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Several predictive equations based on the chemical composition of gasoline have been shown to estimate the particulate emissions of light-duty, internal combustion engine (ICE) powered vehicles and are reviewed in this paper. Improvements to one of them, the PEISimDis equation are detailed herein. The PEISimDis predictive equation was developed by General Motor’s researchers in 2022 based on two laboratory gas chromatography (GC) analyses; Simulated Distillation (SimDis), ASTM D7096 and Detailed Hydrocarbon Analysis (DHA), ASTM D6730. The DHA method is a gas chromatography mass spectroscopy (GC/MS) methodology and provides the detailed speciation of the hundreds of hydrocarbon species within gasoline. A DHA’s aromatic species from carbon group seven through ten plus (C7 – C10+) can be used to calculate a Particulate Evaluation Index (PEI) of a gasoline, however this technique takes many hours to derive because of its long chromatography analysis time.

The goal of this study was to generate exhaust fast gas data that could be used to identify phenomena that occur before, during, and after stochastic preignition (SPI), also called low-speed preignition (LSPI), events. Crank angle resolved measurement of exhaust hydrocarbons, NO, CO, and CO2 was performed under engine conditions prone to these events. Fuels and engine operating strategies were varied in an attempt to understand similarities and differences in SPI-related behavior that may occur between them. Several different uncommon (typically occurring in less than 1% of engine cycles) features of the fast gas data were identified, and the correlations between them and SPI events were explored. Although the thresholds used to define and identify these observations were arbitrary, they provided a practical means of identifying behavior in the fast gas data and correlating it to SPI occurrence.

In this multi-phase study, fuel and lubricant effects on stochastic preignition (SPI) were examined. First, the behavior of fuels for which SPI data had previously been collected were characterized in terms of their combustion and emissions behavior, and correlations between these characteristics and their SPI behavior were examined. Second, new SPI data was collected for a matrix of fuels that was constructed to test and confirm hypotheses that resulted from interpretation of the earlier data in the study and from data in open literature. Specifically, the extent to which the presence of heavy components in the fuel affected SPI propensity, and the extent to which flame initiation propensity affected SPI propensity, were examined. Finally, the interaction of fuels with lubricants expected to exhibit a range of SPI propensities was examined.

In this work, an experimental and analysis methodology was developed to evaluate the preignition propensity of fuels and engine operating conditions in an SI engine. A heated glow plug was introduced into the combustion chamber to induce early propagating flames. As the temperature of the glowplug varied, both the fraction of cycles experiencing these early flames and the phasing of this combustion in the engine cycle varied. A statistical methodology for assigning a single-value to this complex behavior was developed and found to have very good repeatability. The effects of engine operating conditions and fuels were evaluated using this methodology. While this study is not directly studying the so-called stochastic preignition or low-speed preignition problem, it studies one aspect of that problem in a very controlled manner.

Automakers are designing smaller displacement engines with higher power densities to improve vehicle fuel economy, while continuing to meet customer expectations for power and drivability. The specific power produced by the spark-ignited engine is constrained by knock and fuel octane. Whereas the lowest octane rating is 87 AKI (antiknock index) for regular gasoline at most service stations throughout the U.S., 85 AKI fuel is widely available at higher altitudes especially in the mountain west states. The objective of this study was to explore the effect of gasoline octane rating on the net power produced by modern light duty vehicles at high altitude (1660 m elevation). A chassis dynamometer test procedure was developed to measure absorbed wheel power at transient and stabilized full power operation. Five vehicles were tested using 85 and 87 AKI fuels.

A computational and experimental study was performed to characterize the flow within a gasoline injector and the ensuing sprays. The computations included the effects of turbulence, cavitation, flash-boiling, compressibility, and the presence of non-condensible gases. The flow domain corresponded to the Engine Combustion Network's Spray G, an eight-hole counterbore injector operating in a variety of conditions. First, a rate tube method was used to measure the rate of injection, which was then used to define inlet boundary conditions for simulation. Correspondingly, injection under submerged conditions was simulated for direct comparison with experimental measurements of discharge coefficient. Next, the internal flow and external spray into pressurized nitrogen were simulated under the base spray G conditions. Finally, injection under flashing conditions was simulated, where the ambient pressure was below the vapor pressure of the fuel.

