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Although in-cylinder optical diagnostics have provided significant understanding of conventional diesel combustion, most alternative combustion strategies have not yet been explored to the same extent. In an effort to build the knowledge base for alternative low-temperature combustion strategies, this paper presents a comparison of three alternative low-temperature combustion strategies to two high-temperature conventional diesel combustion conditions. The baseline conditions, representative of conventional high-temperature diesel combustion, have either a short or a long ignition delay. The other three conditions are representative of some alternative combustion strategies, employing significant charge-gas dilution along with either early or late fuel injection, or a combination of both (double-injection).

This paper reports on the third part of a continued study (SAE Papers 961182, 971636) to develop the Ignition Quality Tester (IQT™). Past research has shown that this automated laboratory/refinery apparatus can be used to accurately predict the cetane number of middle distillates and alternative fuels using small sample volumes (< 50 mL). The paper reports on the main objective of a study performed by Advanced Engine Technology Ltd. (AET), in co-operation with its research partners. The primary research objective of this work is to further the understanding of fuel preparation (fuel air mixing) and start of combustion processes in the IQT™. Key to this understanding is the manner in which single molecule compounds and full boiling-range diesel fuels behave during these processes. Insights are provided into the manner in which the American Society for Testing and Materials (ASTM) D-613 primary reference fuels (PRFs) undergo fuel preparation and start of combustion in the IQT™.

This paper is part of a larger body of experimental and computational work devoted to studying the role of close-coupled post injections on soot reduction in a heavy-duty optical engine. It is a continuation of an earlier computational paper. The goals of the current work are to develop new CFD analysis tools and methods and apply them to gain a more in depth understanding of the different in-cylinder environments into which fuel from main- and post-injections are injected and to study how the in-cylinder flow, thermal and chemical fields are transformed between start of injection timings. The engine represented in this computational study is a single-cylinder, direct-injection, heavy-duty, low-swirl engine with optical components. It is based on the Cummins N14, has a cylindrical shaped piston bowl and an eight-hole injector that are both centered on the cylinder axis. The fuel used was n-heptane and the engine operating condition was light load at 1200 RPM.

The key feature of diesel fuel ignition quality is ignition delay time. In the American Society for Testing and Materials standard test for cetane number measurement, (ASTM D 613) the ignition delay time is held constant while the compression ratio is varied until ignition occurs at the set time. On the other hand, commercial diesel engines have set compression ratios and therefore, the ignition delay time varies with the cetane number of the fuel. The shorter this delay time, the wider the time window over which the combustion processes are spread. This leads to a more controlled heat release rate and pressure rise, resulting in prevention of diesel knock and in lowering of emissions. High cetane fuels exhibit short ignition delay times. The Constant Volume Combustion Apparatus (CVCA) precisely measures the ignition delay time of fuels. This study investigates the CVCA as a supplementary tool for characterization of diesel fuel ignition quality under a variety of conditions.

Biodiesel is a mixture of esters (usually methyl esters) of fatty acids found in the triglycerides of vegetable oils. The different fatty compounds comprising biodiesel possess different ignition properties. To investigate and potentially improve these properties, the cetane numbers of various fatty acids and esters were determined in a Constant Volume Combustion Apparatus. The cetane numbers range from 20.4 for linolenic acid to 80.1 for butyl stearate. The cetane numbers depend on the number of CH2 groups as well as the number of double bonds and other factors. Various oxygenated compounds were studied for their potential of improving the cetane numbers of fatty compounds. Several potential cetane improvers with ignition delay properties giving calculated cetane numbers over 100 were identified. The effect of these cetane improvers depended on their concentration and also on the fatty material investigated.

During the 1980's, vegetable oils, microemulsions containing fatty alcohols as surfactants, and fatty esters have been extensively investigaed as alternative fuels to #2 diesel fuel (DF-2) used in farm tractors. Despite the importance of vegetable oils (mainly triglycerides) and fatty derivatives to the alternative fuel program, cetane numbers for pure triglycerides and many fatty derivatives were not reported. In the current study, estimated cetane numbers of these materials have been determined by use of a constant volume combustion bomb. Prior research has shown that this equipment can produce cetane numbers that correlate satisfactorily with engine cetane numbers as determied by ASTM D 613. The influence of chemical structure on ignition delay and cetane number was investigated. Evidence is presented that shows the current cetane number scale is not always suitable for these fatty materials. Suggestions are made as to what might be done to remedy this problem.

Four major coal fuel projects which were performed at Southwest Research Institute over the past ten years are reviewed. Beginning with the “Alternative Fuels for Highway Utilization” project in 1979, and the success of carbon-black/diesel fuel slurries, the development of the coal slurries is traced to the current technology. Most recently, full-scale locomotive engines have been operated on 50% coal in water slurries at thermal efficiencies approaching that of diesel fuel performance. The paper is concluded with a recommended engine design for coal slurries.

