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Butanol, which is a renewable biofuel, has been regarded as a promising alternative fuel for internal combustion engines. When blended with diesel and applied to pilot ignited natural gas engines, butanol has the capability to achieve lower emissions without sacrifice on thermal efficiency. However, high blend ratio of butanol is limited by its longer ignition delay caused by the higher latent heat and higher octane number, which restricts the improvement of emission characteristics. In this paper, the potential of increasing butanol blend ratio by adding hot exhaust gas recirculation (EGR) is investigated. 3D CFD model based on a detailed kinetic mechanism was built and validated by experimental results of natural gas engine ignited by diesel/butanol blends. The effects of hot EGR is then revealed by the simulation results of the combustion process, heat release traces and also the emissions under different diesel/butanol blend ratios.

Alcohols, because of their potential to be produced from renewable sources and their characteristics suitable for clean combustion, are considered potential fuels which can be blended with fossil-based gasoline for use in internal combustion engines. As such, n-butanol has received a lot of attention in this regard and has shown to be a possible alternative to pure gasoline. The main issue preventing butanol's use in modern engines is its relatively high cost of production. Acetone-Butanol-Ethanol (ABE) fermentation is one of the major methods to produce bio-butanol. The goal of this study is to investigate the combustion characteristics of the intermediate product in butanol production, namely ABE, and hence evaluate its potential as an alternative fuel. Acetone, n-butanol and ethanol were blended in a 3:6:1 volume ratio and then splash blended with pure ethanol-free gasoline with volumetric ratios of 0%, 20%, 40% to create various fuel blends.

In order to comply with the stringent emission regulations, many researchers have been focusing on diesel-compressed natural gas (CNG) dual fuel operation in compression ignition (CI) engines. The diesel-CNG dual fuel operation mode has the potential to reduce both the soot and NOx emissions; however, the thermal efficiency is generally lower than that of the pure diesel operation, especially under the low and medium load conditions. The current experimental work investigates the potential of using diesel-1-butanol blends as the pilot fuel to improve the engine performance and emissions. Fuel blends of B0 (pure diesel), B10 (90% diesel and 10% 1-butanol by volume) and B20 (80% diesel and 20% 1-butanol) with 70% CNG substitution were compared based on an equivalent input energy at an engine speed of 1200 RPM. The results indicated that the diesel-1-butanol pilot fuel can lead to a more homogeneous mixture due to the longer ignition delay.

Dual-fuel combustion combining a premixed charge of compressed natural gas (CNG) and a pilot injection of diesel fuel offer the potential to reduce diesel fuel consumption and drastically reduce soot emissions. In this study, dual-fuel combustion using methane ignited with a pilot injection of No. 2 diesel fuel, was studied in a single cylinder diesel engine with optical access. Experiments were performed at a CNG substitution rate of 70% CNG (based on energy) over a wide range of equivalence ratios of the premixed charge, as well as different diesel injection strategies (single and double injection). A color high-speed camera was used in order to identify and distinguish between lean-premixed methane combustion and diffusion combustion in dual-fuel combustion. The effect of multiple diesel injections is also investigated optically as a means to enhance flame propagation towards the center of the combustion chamber.

Butanol has proved to be a very promising alternative fuel in recent years. The production of bio-butanol, typically done using the acetone-butanol-ethanol (ABE) fermentation process is expensive and consumes a lot of energy. Hence it is of interest to study the intermediate fermentation product, i.e. water-containing ABE as a potential fuel. The combustion and emissions performance of ABE29.5W0.5 (29.5 vol.% ABE, 0.5 vol.% water and gasoline blend), ABE30 (30 vol.% ABE and gasoline blend) and ABE0 (pure gasoline) were investigated in this study. The results showed that ABE29.5W0.5 enhanced engine torque by 9.6%-12.7% and brake thermal efficiency (BTE) by 5.2%-11.6% compared to pure gasoline, respectively. ABE29.5W0.5 also showed similar brake specific fuel consumption (BSFC) relative to pure gasoline.

