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Biofuels, such as ethanol and butanol, have been the subject of significant political and scientific attention, owing to concerns about climate change, global energy security, and the decline of world oil resources that is aggravated by the continuous increase in the demand for fossil fuels. This study evaluated the potential emissions impacts of different alcohol blends on a fleet of modern gasoline vehicles. Testing was conducted on a fleet of nine vehicles with different combinations of ten fuel blends over the Federal Test Procedure and Unified Cycle. The vehicles ranged in model year from 2007-2014 and included four vehicles with port fuel injection (PFI) fueling and five vehicles with direct injection (DI) fueling. The ten fuel blends included ethanol blends at concentrations of 10%, 15%, 20%, 51%, and 83% by volume and iso-butanol blends at concentrations of 16%, 24%, 32%, and 55% by volume, and an alcohol mixture giving 10% ethanol and 8% iso-butanol in the final blend.

This paper presents a new concept of a partial flow sampling system (PFSS), involving a two-stage dilutor which operates at underpressure, while exhaust is sampled through a capillary. The sample flowrate is in the order of few cubic centimeters per minute. Due to the low flowrate, no tight fixation is required between the exhaust line and the capillary inlet. The dilutor may sample from an opening in the exhaust line which freely exhausts to ambient pressure. As a result, the PFSS operates at constant pressure conditions even upstream of diesel particle filters (DPF). A straightforward mathematical model is then developed to calculate the dilution ratio (DR), depending on the dilution air flowrate and the dilutor underpressure. The model is validated using CO2 as a trace gas, and a very good agreement is demonstrated between the calculated and the measured DR values.

This study investigates the impact of mid-high biodiesel blends on the criteria and PAH emissions from a modern pick-up diesel vehicle. The vehicle was a Euro 4 (category N1, subclass III) compliant common-rail light-duty goods pick-up truck fitted with a diesel oxidation catalyst. Emission and fuel consumption measurements were performed on a chassis dynamometer equipped with CVS, following the European regulations. All measurements were conducted over the certification New European Driving Cycle (NEDC) and the real traffic-based Artemis driving cycles. Aiming to evaluate the fuel impact on emissions, a soy-based biodiesel, a palm-based biodiesel, and an oxidized biodiesel obtained from used frying oils were blended with a typical automotive ultra-low-sulfur diesel at proportions of 30, 50 and 80% by volume. The experimental results revealed that CO₂ emissions and fuel consumption exhibited an increase with biodiesel over all driving conditions.

The Pegasor Particle Sensor (PPS) has been earlier presented by Ntziachristos et al. (SAE Paper 2011-01-0626) as a novel small and robust instrument that can be directly installed in the exhaust line to measure exhaust particles without any dilution. The instrument is based on the electrical detection of aerosol. It is increasingly being used to measure exhaust particles from engines and vehicles with different exhaust configurations. In this study, a number of tests have been conducted using two sensors in parallel, one directly installed in the tailpipe and one installed in the CVS, side by side to the PM sampling filter. Aim of the study was to make recommendations on the proper use of the sensor and to check how the sensor signal compares to particulate mass, soot concentration, and particle number. A first finding is that external heating has to be provided to the sensor to avoid condensation.

The Pegasor Particle Sensor (PPS) is a small and lightweight sensor that can be used directly in raw exhaust to provide the mass and number concentration of exhaust aerosol. Its operation principle is based on the electrical charging of exhaust aerosol and determination of particle concentration by measuring the charge accumulated on the particles. In this paper we have applied the PPS in a variety of vehicle exhaust configurations to evaluate its performance characteristics. First, the output signal of the instrument was calibrated with diesel exhaust to deliver either the mass or the number concentration of exhaust aerosol. Linear response with the soot mass concentration measured by a Photo Acoustic Soot Sensor and number concentration measured by an Electrical Low Pressure Impactor was established.

