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Abstract The ASTM D130 was first issued in 1922 as a tentative standard for the detection of corrosive sulfur in gasoline. A clean copper strip was immersed in a sample of gasoline for three hours at 50°C with any corrosion or discoloration taken to indicate the presence of corrosive sulfur. Since that time, the method has undergone many revisions and has been applied to many petroleum products. Today, the ASTM D130 standard is the leading method used to determine the corrosiveness of various fuels, lubricants, and other hydrocarbon-based solutions to copper. The end-of-test strips are ranked using the ASTM Copper Strip Corrosion Standard Adjunct, a colored reproduction of copper strips characteristic of various degrees of sulfur-induced tarnish and corrosion, first introduced in 1954. This pragmatic approach to assessing potential corrosion concerns with copper hardware has served various industries well for a century.

1 An all fiber-optic sensor has been developed to measure H2O mole fraction and gas temperature in an HCCI engine. This absorption-spectroscopy-based sensor utilizes a broad wavelength (1320 to 1380 nm) source (supercontinua generated by a microchip laser) and a series of fiber Bragg gratings (19 gratings centered on unique water absorption peaks) to track the formation and temperature of combustion water vapor. The spectral coverage of the system promises improved measurement accuracy over two-line diode-laser based systems. Meanwhile, the simplicity of the fiber Bragg grating chromatic dispersion approach significantly reduces the data reduction time and cost relative to previous supercontinuum-based sensors. The data provided by the system is expected to enhance studies of the chemical kinetics which govern HCCI ignition as well as HCCI modeling efforts.

This paper deals with some recent advances in the field of 1D fluid dynamic modeling of unsteady reacting flows in complex s.i. engine pipe-systems, involving a catalytic converter. In particular, a numerical simulation code has been developed to allow the simulation of chemical reactions occurring in the catalyst, in order to predict the chemical specie concentration in the exhaust gas from the cylinder to the tailpipe outlet, passing through the catalytic converter. The composition of the exhaust gas, discharged by the cylinder and then flowing towards the converter, is calculated by means of a thermodynamic two-zone combustion model, including emission sub-models. The catalytic converter can be simulated by means of a 1D fluid dynamic and chemical approach, considering the laminar flow in each tiny channel of the substrate.

Urea-selective catalytic reduction (SCR) catalysts are the leading aftertreatment technology for diesel engines, but there are major challenges associated with meeting future NOx emission standards, especially under transient drive cycle conditions that include large swings in exhaust temperatures. Here we present a simplified, transient, one-dimensional integral model of NOx reduction by NH₃ on a commercial small-pore Cu-zeolite urea-SCR catalyst for which detailed kinetic parameters have not been published. The model was developed and validated using data acquired from bench reactor experiments on a monolith core, following a transient SCR reactor protocol. The protocol incorporates NH₃ storage, NH₃ oxidation, NO oxidation and three global SCR reactions under isothermal conditions, at three space velocities and at three NH₃/NOx ratios.

In this work a detailed model to simulate the transient behavior of catalytic converters is presented. The model is able to predict the unsteady and reacting flows in the exhaust ducts, by solving the system of conservation equations of mass, momentum, energy and transport of reacting chemical species. The en-gine and the intake system have not been included in the simulation, imposing the measured values of mass flow, gas temperature and chemical composition as a boundary condition at the inlet of the exhaust system. A detailed analysis of the diffusion stage triggering is proposed along with simplifications of the physics, finalized to the reduction of the calculation time. Submodels for water condensation and its following evaporation on the monolith surface have been taken into account as well as oxygen storage promoted by ceria oxides.

This work describes an experimental and numerical investigation of the thermal transient of i.c. engine exhaust systems. A prototype of exhaust system has been investigated during a NEDC cycle in two different configurations. Firstly an uncoated catalyst has been adopted to consider only the effect of the gas-wall heat transfer. The measurements have been repeated on the same exhaust system equipped with a coated catalyst to point out the contribution of the chemical reactions to the thermal transient of the system. The measured values have been compared to the predicted results carried out with a 1D thermo fluid dynamic code, developed in-house to account for the thermal transient of the system and the chemical reactions occurring in the catalyst.