Autoignition of coal-water-slurry (CWS) fuel in a two-stroke engine operating at 1900 RPM has been achieved. A Pump-Line-Nozzle (PLN) injection system, delivering 400mm3/injection of CWS, was installed in one modified cylinder of a Detroit Diesel Corporation (DI)C) 8V-149TI engine, while the other seven cylinders remained configured for diesel fuel. Coal Combustion was sustained by maintaining high gas and surface temperatures with a combination of hot residual gases, warm inlet air admission, ceramic insulated components and increased compression ratio. The coal-fueled cylinder generated 85kW indicated power (80 percent of rated power), and lower NOx levels with a combustion efficiency of 99.2 percent.

Mixtures of methanol, water and heavier alcohols, simulating “raw’ methanol at various levels of processing, were tested in a constant volume combustion apparatus (CVCA) and in a single-cylinder, direct-injection diesel engine. The ignition characteristics determined in the CVCA indicated that the heavier alcohols have beneficial effects on the auto-ignition quality of the fuels, as compared to pure methanol. Water, at up up to 10 percent by volume, has little effect on the ignition quality. In all cases, however, the cetane numbers of the alcohol mixtures were very low. The same fuels were tested in a single cylinder engine, set-up in a configuration similar to current two-valve DI engines, except that the compression ratio was increased to 19:1. Pure methanol and five different blends of alcohols and water were tested in the engine at five different speed-load conditions.

A technique is verified for mapping the exhaust emission levels of a diesel engine during transient operation. Particulate matter, oxides of nitrogen, hydrocarbons, and carbon monoxide emissions were sampled for discrete segments of various transient cycles. Each cycle consisted of four distinct segments. The discrete segments are described by average engine conditions, rate of change variables, and segment length. Regression analysis was used to develop equations relating the emission levels during each segment to the engine parameters. The regression equations were then used to obtain estimates of composite emission levels of several complex transient cycles that were subsequently tested. These cycles included the EPA heavy-duty transient cycle and two simulated heavy-duty cycles developed for underground mine vehicles. Comparison of the predicted and measured cycle emissions are made for the EPA heavy duty cycle and the simulated mine cycles.

Three different approaches for modeling diesel engine combustion are compared against cylinder pressure, NOx emissions, high-speed soot luminosity imaging, and 2-color thermometry data from a heavy-duty DI diesel engine. A characteristic time combustion (KIVA-CTC) model, a representative interactive flamelet (KIVA-RIF) model, and direct integration using detailed chemistry (KIVA-CHEMKIN) were integrated into the same version of the KIVA-3v computer code. In this way, the computer code provides a common platform for comparing various combustion models. Five different engine operating strategies that are representative of several different combustion regimes were explored in the experiments and model simulations. Two of the strategies produce high-temperature combustion with different ignition delays, while the other three use dilution to achieve low-temperature combustion (LTC), with early, late, or multiple injections.

The increased use of diesel-powered equipment in underground mines has prompted interest in reducing their exhaust pollutants. Control of particulate emissions without substantial penalties in other emissions or fuel consumption is necessary. This paper describes test results on a prechaaber, naturally-aspirated, four-cycle diesel engine in which two different concentrations of water-in-fuel emulsions were run. The independent variables comprising the test matrix were fuel, speed, load, injection timing, injection rate, and compression ratio. The dependent variables of the experiment included particulate and gaseous emissions and engine thermal efficiency. Regression analysis was performed on the data to determine how particulate emissions were affected by fuel and engine parameters. Results of this analysis indicated that substantial reductions in particulate emissions could be obtained by utilizing water-in-fuel emulsions.

This paper is the fourth in a series describing work sponsored by the Bureau of Mines to reduce diesel particulate and gaseous emissions through fuel modification. A stabilized water microemulsion fuel developed in previous work was tested in a Caterpillar 3304 NA four-cylinder engine with compression ratio and injection timing and rate optimized for this fuel to demonstrate the emissions reductions achieved. It was tested in both standard and optimum configurations with both baseline DF-2 and optimized microemulsion fuels. Gaseous and particulate data are presented from steady-state tests using a computer-operated mini-dilution tunnel and from transient tests using a total exhaust dilution tunnel. The optimized engine-fuel combination was effective in reducing particulates and oxides of nitrogen in steady-state tests. However, the standard engine-fuel combination provided the lowest particulate and NOx emissions in transient tests.

