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Hydrogen is a promising energy carrier because it is characterized by a fast combustion velocity, a wide range of sources, and clean combustion products. A hydrogen internal combustion engine (H2ICE) with a turbocharger has been used to solve the contradiction of power density and control NOx. However, the selection of a H2ICE compressor with a turbocharger is very different from traditional engines because of gas fuel. Hydrogen as a gas fuel has the same volume as its cylinder and thus increases pressure and reduces the mass flow rate of air in cylinder for a port fuel injection-H2ICE (PFI-H2ICE). In this study, a general method involving a H2ICE with a turbocharger is proposed by considering the effect of hydrogen on cylinders. Using this method, we can calculate the turbocharged pressure ratio and mass flow rate of air based on the target power and general parameters. This method also provides a series of intake temperatures of air before calculation to improve accuracy.

The motivation of the present work was to understand the mechanism by which alcohols produce less aromatic species in their combustion process than an equal amount of hydrocarbon with similar molecular structure does. Due to its numerous advantages over short-chain alcohols, butanol has been considered very promising in soot reduction. Excluding the influence of spray, vaporization and mixing process in engine cases, an adiabatic constant-pressure reactor model was applied to investigate the effect of butanol additives on aromatic species, which are known to be soot precursors, in fuel-rich butane flames. To keep the carbon flux constant, 5% and 10% oxygen by mass of the fuel were added to butane using butanol additive, respectively. Based on the soot reduction effects proposed in literature, effects on temperature, key radical concentrations and the carbon removal from the pathway to aromatic species were considered to identify the major mechanism of reduction in aromatic species.

Butanol, which is a renewable biofuel, has been regarded as a promising alternative fuel for internal combustion engines. When blended with diesel and applied to pilot ignited natural gas engines, butanol has the capability to achieve lower emissions without sacrifice on thermal efficiency. However, high blend ratio of butanol is limited by its longer ignition delay caused by the higher latent heat and higher octane number, which restricts the improvement of emission characteristics. In this paper, the potential of increasing butanol blend ratio by adding hot exhaust gas recirculation (EGR) is investigated. 3D CFD model based on a detailed kinetic mechanism was built and validated by experimental results of natural gas engine ignited by diesel/butanol blends. The effects of hot EGR is then revealed by the simulation results of the combustion process, heat release traces and also the emissions under different diesel/butanol blend ratios.

Alcohols, because of their potential to be produced from renewable sources and their characteristics suitable for clean combustion, are considered potential fuels which can be blended with fossil-based gasoline for use in internal combustion engines. As such, n-butanol has received a lot of attention in this regard and has shown to be a possible alternative to pure gasoline. The main issue preventing butanol's use in modern engines is its relatively high cost of production. Acetone-Butanol-Ethanol (ABE) fermentation is one of the major methods to produce bio-butanol. The goal of this study is to investigate the combustion characteristics of the intermediate product in butanol production, namely ABE, and hence evaluate its potential as an alternative fuel. Acetone, n-butanol and ethanol were blended in a 3:6:1 volume ratio and then splash blended with pure ethanol-free gasoline with volumetric ratios of 0%, 20%, 40% to create various fuel blends.

In the present study, we developed a reduced chemical reaction mechanism consisted of n-heptane and toluene as surrogate fuel species for diesel engine combustion simulation. The LLNL detailed chemical kinetic mechanism for n-heptane was chosen as the base mechanism. A multi-technique reduction methodology was applied, which included directed relation graph with error propagation and sensitivity analysis (DRGEPSA), non-essential reaction elimination, reaction pathway analysis, sensitivity analysis, and reaction rate adjustment. In a similar fashion, a reduced toluene mechanism was also developed. The reduced n-heptane and toluene mechanisms were then combined to form a diesel surrogate mechanism, which consisted of 158 species and 468 reactions. Extensive validations were conducted for the present mechanism with experimental ignition delay in shock tubes and laminar flame speeds under various pressures, temperatures and equivalence ratios related to engine conditions.

With the development of advanced ABE fermentation technology, the volumetric percentage of acetone, butanol and ethanol in the bio-solvents can be precisely controlled. To seek for an optimized volumetric ratio for ABE-diesel blends, the previous work in our team has experimentally investigated and analyzed the combustion features of ABE-diesel blends with different volumetric ratio (A: B: E: 6:3:1; 3:6:1; 0:10:0, vol. %) in a constant volume chamber. It was found that an increased amount of acetone would lead to a significant advancement of combustion phasing whereas butanol would compensate the advancing effect. Both spray dynamic and chemistry reaction dynamic are of great importance in explaining the unique combustion characteristic of ABE-diesel blend. In this study, a semi-detailed chemical mechanism is constructed and used to model ABE-diesel spray combustion in a constant volume chamber.