Ethanol is the most widely used renewable fuel in the world now. Compared to ethanol, butanol is another very promising renewable fuel for internal combustion engines. It is less corrosive, and has higher energy density, lower vapor pressure and lower solubility in water. However, the use of Acetone-Butanol-Ethanol (ABE), an intermediate product in ABE fermentation, presents a cost advantage over ethanol and butanol and has attracted much attention recently. In this study, three high-alcohol-content gasoline blends (85% vol. of ethanol, butanol and ABE, referred as E85, B85 and ABE85, respectively) were investigated in a port-injection spark-ignition engine. ABE has a component ratio of 3:6:1. In addition, pure gasoline was also tested as a baseline for comparison. All fuels were tested under the same conditions (1200 RPM, Φ = 0.83−1.25, BMEP = 3 bar).

Due to the increasing consumption of fossil fuels, alternative fuels in internal combustion engines have attracted a lot of attention in recent years. Ethanol is the most common alternative fuel used in spark ignition (SI) engines due to its advantages of biodegradability, positively impacting emissions reduction as well as octane number improvement. Meanwhile, acetone is well-known as one of the industrial waste solvents for synthetic fibers and most plastic materials. In comparison to ethanol, acetone has a number of more desirable properties for being a viable alternative fuel such as its higher energy density, heating value and volatility.

Methanol has been regarded as a potential transportation fuel due to its advanced combustion characteristics and flexible source. However, it is suffering from misfire and high HC emissions problems under cold start and low load conditions either on methanol SI engine or on methanol/diesel dual fuel engine. Hydrogen is a potential addition that can enhance the combustion of methanol due to its high flammability and combustion stability. In the current work, the effect of hydrogen fraction on the laminar flame characteristics of methanol- hydrogen-air mixture under varied equivalence ratio was investigated on a constant volume combustion chamber system coupled with a schlieren setup. Experiments were performed over a wide range of equivalence ratio of the premixed charge, varied from 0.8 to 1.4, as well as different hydrogen fraction, 0%, 5%, 10%, 15% and 20% (n/n). All tests were carried out at fixed temperature and pressure of 400K and 0.1MPa.

CNG-diesel dual fuel combustion mode has been regarded as a practical operation strategy because it not only can remain high thermal efficiency but also make full use of an alternative fuel, natural gas. However, it is suffering from misfire and high HC emissions under cold start and low load conditions. As known, hydrogen has high flammability. Thus, a certain proportion of hydrogen can be added in the natural gas (named HCNG) to improve combustion performance. In this work, the effect of hydrogen volume ratio on combustion characteristics was investigated on an optically accessible single-cylinder CNG-diesel engine using a Phantom v7.3 color camera. HCNG was compressed into the tank under different hydrogen volume ratios varied from 0% to 30%, while the energy substitution rate of` HCNG remained at 70%.

An experimental investigation was conducted using a Ford single-cylinder spark-ignition research engine to compare the performance and emissions of neat n-butanol fuel to that of gasoline and ethanol. Measurements of brake torque and exhaust gas temperature along with in-cylinder pressure traces were used to study the performance of the engine and measurements of emissions of unburned hydrocarbons, carbon monoxide, and nitrogen oxide ere used to compare the three fuels in terms of combustion byproducts. It was found that gasoline and butanol are closest in engine performance with butanol producing slightly less brake torque. Exhaust gas temperature and nitrogen oxide measurements show that butanol combusts at a lower peak temperature. Of particular interest were the emissions of unburned hydrocarbons which were between two and three times those of gasoline suggesting that butanol is not atomizing as effectively as gasoline and ethanol.

A single nozzle port fuel injector was modified to apply electrostatic charge to the fuel stream, with the intention of studying electrostatically assisted sprays in a practical, port-injected engine. The modifications were kept external to the injector and involved placing an electrode and insulating liner over the tip of the injector. The performance of the modified injector, which combined pressure driven and electrostatic atomization, was characterized in three phases: the injector sprays themselves were studied, combustion of charged fuel droplets was studied, and the injector was installed and tested on a single cylinder spark ignition engine. In the first phase, Fraunhofer diffraction measurements of droplet size, and particle image velocimetry measurements of droplet velocity were performed. The charge transferred by the sprays was measured using an electrometer, and typical forces exerted on droplets in the sprays were estimated.