In this study, tailpipe-sampling was used to sample the exhaust aerosol of a Stage IV tractor equipped with Diesel Oxidation Catalyst (DOC) and Selective Catalytic Reduction (SCR) aftertreatment systems. The particle emissions were characterized in terms of number concentration (particle size of > 2.5 nm), mass concentration (particle size of 6-612 nm) BC mass concentration and chemical composition (particle size of > 30 nm). The measurements were conducted on-road by setting a mobile laboratory on a trailer and pulling it with the tractor. In addition to driving, heavy-lift work cycles were tested, where separate lifts of a 1000 kg weight were conducted with the front fork of the tractor with two minutes of idling between consecutive lifts. Both a Porous Tube Diluter (PTD) with ambient temperature dilution air as well as an ejector diluter with hot dilution air were used to sample the exhaust aerosol.

The Particle Measurement Programme (PMP), initiated from different Member States, aims at developing a method and sampling recommendations for a particle number-based emission standard, to support future emission regulation in Europe. In this paper we applied two different commercially available dilution systems (an FPS from Dekati Ltd and an MD19-2E from Matter Engineering AG) to record the particle emissions of a Euro II and a Euro III diesel passenger car. The latter was also fitted with a diesel particle filter (DPF) to simulate future emission levels. At their present development stage, both dilution systems failed to totally comply with all requirements of the PMP protocol. The main problems appeared to be the lack of accurate determination of the dilution ratio and the inability to reach the desired dilution temperature.

This study provides one of the first evaluations of the integrated particle size distribution (IPSD) method in comparison with the current gravimetric method for measuring particulate matter (PM) emissions from light-duty vehicles. The IPSD method combines particle size distributions with size dependent particle effective density to determine mass concentrations of suspended particles. The method allows for simultaneous determination of particle mass, particle surface area, and particle number concentrations. It will provide a greater understanding of PM mass emissions at low levels, and therefore has the potential to complement the current gravimetric method at low PM emission levels. Six vehicles, including three gasoline direct injected (GDI) vehicles, two port fuel injected (PFI) vehicles, and one diesel vehicle, were tested over the Federal Test Procedure (FTP) driving cycle on a light-duty chassis dynamometer.

Diesel engines are widespread in both passenger car and heavy duty truck applications. However, despite that the combustion concepts are similar in the two cases, the engine calibration required for compliance with the different emission standards leads to distinct particle emission behavior from the two categories. This paper compares the exhaust particle emissions from heavy duty engines with typical diesel passenger cars of similar emission standard and/or emission control technology. Measurements were conducted with the same sampling system and sampling protocol to avoid interferences induced by the sampling methodology. A range of particle properties were studied, including mass, number of solid and total particles and total particle surface. For comparability, the results are expressed per unit of exhaust volume, per unit of fuel consumed and per unit of distance driven.

This paper investigates the effect of lubrication oil on the physical and chemical characteristics of the particulate matter (PM) emitted from a Euro 4 diesel vehicle. Two different lubrication oils were examined. A fully synthetic ACEA grade B3 service-fill oil of low sulfur content (1760 ppm wt.) falling into the OW-40 SAE viscosity grade and a mineral ACEA B2-98 motor oil of high sulfur (8890 ppm wt.), falling into the 15W-40 SAE viscosity grade. To exclude interferences from the fuel derived sulfur, a rather sulfur-free fuel (< 10 ppm wt.) was used in the experiments. The experiments included steady state tests, the certification cycle and real-world highspeed transient driving conditions. The properties measured included total particle mass collected on Teflon-coated filters, total particle number measured by a condensation particle counter, size distributions determined by a scanning mobility particle sizer.