Ternary blends of butanol-biodiesel-diesel with different blending ratios were tested inside a constant volume chamber under various ambient temperatures so as to investigate the spray and combustion characteristics of the fuels. Applying the high speed imaging, a sudden drop in spray penetration was observed at ambient temperature of 800 K and 900 K for fuels with certain blending ratio, but not at 1000 K and 1200 K. When the spray penetration of the butanol-biodiesel-diesel blends was compared to that of the biodiesel-diesel blends under non-combusting environment, a sudden drop in spray penetration length was also observed at 1100 K. The results indicated that for the non-combusting case, the tip of the spray jet erupted into a plume sometime after injection for the butanol-biodiesel-diesel blend at an ambient temperature of 1100 K. Such phenomenon was not seen with the biodiesel-diesel blend, neither with the same fuel but at a lower ambient temperature of 900 K.

NOx are the only harmful emissions of hydrogen internal combustion engine. EGR is one of the effective methods to reduce NOx. The traditional EGR is not suitable for hydrogen internal combustion engine. Therefore, the study of influence of hot EGR on hydrogen internal combustion engine is important. A 2.0L hydrogen internal combustion engine with hot EGR system model is employed to optimize the diameter and position of hot EGR based on a simulation analysis. The result shows that both of the combustion temperature and NOx increase as EGR increases due to the rise of intake temperature for low load condition, for heavy load, with the increase of EGR rate, NOx emissions decreases slightly before the mixture equivalence ratio comes to 1and then dropped significantly after the mixture equivalence ratio greater than 1. Unburned hydrogen in TWC has the effect of reducing NOx after catalysts decrease largely.

Nowadays, the world is facing severe energy crisis and environment problems. Development of hydrogen fuel vehicles is one of the best ways to solve these problems. Due to the difficulties of infrastructures, such as the hydrogen transport and storage, hydrogen fuel vehicles have not been widely used yet. As a result, Hydrogen-gasoline dual-fuel vehicle is a solution as a compromise. In this paper, three way catalytic converter (TWC) was used to reduce emissions of hydrogen-gasoline dual-fuel vehicles. On wide open throttle and load characteristics, the conversion efficiency of TWC in gasoline engine was measured. Then the TWC was connected to a hydrogen internal combustion engine. After switching the hydrogen and gasoline working mode, emission data was measured. Experiment results show that the efficiency of a traditional TWC can be maintained above 85%., while it works in a hydrogen-gasoline dual-fuel alternative working mode.

In this work, an efficient and unified combustion model is introduced to simulate the flame propagation, diffusion-controlled combustion, and chemically-driven ignition in both SI and CI engine operation. The unified model is constructed upon a G-equation model which addresses the premixed flame propagation. The concept of the Livengood-Wu integral is used with tabulated ignition delay data to account for the chemical kinetics which is responsible for the spontaneous ignition of fuel-air mixture. A set of rigorously defined operations are used to couple the evolution of the G scalar field and the Livengood-Wu integral. The diffusion-controlled combustion is simulated equivalent to applying the Burke-Schumann limit. The combined model is tested in the simulation of the premixed SI combustion in a constant volume chamber, as well as the CI combustion in a conventional small bore diesel engine.

Acetone-Butanol-Ethanol (ABE), an intermediate product in the ABE fermentation process for producing bio-butanol, is considered a promising alternative fuel because it not only preserves the advantages of oxygenated fuel which typically emit less pollutants compared to conventional diesel, but also lowers the cost of fuel recovery for each individual component during the fermentation. With the development of advanced ABE fermentation technology, the volumetric percentage of acetone, butanol and ethanol in the bio-solvents can be precisely controlled. In this respect, it is desirable to estimate the performance of different ABE blends to determine the best blend and optimize the production process accordingly. ABE fuels with different component ratio, (A: B: E: 6:3:1; 3:6:1; 0:10:0, vol. %), were blended with diesel and tested in a constant volume chamber.

In order to comply with the stringent emission regulations, many researchers have been focusing on diesel-compressed natural gas (CNG) dual fuel operation in compression ignition (CI) engines. The diesel-CNG dual fuel operation mode has the potential to reduce both the soot and NOx emissions; however, the thermal efficiency is generally lower than that of the pure diesel operation, especially under the low and medium load conditions. The current experimental work investigates the potential of using diesel-1-butanol blends as the pilot fuel to improve the engine performance and emissions. Fuel blends of B0 (pure diesel), B10 (90% diesel and 10% 1-butanol by volume) and B20 (80% diesel and 20% 1-butanol) with 70% CNG substitution were compared based on an equivalent input energy at an engine speed of 1200 RPM. The results indicated that the diesel-1-butanol pilot fuel can lead to a more homogeneous mixture due to the longer ignition delay.

Dual-fuel combustion combining a premixed charge of compressed natural gas (CNG) and a pilot injection of diesel fuel offer the potential to reduce diesel fuel consumption and drastically reduce soot emissions. In this study, dual-fuel combustion using methane ignited with a pilot injection of No. 2 diesel fuel, was studied in a single cylinder diesel engine with optical access. Experiments were performed at a CNG substitution rate of 70% CNG (based on energy) over a wide range of equivalence ratios of the premixed charge, as well as different diesel injection strategies (single and double injection). A color high-speed camera was used in order to identify and distinguish between lean-premixed methane combustion and diffusion combustion in dual-fuel combustion. The effect of multiple diesel injections is also investigated optically as a means to enhance flame propagation towards the center of the combustion chamber.