This paper describes some recent advances of the research work concerning the 1D fluid dynamic modeling of unsteady reacting flows in s.i. engine pipe-systems, including pre-catalysts and main catalysts. The numerical model GASDYN developed in previous work has been further enhanced to enable the simulation of the catalyst. The main chemical reactions occurring in the wash-coat have been accounted in the model, considering the mass transfer between gas and solid phase. The oxidation of CO, C3H6, C3H8, H2 and reduction of NO, the steam-reforming reactions of C3H6, C3H8, the water-gas shift reaction of CO have been considered. Moreover, an oxygen-storage sub-model has been introduced, to account for the behavior of Cerium oxides. A detailed thermal model of the converter takes into account the heat released by the exothermic reactions as a source term in the heat transfer equations. The influence of the insulating mat is accounted.

Although in-cylinder optical diagnostics have provided significant understanding of conventional diesel combustion, most alternative combustion strategies have not yet been explored to the same extent. In an effort to build the knowledge base for alternative low-temperature combustion strategies, this paper presents a comparison of three alternative low-temperature combustion strategies to two high-temperature conventional diesel combustion conditions. The baseline conditions, representative of conventional high-temperature diesel combustion, have either a short or a long ignition delay. The other three conditions are representative of some alternative combustion strategies, employing significant charge-gas dilution along with either early or late fuel injection, or a combination of both (double-injection).

Cross-sectional distributions of the liquid phase temperatures in fuel sprays were measured using a laser-induced fluorescence technique. The liquid fuel (n-hexadecane or squalane) was doped with pyrene(C16H10). The fluorescence intensity ratios of the pyrene monomer and excimer emissions has temperature dependence, and were used to determine the liquid phase temperatures in the fuel sprays. The measurements were performed on two kinds of sprays. One was performed on pre-heated fuel sprays injected into surrounding gas at atmospheric conditions. The other was performed on fuel sprays exposed to hot gas flow. The spray was excited by laser radiation at 266nm, and the resulting fluorescence was imaged by an intensified CCD camera. The cross-sectional distribution of the liquid phase temperature was estimated from the fluorescence image by the temperature dependence of the intensity ratio.

This paper describes the engineering, manufacturing and integration necessary to produce the Corvette's first ever all-aluminum spaceframe (see Figure 1). The engineering and manufacturing of the spaceframe was a joint venture between General Motors and suppliers ALCOA (Aluminum Company of America) and Dana Corporation. ALCOA led the initial design of the spaceframe; Dana Corp led the manufacturing; General Motors' Engineering and Manufacturing groups led the integration of the assembly. The aluminum spaceframe design is modeled after the baseline steel structure of the Corvette coupe. The aluminum spaceframe reduces 140 lbs from the steel baseline and enters the plant at 285 lbs. This frame allows the 2006 Corvette Z06 to enter the market at a 3100 lbs curb weight. Aluminum casting, extruding, stamping, hydroforming, laser welding, Metal Inert Gas (MIG) welding, Self Pierce Riveting (SPR), and full spaceframe machining make up the main technologies used to produce this spaceframe.

Various techniques are constantly being devised to accelerate model generation leading to shorter product development cycle. This work proposes and implements a reduced synthetic gas bench (SGB) test protocol for a commercial Pt-Pd diesel oxidation catalyst (DOC) that can be used to develop global reaction kinetics. The kinetics thus developed were implemented in a 1D model to predict DOC emissions accurately over a wide operating window. Hydrocarbons (HCs) in the exhaust were categorized as Propylene (C3H6) representing partially oxidized hydrocarbons and n-Decane (C10H22) representing unburnt fuel. Test protocols were defined using the order of inhibition of the various species present in the exhaust, namely, CO, NOx (NO+NO2) and HC for the specific reaction under consideration. The oxidation reactions for CO and HCs were found to be inhibited competitively by CO and HCs; both the NOx species inhibited these reactions to the same extent.

On January 14, 2004 President George W Bush outlined a new vision for NASA that has humans venturing back to the moon by 2020. With this ambitious goal, new tools and models have been developed to help define and predict the amount of space radiation astronauts will be exposed to during transit and habitation on the moon. A representative scenario is used that includes a trajectory from LEO to a Lunar Base, and simplified CAD models for the transit and habitat structures. For this study galactic cosmic rays, solar proton events, and trapped electron and proton environments are simulated using new dynamic environment models to generate energetic electron, and light and heavy ion fluences. Detailed calculations are presented to assess the human exposure for transit segments and surface stays.

Growing interest in pollutant emission reduction has increased the importance of numerical simulations of spark ignition as a first step in IC engine combustion. In this work, we present simulations involving the coupling of flow, chemical reactions and molecular transport with the discharge processes. The main focus hereby is to investigate the early stages of the formation of a flame kernel in a two-dimensional, cylindrical geometry with electrodes. The computational results shown here include the initial shock-determined phase after the breakdown of the channel, but also the transition to flame propagation for a methane-air mixture.