This work studies the formation of nucleation mode (NM) particles from a Euro 3 passenger car operating on 280 ppm wt. sulfur fuel, during on-road plume chasing and in the laboratory. The vehicle produced a distinct NM when its speed exceeded 100 km/h in both sampling environments. A higher particle number (up to 8 times) after 4 min at constant speed was measured when this speed was approached from a lower than from a higher speed. The variability in the measurement of NM particles was explained using literature information on sulfur-to-sulfate conversion over a catalyst and, in particular, on the extent and rate of sulfate storage and release mechanisms. All evidence led to the conclusion that storage and release processes take several minutes to conclude after a step-wise change in speed and have significant implications in the total particle number measurements during steady-speed testing.

This paper studies the effect of a Catalyzed Diesel Particle Filter (CDPF) on the emission profile of a Euro 4 diesel vehicle operated on low sulfur fuel and lubrication oil. The vehicle was tested in its original configuration and with the CDPF retrofitted in place of its main underbody catalyst. Experiments included steady state tests, the certification cycle and real-world high speed transient driving conditions. Measurements included total particle mass collected on Teflon-coated filters, total particle number measured by a condensation particle counter, size distributions determined by a Scanning Mobility Particle Sizer and chemical analysis of the mass collected for elemental and organic carbon, ions, PAHs, and trace elements. Results showed that the vehicle complies with the Euro 4 emission limits when tested over the type-approval NEDC, but it emits more nitrogen oxides and, in some cases, more particulate matter when tested over real-world test cycles.

Electrical low pressure impactor ELPI was modified to measure particles below 30 nanometers in aerodynamic diameter. This was accomplished by adding a filter stage to collect and measure nanoparticles. The charging unit of the instrument was modified to increase the charging efficiency of the smallest, nanometer sized, particles. The modified charging unit was calibrated and the new construction of the ELPI was tested in laboratory and in vehicle dynamometer test cell. Measurements performed in the engine test cell showed that modifications improve the size range and measurement capability of the ELPI for engine emissions.

Gaseous and particulate matter (PM) emissions were assessed from two current technology heavy-duty vehicles operated on CARB ultra-low sulfur diesel (ULSD), hydrotreated vegetable oil (HVO) blends, and a biodiesel blend. Testing was performed on a 2014 model year Cummins ISX15 vehicle and on a 2010 model year Cummins ISB6.7 vehicle. Both vehicles were equipped with diesel oxidation catalysts (DOC), diesel particulate filter (DPF), and selective catalytic reduction (SCR) systems. Testing was conducted over the Heavy-Duty Urban Dynamometer Driving Schedule (UDDS) and Heavy Heavy-Duty Diesel Truck (HHDDT) Transient Cycle. The results showed lower total hydrocarbons (THC), non-methane hydrocarbons (NMHC), and methane (CH4) emissions for the HVO fuels and the biodiesel blend compared to CARB ULSD. Overall, nitrogen oxide (NOx) emissions showed discordant results, with both increases and decreases for the HVO fuels.

The primary objective of this study was to evaluate the impact of three different biodiesel feedstocks on emissions compared to a baseline CARB ULSD with two heavy-duty trucks equipped with and without aftertreatment technologies. The biodiesels included a soybean oil methyl ester (SME), a waste cooking oil methyl ester (WCO), and a methyl ester obtained from animal fat (AFME), blended at a 50% level by volume with the CARB diesel. The vehicles were equipped with a 2010 Cummins ISX-15 engine with a selective catalytic reduction (SCR), diesel oxidation catalyst (DOC) and a diesel particulate filter (DPF) and with a 2002 Cummins ISX-450 engine. Both vehicles were tested over the Urban Dynamometer Driving Schedule (UDDS) on a heavy-duty chassis dynamometer. For this study, nitrogen oxides (NOx), carbon monoxide (CO), carbon dioxide (CO2), total hydrocarbons (THC), methane (CH4), non-methane hydrocarbons (NMHC), and particulate matter (PM) were measured.