The modeling of fuel jet atomization is key in the characterization of Internal Combustion (IC) engines, and 3D Computational Fluid Dynamics (CFD) is a recognized tool to provide insights for design and control purposes. Multi-hole injectors with counter-bored nozzle are the standard for Gasoline Direct Injection (GDI) applications and the Spray-G injector from the Engine Combustion Network (ECN) is considered the reference for numerical studies, thanks to the availability of extensive experimental data. In this work, the behavior of the Spray-G injector is simulated in a constant volume chamber, ranging from sub-cooled (nominal G) to flashing conditions (G2), validating the models on Diffused Back Illumination and Phase Doppler Anemometry data collected in vaporizing inert conditions.

The combustion characteristics of hydrogen-air mixtures have significance significant impact on the performance and control of hydrogen-fueled internal combustion engines and the combustion velocity is an important parameter in characterizing the combustion characteristics of the mixture. A four-cylinder hydrogen internal combustion engine was used to study hydrogen combustion; the combustion characteristics of a hydrogen mixture were experimentally studied in a constant-volume incendiary bomb, and the turbulent premixed combustion characteristics of hydrogen were calculated and analyzed. Turbulent hydrogen combustion comes under the folded laminar flame model. The turbulent combustion velocity in lean hydrogen combustion is related not only to the turbulent velocity and the laminar burning velocity, but also to the additional turbulence term caused by the instability of the flame.

Cavitation plays a significant role in the spray characteristics and the subsequent mixing and combustion process in engines. Cavitation has beneficial effects on the development of the fuel sprays by improving injection velocity and promoting primary break-up. On the other hand, intense pressure peaks induced by the vapor collapse may lead to erosion damage and severe degradation of the injector performance. In the present paper, the transient cavitating flow in the injector-like geometry was investigated using the modified turbulence model and cavitation criterion. A local density correction was used in the Reynolds-averaged Navier-Stokes turbulence model to reduce the turbulent viscosity, which facilitates the cavitation development. The turbulent stress was also considered in the cavitation inception stage. The modified model is capable of reproducing the cavitating flow with an affordable computational cost.

Recent research has shown that butanol, instead of ethanol, has the potential of introducing a more suitable blend in diesel engines. This is because butanol has properties similar to current transportation fuels in comparison to ethanol. However, the main downside is the high cost of the butanol production process. Acetone-butanol-ethanol (ABE) is an intermediate product of the fermentation process of butanol production. By eliminating the separation and purification processes, using ABE directly in diesel blends has the potential of greatly decreasing the overall cost for fuel production. This could lead to a vast commercial use of ABE-diesel blends on the market. Much research has been done in the past five years concerning spray and combustion processes of both neat ABE and ABE-diesel mixtures. Additionally, different compositions of ABE mixtures had been characterized with a similar experimental approach.

Butanol has proved to be a very promising alternative fuel in recent years. The production of bio-butanol, typically done using the acetone-butanol-ethanol (ABE) fermentation process is expensive and consumes a lot of energy. Hence it is of interest to study the intermediate fermentation product, i.e. water-containing ABE as a potential fuel. The combustion and emissions performance of ABE29.5W0.5 (29.5 vol.% ABE, 0.5 vol.% water and gasoline blend), ABE30 (30 vol.% ABE and gasoline blend) and ABE0 (pure gasoline) were investigated in this study. The results showed that ABE29.5W0.5 enhanced engine torque by 9.6%-12.7% and brake thermal efficiency (BTE) by 5.2%-11.6% compared to pure gasoline, respectively. ABE29.5W0.5 also showed similar brake specific fuel consumption (BSFC) relative to pure gasoline.

Ethanol is the most widely used renewable fuel in the world now. Compared to ethanol, butanol is another very promising renewable fuel for internal combustion engines. It is less corrosive, and has higher energy density, lower vapor pressure and lower solubility in water. However, the use of Acetone-Butanol-Ethanol (ABE), an intermediate product in ABE fermentation, presents a cost advantage over ethanol and butanol and has attracted much attention recently. In this study, three high-alcohol-content gasoline blends (85% vol. of ethanol, butanol and ABE, referred as E85, B85 and ABE85, respectively) were investigated in a port-injection spark-ignition engine. ABE has a component ratio of 3:6:1. In addition, pure gasoline was also tested as a baseline for comparison. All fuels were tested under the same conditions (1200 RPM, Φ = 0.83−1.25, BMEP = 3 bar).

In the new combustion strategies such as RCCI and dual-fuel combustion, the diesel pilot injection plays a pivotal role as it determines the ignition characteristics of the mixture and ultimately the combustion and emission performance. In this regard, equivalence ratio distribution resulted from the pilot injection becomes very important. In this work, computation study is carried out using KIVA-3V to simulate the engine compression stroke from intake valve close (IVC) to close to TDC so as to investigate the impact of piston geometry, injection start timing and flow initialization on the equivalence ratio distribution from a pilot injection in HSDI engine.