A lightning mapping system has been developed that locates the sources of VHF radiation from lightning discharges in three spatial dimensions and time. The system consists of several VHF receivers distributed over an area of about 100 km diameter. The system locates VHF radiation sources over the array with an accuracy of about 100 m. The system locates sources out to 250 km from the center of the array with reduced accuracy. The observations are found to reflect the basic charge structure of electrified storms.

A compound-laser welding method has been developed for the rapid three-dimensional welding of motorcycle aluminum-alloy structural parts. The term “compound-laser welding” means a high-speed welding method in which a number of lasers with different characteristics are arranged on the same axis. This paper reports the results of welding by a compound laser consisting of a YAG laser and a CO2 laser. It was found that compound-laser welding with two or more types of gases mixed as shielding gas gives a better welding performance than single-laser welding due to the advantages of the different lasers used in compound-laser welding.

The SI engine combustion model LI-CFM introduced by Boudier et, al. (1992) [8] is extended to deal with actual engines. New models are proposed to simulate ignition with convection at the spark and flame-wall interaction. The scalar properties of the unburnt gases within the combustion zone are computed. This allows for the computation of flame propagation in temperature, fuel and residual gas stratified charges. A model for NO and CO formation is introduced. It is based on a conditional burnt/unburnt averaging of the reaction rates. Pollutants are created at the flamelet level and evolve in the burnt, gases using a mixed equilibrium/kinetic scheme. All these physical models are implemented in a multi-block version of the Kiva 2 code, KMB. This code is used to simulate a 4-valve engine including intake ports. Initial and boundary conditions are obtained from a ID acoustic code.

The vehicle Heating, Ventilation and Air conditioning (HVAC) system is designed to meet both the safety and thermal comfort requirements of the passengers inside the cabin. The thermal comfort requirement, however, is highly subjective and is usually met objectively by carrying out time dependent mapping of parameters like the velocity and temperature at various in-cabin locations. These target parameters are simulated for the vehicle interior for a case of hot soaking and its subsequent cool-down to test the efficacy of the AC system. Typically, AC performance is judged by air temperature at passenger locations, thermal comfort estimation along with time to reach comfortable condition for human. Simulating long transient vehicle cabin for thermal comfort evaluation is computationally expensive and involves complex cabin material modelling.

A chemical sub-model for realistic CFD simulations of Diesel engines is developed and demonstrated by application to some test cases. The model uses a newly developed progress variable approach to incorporate a realistic treatment of chemical reactions into the description of the reactive flow. The progress variable model is based on defining variables that represent the onset and temporal development of chemical reactions before and during self ignition, as well as the stage of the actual combustion. Fundamental aspects of the model, especially its physical motivation and finding a proper progress variable, are discussed, as well as issues of practical implementation. Sample calculations of Diesel-typical combustion scenarios are presented which are based on the progress-variable model, showing the capability of the model to realistically describe the ignition-and combustion phase.

3M is committed to continuously improving products and their manufacture toward the goal of sustainability. The 3M Life Cycle Management (LCM) program has been established to implement this goal. It utilizes a matrix tool to facilitate the review. The matrix consists of LCM Stage (Material Acquisition, R&D Operations, Manufacturing Operations, and Customer Use/Disposal) and Impact (Environment, Health, Safety, and Energy/Resources). The program is coordinated at the staff level by the Corporate Product Responsibility group. The corporate goal is to apply LCM to all new and existing products. The LCM program started with evaluations of new products within business units. Since 3M produces more than 60,000 products manufactured from more than 10,000 different raw materials, the routine evaluation of individual products challenges available staff and business unit resources. A technology-based approach for doing LCMs has been implemented to meet the challenge.

This paper discusses five different methods for measuring the gas stream temperature from a burner using a hydrocarbon fuel, air, and oxygen. Tests were made with a single shielded BeO probe, a bare wire iridium -- 60% rhodium/iridium couple, a tantalum triple shielded platinum -- 10% rhodium/platinum thermocouple, the sodium line reversed technique, and a watercooled total enthalpy probe. The most serviceable system proved to be the bare wire iridium -- 60% rhodium/iridium couple, particularly for carrying out stream surveys where relative, rather than true temperatures, are of primary concern. More study is needed to establish a system for determining the true stream temperature.