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A model has been developed for a divided-chamber automotive diesel engine which describes the intake, compression, combustion and expansion, and exhaust processes in sufficient detail to permit calculations of pressure, fuel-air ratio distribution, heat release distribution, NO formation, soot mass loading, and soot oxidation processes. The novel feature of this model is the use of a stochastic mixing approach during the combustion and expansion processes to describe the nonuniform fuel-air ratio distribution within the engine. In this approach, the fuel-air ratio distribution during the combustion and emissions formation processes can be followed as it evolves with time. Experimental data generated on a single-cylinder divided-chamber diesel engine were used to verify the accuracy of the model predictions. Agreement between experimental data and predicted values of engine performance and NOx emissions levels was good.

An experimental study was performed in a firing SI engine at conditions representative of the warmup phase of operation in which liquid gasoline films were established at various locations in the combustion chamber and the resulting impact on hydrocarbon emissions was assessed. Unique about this study was that it combined, in a firing engine environment, direct visual observation of the liquid fuel films, measurements of the temperatures these films were subjected to, and the determination from gas analyzers of burned and unburned fuel quantities exiting the combustion chamber - all with cycle-level resolution or better. A means of deducing the exhaust hydrocarbon emissions that were due to the liquid fuel films in the combustion chamber was developed. An increase in exhaust hydrocarbon emissions was always observed with liquid fuel films present in the combustion chamber.

Experiments to study the effects of oxygenated fuels on emissions and combustion were performed in a single-cylinder direct-injection (DI) diesel engine. A matrix of oxygen containing fuels assessed the impact of weight percent oxygen content, oxygenate chemical structure, and oxygenate volatility on emissions. Several oxygenated chemicals were blended with an ultra-low sulfur diesel fuel and evaluated at an equivalent energy release and combustion phasing. Additional experiments investigated the effectiveness of oxygenated fuels at a different engine load, a matched fuel/air equivalence ratio, and blended with a diesel fuel from the Fischer-Tropsch process. Interactions between emissions and critical engine operating parameters were also quantified. A scanning mobility particle sizer (SMPS) was used to evaluate particle size distributions, in addition to particulate matter (PM) filter and oxides of nitrogen (NOx) measurements.