To face the challenges of fossil fuel shortage and air pollution problems, there is growing interest in the potential usage of alternative fuels such as bio-ethanol and bio-butanol in internal combustion engines. The literature shows that the acetone in the Acetone-Butanol-Ethanol (ABE) blends plays an important part in improving the combustion performance and emissions, owing to its higher volatility. In order to study the effects of acetone addition into commercial gasoline, this study focuses on the differences in combustion, performance and emission characteristics of a port-injection spark-ignition engine fueled with pure gasoline (G100), ethanol-containing gasoline (E30) and acetone-ethanol-gasoline blends (AE30 at A:E volumetric ratio of 3:1). The tests were conducted at 1200RPM with the default calibration (for gasoline), at 3 bar and 5 bar BMEP under various equivalence ratios.

Alcohols, especially n-butanol, have received a lot of attention as potential fuels and have shown to be a possible alternative to pure gasoline. The main issue preventing butanol's use in modern engines is its relatively high cost of production. ABE, the intermediate product in the ABE fermentation process for producing bio-butanol, is being studied as an alternative fuel because it not only preserves the advantages of oxygenated fuels, but also lowers the cost of fuel recovery for individual component during fermentation. With the development of advanced ABE fermentation technology, the volumetric percentage of acetone, butanol and ethanol in the bio-solvents can be precisely controlled. In this respect, it is desirable to estimate the performance of different ABE blends to determine the best blend and optimize the production process accordingly.

This work presents a comprehensive computational study of diesel - natural gas (NG) dual fuel engine. A complete computational model is developed for the operation of a diesel - NG dual fuel engine modified from an AVL 5402 single cylinder diesel test engine. The model is based on the KIVA-3V program and includes customized sub-models. The model is validated against test cell measurements of both pure diesel and dual fuel operation. The effects of NG on ignition and combustion in dual fuel operation are analyzed in detail. Zero-dimensional computations with a diesel surrogate reaction mechanism are conducted to discover the effects of NG on ignition and combustion and to reveal the fundamental chemical mechanisms behind such effects. Backed by the detailed theoretical analysis, the engine operation parameters are optimized with genetic algorithm (GA) for the dual fuel operation of the modified AVL 5402 test engine.

Bio-butanol has been widely investigated as a promising alternative fuel. However, the main issues preventing the industrial-scale production of butanol is its relatively low production efficiency and high cost of production. Acetone-butanol-ethanol (ABE), the intermediate product in the ABE fermentation process for producing bio-butanol, has attracted a lot of interest as an alternative fuel because it not only preserves the advantages of oxygenated fuels, but also lowers the cost of fuel recovery for individual component during fermentation. If ABE could be directly used for clean combustion, the separation costs would be eliminated which save an enormous amount of time and money in the production chain of bio-butanol.

The combustion and emission characteristics of a diesel engine running on butanol-diesel blends were investigated in this study. The blending ratio of n-butanol to diesel was varied from 0 to 40 vol% using an increment of 10 vol%, and each blend was tested on a 2.7 L V6 common rail direction injection diesel engine equipped with an EGR system. The test was carried out under two engine loads at a constant engine speed, using various combinations of EGR ratios and injection timings. Test results indicate that n-butanol addition to engine fuel is able to substantially decrease soot emission from raw exhaust gas, while the change in NOx emissions varies depending on the n-butanol content and engine operating conditions. Increasing EGR ratio and retarding injection timing are effective approaches to reduce NOx emissions from combustion of n-butanol-diesel blends.

Droplets impacting onto the heated surface is a typical phenomenon either in CI engines or in GDI SI engines, which is regarded significant for their air-fuel mixing. Meanwhile, alcohols including ethanol and butanol, has been widely studied as internal combustion engine alternative fuels due to their excellent properties. In this paper, under different component ratio conditions, the ethanol-butanol droplet impacting onto the heated aluminum surface has been studied experimentally. The falling height of the droplets were set at 5cm. A high-speed camera, set at 512×512pixels, 5000 fps and 20 μs of exposure time, was used to visualize the droplet behavior impinging onto the hot aluminum surface. The impact regimes of the binary droplet were identified. The result showed that the Leidenfrost temperature of droplets was affected by the ratio of ethanol to butanol. The higher the content of butanol in the droplet, the higher the Leidenfrost temperature.