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The use of biofilters for the control of air contaminants in Advanced Life Support (ALS) systems is currently being investigated by the Waste Processing and Resource Recovery research team of the New Jersey - NSCORT (NASA Specialized Center of Research and Training). Ammonia (NH3) was selected as a test air contaminant as it presents special challenges to the sustained operation of a biofilter. Ammonia loading to the ALS atmosphere will likely be from waste treatment (biological treatment of human, plant and food wastes) and food processing operations. This NH3 has the potential of causing adverse effects on plant growth and humans.

BIO-Plex is a ground-based test bed currently under development by NASA for testing technologies and practices that may be utilized in future long-term life support missions. All aspects of such an Advanced Life Support (ALS) System must be considered to confidently construct a reliable system, which will not only allow the crew to survive in harsh environments, but allow the crew time to perform meaningful research. Effective handling of solid wastes is a critical aspect of the system, especially when recovery of resources contained in the waste is required. This is particularly important for ALS Systems configurations that include a Biomass Production Chamber. In these cases, significant amounts of inedible biomass waste may be produced, which can ultimately serve as a repository of necessary resources for sustaining life, notably carbon, water, and plant nutrients. Numerous biological and physicochemical solid waste processing options have been considered.

The electrosynthesis of expendable reagents including acids, bases, and oxidants from simple salts or salt mixtures has been demonstrated using a variety of electrochemical cells. A five chambered electrodialytic water splitting (EDWS) cell with bipolar membranes was utilized to efficiently convert sodium sulfate, sodium chloride, potassium nitrate, and potassium chloride to conjugate acids and bases. With the same cell, selective segregation of cations and anions from mixed salt solutions occurred, resulting in relatively pure acids and bases. These results suggest that pure acids and bases can be produced from composite spacecraft brines. Chemical oxidants such as sodium and ammonium persulfate were also synthesized with high current efficiencies by the electrooxidation of salts and acids in a two chambered electrochemical cell.

Distant and/or long-term missions, particularly Mars and lunar bases, will require a high degree of regenerative systems utilization. Bio-regenerative systems inherently lend themselves to integrative application, and can serve multiple processing functions in Advanced Life Support (ALS) systems. Striving for maximal use of bio-regenerative systems can reveal possibilities and relationships difficult to conceptualize within the context of a “unit process” methodology common to physico-chemical (P/C) systems. The required regenerative functions of biomass production and solid, liquid, and air processing are discussed, and a potential integrated ALS system scenario including “soil'based” plant production is developed to illustrate potential ramifications of biological (and P/C) system integration.

Advanced Life Support (ALS) systems designed for long-duration manned space missions, particularly permanent bases on the Moon or Mars, are likely to employ extensive use of regenerative closed loop systems, including the production of higher plants for food. Such systems will produce substantial amounts of inedible plant material in addition to other standard mission wastes. Composting is one of the several methods currently under investigation for waste processing and resource recovery in ALS systems. While composting is a robust microbiological process that can be utilized to treat a variety of organic materials under a wide range of environmental conditions, both feedstock preparation and process control require optimization. For instance, initial waste feedstock composition, carbon to nitrogen ratio (C:N), particle size, and moisture content are critical factors for ensuring optimal processing conditions and maximal rates of degradation.

In this paper we have developed a unique approach to providing the elements required for crop production in a steady-state condition, which is essential for Space habitats. The approach takes into consideration human elemental requirements and crop requirements for healthy growth and develops a method for the calculation of the rates of nutrient uptake for the different elements for different crops. The uptake rates can be used to calculate the rate of nutrient supply required in the hydroponic solution. This approach ensures that crops produced will not have excessive levels of elements that may be harmful to humans. It also provides an opportunity to optimize the processes of crop production and waste processing through highly controlled feed rates.

The growth of Swiss chard in compost, Mars regolith simulant, and mixtures thereof, was studied for application in Advanced Life Support (ALS) systems, particularly Mars/lunar based operations. The purpose was to begin characterizing a sustainable biomass production method based on compost derived from inedible biomass. Compost would serve both as a means of recycling plant nutrients while improving the physical qualities of regolith as a plant growth medium. An outpost’s cropping area could be expanded by blending a minimal amount of compost (scarce, initially imported resource) and a maximal amount of regolith (plentiful local resource), consistent with adequate crop yields. Swiss chard was selected for the study as it is an ALS crop candidate for which there are little data.

This paper presents the results from a joint research initiative between NASA Ames Research Center and Lawrence Berkeley National lab. The objective of the research is to produce activated carbon from life support wastes and to use the activated carbon to adsorb and chemically reduce the NOx and SO2 contained in incinerator flue gas. Inedible biomass waste from food production is the primary waste considered for conversion to activated carbon. Results to date show adsorption of both NOx and SO2 in activated carbon made from biomass. Conversion of adsorbed NOx to nitrogen has also been observed.

NASA Ames Research Center and Lawrence Berkeley National lab have completed a three-year joint NRA research project on the use of waste biomass to make a gaseous contaminant removal system. The objective of the research was to produce activated carbon from life support wastes and to use the activated carbon to adsorb and remove incineration flue gas contaminants such as NOx. Inedible biomass waste from food production was the primary waste considered for conversion to activated carbon. Previous research at NASA Ames has demonstrated the adsorption of both NOx and SO2 on activated carbon made from biomass and the subsequent conversion of adsorbed NOx to nitrogen and SO2 to sulfur. This paper presents the results testing the whole process system consisting of making, using, and regenerating activated carbon with relevant feed from an actual incinerator. Factors regarding carbon preparation, adsorption and regeneration are addressed.

Since the mid 1980s, NASA has developed advanced waste management technologies that collect and process waste. These technologies include incineration, hydrothermal oxidation, pyrolysis, electrochemical oxidation, activated carbon production, brine dewatering, slurry bioreactor oxidation, composting, NOx control, compaction, and waste collection. Some of these technologies recover resources such as water, oxygen, nitrogen, carbon dioxide, carbon, fuels, and nutrients. Other technologies such as the Waste Collection System (WCS - the commode) collect waste for storage or processing. The need for waste processing varies greatly depending upon the mission scenario. This paper reviews the waste management technology development activities conducted by NASA since the mid 1980s and explores the drivers that determine the application of these technologies to future missions.