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The US EPA emission standards for 2010 on-highway and 2014 non-road diesel engines are extremely stringent, both in terms of oxides of nitrogen (NOX) and particulate matter (PM). Diesel engines typically operate lean and use at least 40-50 percent more air than what is needed for stoichiometric combustion of the fuel. As a result, significant excess oxygen (O₂) is present in diesel exhaust gas which prevents the application of the mature three-way catalyst (TWC) technology for NOX control used in gasoline engines. The objective of this work was to investigate whether or not the catalyzed DPF had a TWC-type of effect on NOX emissions and if so, why and to what extent when used on a diesel engine operating at reduced A/F ratio conditions.

The diesel engine has long been the most energy efficient powerplant for transportation. Moreover, diesels emit extremely low levels of hydrocarbon and carbon monoxide that do not require post-combustion treatment to comply with current and projected standards. It is admittedly, however, difficult for diesel engines to simultaneously meet projected nitrogen oxides and particulate matter standards. Traditionally, measures aimed at reducing one of these two exhaust species have led to increasing the other. This physical characteristic, which is known as NOx/PM tradeoff, remains the subject of an intense research effort. Despite this challenge, there is significant evidence that heavy-duty highway engine manufacturers can achieve substantial emission reductions. Many development programs carried out over the last five years have yielded remarkable results in laboratory demonstrations.

Tightening regulations throughout the world demand a reduction in fuel consumption and NOX emission levels, creating an increasing need for additional heat for SCR aftertreatment. A durable and low cost heating system is needed for vehicles with hybrid or 24Vdc electricity. Recent development efforts have resulted in much smaller and lower cost heating systems for electrical systems ranging from 400 to 24Vdc. Test results demonstrate the feasibility of reducing the size of the heater and the relationship of heater power to the amount of time required to heat the exhaust. Intelligent solid state switching enables the heater to be smaller without compromising durability.

Real world driving conditions and tightening legislations require improved performance of aftertreatment systems at lower temperatures. Electric heat has been shown to be an effective method of heating exhaust, but having a practical means to provide power and control for the heater has been a barrier for implementation. Recent testing has demonstrated the ability of a 24Vdc heating and control system to effectively heat exhaust using only conventional alternator and battery power sources. Results from transient cycles show the effectiveness of the electrical system and the extent of exhaust heating.

Exhaust gas recirculation (EGR) has long been used in gasoline and light-duty diesel engines as a NOx reduction tool. Recently imposed emission regulations led several heavy-duty diesel engine manufacturers to adopt EGR as part of their strategy to reduce NOx. The effectiveness of this technology has been widely documented, with NOx reduction in the range of 40 to 50 percent having been recorded. An inevitable consequence of this strategy is an increase in particulate emission, especially if EGR was used in high engine load modes. Selective catalytic reduction (SCR), a method for NOx reduction, is widely used in stationary applications. There is growing interest and activity to apply it to mobile fleets equipped with heavy-duty diesel engines. Results of this work indicate that SCR has the potential to dramatically reduce NOx in diesel exhaust. Reductions greater than 70 percent were reported by several including the Institute's previous work (SAE Paper No. 1999-01-3564).

To evaluate the performance of a variety of commercially available exhaust emission control technologies, the Manufacturers of Emission Controls Association (MECA) sponsored a test program at Southwest Research Institute (SwRI). The test engine was a current design heavy-duty diesel engine operated on standard No. 2 diesel (368 ppm) and lower sulfur (54 ppm) diesel fuel. Technologies evaluated included: diesel oxidation catalysts (DOCs), diesel particulate filters (DPFs), selective catalytic reduction (SCR), fuel-borne catalysts (FBCs) in combination with filters and oxidation catalysts, and combinations of the above technologies. The program was structured to demonstrate that a variety of exhaust emission control technologies, including exhaust gas recirculation, could be used to substantially reduce emissions from a modern MY 1998 heavy-duty diesel engine.

The 2007 emission standards for both light-duty and heavy-duty diesel vehicles remain a challenge. A level of about 90% NOx conversion is required to meet the standards. Technologies that have the most potential to achieve very high NOx conversion at low temperatures of diesel exhaust are lean NOx traps (LNTs) and Selective Catalytic Reduction (SCR) of NOx using aqueous urea, typically known as Urea SCR. The LNT has the advantage of requiring no new infrastructure, and does not pose any new customer compliance issues. However, Urea SCR has high and durable NOx conversion in a wider temperature window, a lower equivalent fuel penalty, and lower system cost. On a technical basis, Urea SCR has the best chance of meeting the 2007 NOx targets. This paper reviews the results of some demonstration programs for both light-and heavy-duty applications.

SCR cold-start effects are increasingly important for meeting today's emission requirements [1]. A significant challenge toward quickly achieving NOx abatement is the presence of moisture in the catalyst at lower temperatures [1]. This paper describes the ability of an electric heater to effectively raise the temperature of the exhaust and overcome the effect of moisture and low exhaust temperature, allowing NOx conversion to begin sooner. A model of the moisture storage and removal is presented, along with results from engine tests. Results show that it is possible to achieve high NOx conversion temperatures quickly with robust heater technology that is suited for diesel applications.