in the preheated Intake air. This study presents results of experimental investigations of HCCI combustion of ethanol at intake air temperature of 120°C and at different air-fuel ratios. In this paper, the combustion parameters, pressure time history, rate of pressure rise, rate of heat release, mean temperature history in the combustion chamber is analyzed and discussed.

Indian Railways have a fleet of high-horsepower diesel-electric locomotives rated at 2310 kW. These high horsepower diesel-electric locomotives have evolved from original design of 1940 kW locomotives. Adoption of new design turbochargers was essential for this upgrading efforts and a series of new design turbochargers were evaluated on the engine test-bed before their use on the diesel locomotives. The objective was to increase engine power output, improve fuel efficiency and limit thermal loading. Test-bed evaluation of different turbochargers was carried out for comparing five different turbochargers. Each turbocharger had different size nozzle ring, diffuser, turbine blade assembly, impeller and inducer. The compressor maps of turbochargers were used to plot the engine load lines and to calculate surge margins. The tests involved measuring critical parameters for various combinations of engine speed and load for every turbocharger.

Adverse health effects of particulate matter (PM) originating from diesel engine exhaust are largely attributed to the complex chemical composition of the exhaust species. This study was set out to characterize particulate emissions from a Euro-III-compliant modern automotive common rail direct injection (CRDI) sports utility vehicle (SUV) diesel engine operated at different loads at rated engine speed (1800 rpm), employing diesel and 20% biodiesel blends (B20) produced from Karanja oil. This study is mainly divided into two main sections, first one includes the gravimetric analysis in order to assess the amount of Benzene Soluble Organic Fraction (BSOF) and trace metals using Inductively Coupled Plasma-Optical Emission Spectrometer (ICPOES). The second section includes real-time measurements for Organic Carbon (OC), Elemental Carbon (EC) and total particle-bound Polycyclic Aromatic Hydrocarbons (PAHs).

Homogeneous charged compression ignition (HCCI) engine is a low-temperature combustion (LTC) strategy with higher thermal efficiency and ultra-low NOx and particulate matter emission. Syngas is a renewable and clean alternative fuel that has gained researchers' interest, and it is one of the alternatives to fossil fuels. Syngas can be a suitable fuel for HCCI Engines due to their characteristics of high flame speed, lower flammability limits, and low auto-ignition temperatures. This paper presents the crank angle-based exergy analysis of syngas fuelled HCCI engines. Energy and exergy analysis is essential for the better performance and utilization of the HCCI engine. The syngas HCCI engine is numerically simulated in this study using a stochastic reactor model (SRM). In SRM models, physical parameters are described by a probability density function (PDF), and these parameters do not vary within the combustion chamber.

Ethanol fuelled homogenous charge compression ignition engine (HCCI) offers a better alternative to tackle the problems of achieving higher engine efficiency and lower emissions. Numerical simulations were carried out for a HCCI engine fueled with ethanol by stochastic reactor model using newly developed reduced ethanol oxidation mechanism consists of 47 species and 272 reactions. Reduced mechanism used in this study is validated by measured engine cylinder pressure curves and measured ignition delays in constant volume reactors in the previous study. Simulations are conducted for engine speeds ranging from 1000 to 3000 rpm at different intake temperatures (range 365-465 K) by varying the air-fuel ratio. Parametric study for combustion and emission characteristics is conducted and engine maps are developed at most efficient inlet temperatures. The HCCI operating range is defined using combustion efficiency (>85%) and maximum pressure rise rate (<5 MPa/ms).

In this study, the influence of fuel premixing ratio (PMR) on the performance, combustion, and emission characteristics of dual-fuel operation in the compression ignition (CI) engine have been investigated. For dual fuel operation in CI-engine, two fuels of different reactivity are utilized in the same combustion cycle. In this study, low reactivity fuels (gasoline/butanol) is injected into the intake manifold, and high reactivity fuel (diesel) is directly injected into the cylinder. To operate the conventional CI engine in dual-fuel mode, the intake manifold of the engine was modified and a solenoid based port fuel injector was installed. A separate port fuel injector controller was used for injecting the gasoline or butanol. Suitable instrumentation was used to measure in-cylinder pressure and exhaust gas emissions. Experiments were performed by maintaining the constant fuel energy at different fuel PMR for different engine loads at constant engine speed.

Increased environmental awareness and depletion of fossil fuel resources are driving industry to develop alternative fuels that are environmentally more acceptable. Vegetable oils are potential alternative fuels. Vegetable oils in India are produced from numerous oil-seed crops. While all vegetable oils have high energy content, most require some processing to ensure safe usage in internal combustion engines. Most detrimental properties of oils are its high viscosity, low volatility and polyunsaturated character. The most widely used method is to convert vegetable oils into biodiesel. Biodiesel fuels are primary esters, which are produced by transesterifcation of vegetable oils. Several vegetable oil esters have been investigated so far in different parts of the world and found suitable to be used in diesel engines.

Emission regulations mandate the measurement of solid particles of size greater than 23 nm according to UNECE informal working group particle measurement protocol (PMP). The volatile particles from the engine exhaust are removed by heating and dilution in a device according to the UNECE PMP program. The analysis of solid particles from diesel engines requires aerosol conditioning systems, which can effectively remove volatile particles/species with minimum solid particle losses. Currently, the regulations only allow using an evaporation tube for the measurement of solid particles. Different laboratories have also demonstrated other alternatives such as thermodenuder and catalytic stripper for measuring the solid ultrafine particles emitted from the diesel engine. This paper reviews the recent literature related to the thermodenuder and catalytic striper’s design and operating characteristics.

This study was set out to characterize particulate emissions from diesel engines in terms of poly aromatic hydrocarbon emissions and Benzene Soluble Organic Fraction. The characteristics of DPM vary with engine operating conditions, quality of fuel and lubricants being used. Hence the diesel exhaust for the purpose of toxicity characterization needs to be studied for Organic Matter in terms of Poly Aromatic Hydrocarbon (PAH) and Benzene Soluble Fraction (BSF). Therefore, the objectives of the present research are to characterize the diesel exhaust particulate matter for the above parameters under varying engine operating conditions/loads. Six PAHs, namely Chrysene, Benzo (k) Flouranthene, Benzo (a) Pyrene, Dibenzo (a, h) Anthracene, Benzo (g,h,i) Perylene and Indenopyrene were analyzed on High Pressure Liquid Chromatography (HPLC). PAH concentrations in the particulates of Mahindra DI engine were affected by engine loads.

This study presents the experimental investigation of performance, combustion, gaseous and nano-particle emission characteristics of conventional compression ignition (CI) engine fueled with neat diesel and butanol/diesel blends. The experiments were conducted for neat diesel, 10%, 20% and 30% butanol/diesel blend on the volume basis at different engine loads. Combustion characteristics were investigated on the basis of in-cylinder pressure measurement and heat release analysis. The in-cylinder combustion pressure traces were recorded for 2000 consecutive engine combustion cycles for computation of heat release and different combustion parameters. Combustion stability analysis is conducted by analyzing the coefficient of variation of in indicated mean effective pressure (IMEP) and total heat release (THR). Wavelet analysis is also used for analyzing the temporal variations in IMEP data series.