As a part of an overall project to improve the techniques for rating the ignition quality of diesel engine fuels, the experiments described in this paper involve examination of the relationship between cetane number and both the physical and chemical ignition delay times. The ignition delay times have been determined from accurate pressure histories obtained during the injection and ignition of a variety of test fuels in a constant volume combustion bomb using a quiescent, high-temperature, high-pressure air environment. The test fuels have included blends of the primary reference fuels as well as other fuels selected because of specific physical properties or chemical composition. The correlation between the cetane numbers of the fuels and various ignition delay times are examined.

Slurry fuels of various forms of solids in diesel fuel were developed and evaluated for their relative potential as fuel for diesel engines. Thirteen test fuels with different solids concentrations were formulated using eight different materials. The injection and atomization characteristics (transient diesel sprays) of the test fuels were examined in a spray bomb in which a nitrogen atmosphere was maintained at high pressure and temperature, 4.2 MPa and 480°C, respectively. The diagnostics of the sprays included high-speed movies and high-resolution still photographs. The slurries were also tested in a single-cylinder CLR engine in both direct-injection and prechamber configurations. The data included the normal performance parameters as well as heat release rates and emissions. In most cases, the slurries performed very much like the baseline fuel. The combustion data indicated that a large fraction (90 percent or more) of the solids were burning in the engine.

Four broad boiling range materials, representative of current and future feedstocks for diesel fuel, were processed to two levels of sulfur and aromatic content. These materials were then distilled into six to eight fractions each. The resulting 63 fuels were then characterized physically and chemically, and tested in both a constant volume combustion apparatus and a single cylinder diesel engine. The data obtained from these analyses and tests have been analyzed graphically and statistically. The results of the initial statistical analysis, reported here, indicate that the ignition quality of a fuel is dependent not only on the overall aromatic content, but also on the composition of the material formed during hydroprocessing of the aromatics. The NOx emissions, however, are related mainly to the aromatic content of the fuel, and the structure of the aromatic material.

The ignition delay times of forty-two different fuels were measured in a constant volume combustion bomb. The measurements were performed at three different initial air temperatures using fuels ranging from the primary reference fuels for cetane rating to complex mixtures of coal-derived liquids. The ignition delay times were examined in terms of the classical definitions of the physical and chemical delay times. The previously used definitions were found to be inadequate, and new definitions have been proposed. The total ignition delay times were studied in the context of providing a means for rating the ignition quality of the fuels. Fuel ignition quality rating schemes are discussed, including one based on the current cetane number scale as well as one based on a new scale which includes a measure of the sensitivity of the various fuels to the air temperature.

A single-cylinder, variable-compression ratio, direct-injection diesel engine was designed and constructed to study the ignition quality of seventeen different test fuels, ranging from the primary reference fuels to a vegetable oil. The objective of the work was to compare the ignition quality rating of the fuels using the standard cetane rating technique to ratings obtained in the test engine. The ignition delay times have been measured as functions of the engine speed, load, and compression ratio. As in the standard cetane rating technique, injection timing was adjusted so that combustion started at top dead center. This was accomplished by adjusting the injection timing as the speed, load, and compression ratio were varied. The resulting data is plotted as the ignition delay times versus compression ratio at the various speed-load conditions.

A combustion-based analytical method, initially developed by the Southwest Research Institute (SwRI) referred to as the Constant Volume Combustion Apparatus (CVCA), has been further researched/developed by an SwRI licensee (Advanced Engine Technology Ltd.) as an Ignition Quality Tester (IQT) for laboratories and refineries. The IQT software/hardware system permits rapid and precise determination of ignition quality for middle distillate fuels. Its features, such as low fuel volume requirement, complete test automation, and self-diagnosis, make it highly suitable for commercial oil industry and research applications. Operating and test conditions were examined in the context of providing a high correlation with cetane number (CN), as determined by the ASTM D-613 method. Preliminary investigation indicates that the IQT results are highly repeatable (± 0.30 CN), providing a high sensitivity to CN variation over the 33 to 58 CN range.

A combustion-based analytical method, initially developed by the Southwest Research Institute (SwRI) and referred to as the Constant Volume Combustion Apparatus (CVCA), has been further researched/developed by an SwRI licensee (Advanced Engine Technology Ltd.). This R&D has resulted in a diesel fuel Ignition Quality Tester (IQT) that permits rapid and precise determination of the ignition quality of middle distillate and alternative fuels. Its features, such as low fuel volume requirement, complete test automation, and self-diagnosis, make it highly suitable for commercial oil industry and research applications. A preliminary investigation, reported in SAE paper 961182, has shown that the IQT results are highly correlated to the ASTM D-613 cetane number (CN). The objective of this paper is to report on efforts to further refine the original CN model and report on improvements to the IQT fuel injection system.