The emissions of two ultralow NOx heavy-duty (HD) vehicles equipped with 0.02 g/bhp-hr low NOx natural gas (NG) engines were evaluated on a chassis dynamometer. This included a waste hauler and a city transit bus, each with a 0.02 g/bhp-hr NOx L9N near zero (NZ) natural gas engine. The vehicles were tested over a variety of different cycles, including the Urban Dynamometer Driving Schedule (UDDS), port drayage cycles, transit bus cycles, and a refuse truck cycle. For both vehicles, the NOx emissions results were below the 0.02 g/bhp-hr level for most cycles, with the exception of some cold start tests. For the waste hauler, NOx emissions averaged between 0.014 and 0.002 g/bhp-hr for the hot start tests, and from 0.043 to 0.014 g/bhp-hr for the cold start tests. This represented NOx emissions reductions from 97%-100% of compared with previous ISL G 8.9 engines.

We assessed the engine-out emissions of an ultra-low sulfur diesel (ULSD) and a neat hydrogenated vegetable oil (HVO) from a light-duty diesel truck equipped with common rail direct injection. The vehicle was tested at least twice on each fuel using the LA-92 drive cycle and at steady-state conditions at 30 mph and 50 mph at different loads. Results showed reductions in the engine-out total hydrocarbon (THC), carbon monoxide (CO), nitrogen oxide (NOx), and particulate emissions with HVO. The reductions in soot mass, solid particle number, and particulate matter (PM) mass emissions with HVO were due to the absence of aromatic and polyaromatic hydrocarbon compounds, as well as sulfur species, which are known precursors of soot formation. Volumetric fuel economy, calculated based on the carbon balance method, did not show statistically significant differences between the fuels.

The relationship between ethanol and iso-butanol fuel concentrations and vehicle particulate matter emissions was investigated. This study utilized a gasoline direct injection (GDI) flexible fuel vehicle (FFV) with wall-guided fueling system tested with four fuels, including E10, E51, E83, and an iso-butanol blend at a proportion of 55% by volume. Emission measurements were conducted over the Federal Test Procedure (FTP) driving cycle on a chassis dynamometer with an emphasis on the physical and chemical characterization of particulate matter (PM) emissions. The results indicated that the addition of higher ethanol blends and the iso-butanol blend resulted in large reductions in PM mass, soot, and total and solid particle number emissions. PM emissions for the baseline E10 fuel were characterized by a higher fraction of elemental carbon (EC), whereas the PM emissions for the higher ethanol blends were more organic carbon (OC) in nature.

Particulate matter (PM) emitted from gasoline combustion continues to be a subject of research and regulatory interest. This is particularly true as new technology gasoline direct injection (GDI) engines can produce significantly higher levels of PM compared to older technology port fuel injection (PFI) engines. The goal of this study was to conduct a comprehensive literature search and subsequent statistical analysis related to the effects of gasoline properties, such as aromatics, octane indices, and fuel volatility, on PM (mass and number) emissions from PFI and GDI vehicles/engines. The statistical analyses showed a range of positive and negative correlations between different fuel properties and PM mass, total particle number (PN) and solid particle number (SPN) for different engine types (GDI, PFI, and for subdivisions of these engine types), numbers of engine cylinders and driving cycles.

We assessed gaseous and particulate matter (PM) emissions from a current technology stoichiometric natural gas waste hauler equipped with a 2011 model year 8.9L Cummins Westport ISL-G engine with cooled exhaust gas recirculation (EGR) and three-way catalyst (TWC). Testing was performed on five fuels with varying Wobbe and methane numbers over the William H. Martin Refuse Truck Cycle. The results showed lower nitrogen oxide (NOx) emissions for the low methane fuels (i.e., natural gas fuels with a relatively low methane content) for the transport and curbside cycles. Total hydrocarbon (THC) and methane (CH4) emissions did not show any consistent fuel trends. Non-methane hydrocarbon (NMHC) emissions showed a trend of higher emissions for the fuels containing higher levels of NMHCs. Carbon monoxide (CO) emissions showed a trend of higher emissions for the low methane fuels.