Corrosion inhibitors (CIs) have been used for years to protect the supply and distribution hardware used for transportation of fuel from refineries and to buffer the potential organic acids present in an ethanol blended fuel to enhance storage stability. The impact of these inhibitors on spark-ignition engine fuel systems, specifically intake valve deposits, is known and presented in open literature. However, the relationship of the corrosion inhibitors to the powertrain intake valve deposit performance is not understood. This paper has two purposes: to present and discuss a second market place survey of corrosion inhibitors and how they vary in concentration in the final blended fuel, specifically E85 (Ethanol Fuel Blends); and, to show how the variation in the concentrations of the components of the CIs impacts the operation and performance of vehicles, specifically, the effects on intake valve deposit formation.

The light-medium load operating range (4-7 bar net IMEP) presents many challenges for advanced low temperature combustion strategies utilizing low cetane fuels (specifically, 87-octane gasoline) in light-duty, high-speed engines. The overly lean overall air-fuel ratio (Φ≺0.4) sometimes requires unrealistically high inlet temperatures and/or high inlet boost conditions to initiate autoignition at engine speeds in excess of 1500 RPM. The objective of this work is to identify and quantify the effects of variation in input parameters on overall engine operation. Input parameters including inlet temperature, inlet pressure, injection timing/duration, injection pressure, and engine speed were varied in a ~0.5L single-cylinder engine based on a production General Motors 1.9L 4-cylinder high-speed diesel engine.

The U.S. Renewable Fuel Standard 2 (RFS2) mandates the use of advanced renewable fuels such as cellulosic ethanol to be blended into gasoline in the near future. As such, determining the impact of these new fuel blends on vehicle performance is important. Therefore, General Motors conducted engine dynamometer evaluations on the impact of cellulosic ethanol blends on port fuel injected (PFI) intake valve deposits and gasoline direct injected (GDI) fuel injector plugging. Chemical analysis of the test fuels was also conducted and presented to support the interpretation of the engine results. The chemical analyses included an evaluation of the specified fuel parameters listed in ASTM International's D4806 denatured fuel ethanol specification as well as GC/MS hydrocarbon speciations to help identify any trace level contaminant species from the new ethanol production processes.

Biodiesel, a fuel comprised of mono-alkyl esters of long-chain fatty acids also known as Fatty Acid Methyl Esters(FAME), derived from vegetable oils or animal fats, has become an important commercial marketplace automotive fuel in the United States (US) and around the world over last few years. FAME biodiesels have many chemical and physical property differences compared to conventional petroleum based diesel fuels. Also, the properties of biodiesel vary based on the feedstock chosen for biodiesel production. One of the key differences between petroleum diesel fuels and biodiesel is the energy content. The energy content, or heating value, is an important property of motor fuel, since it directly affects the vehicle fuel economy. While the energy content can be measured by combustion of the fuel in a bomb calorimeter, this analytical laboratory testing is time consuming and expensive.

An investigation of high speed direct injection (DI) compression ignition (CI) engine combustion fueled with gasoline injected using a triple-pulse strategy in the low temperature combustion (LTC) regime is presented. This work aims to extend the operation ranges for a light-duty diesel engine, operating on gasoline, that have been identified in previous work via extended controllability of the injection process. The single-cylinder engine (SCE) was operated at full load (16 bar IMEP, 2500 rev/min) and computational simulations of the in-cylinder processes were performed using a multi-dimensional CFD code, KIVA-ERC-Chemkin, that features improved sub-models and the Chemkin library. The oxidation chemistry of the fuel was calculated using a reduced mechanism for primary reference fuel combustion chosen to match ignition characteristics of the gasoline fuel used for the SCE experiments.

A combination of laboratory reactor measurements and vehicle FTP testing has been combined to demonstrate a method for diagnosing the formation of NO2 from a diesel oxidation catalyst (DOC). Using small cores from a production DOC and simulated diesel exhaust, the laboratory reactor experiments are used to support a model for DOC chemical reaction kinetics. The model we propose shows that the ability to produce NO2 is chemically linked to the ability of the catalyst to oxidize hydrocarbon (HC). For thermally damaged DOCs, loss of the HC oxidation function is simultaneous with loss of the NO2 production function. Since HC oxidation is the source of heat generated in the DOC under regeneration conditions, we conclude that a diagnostic of the DOC exotherm is able to detect the failure of the DOC to produce NO2. Vehicle emissions data from a 6.6 L Duramax HD pick-up with DOC of various levels of thermal degradation is provided to support the diagnostic concept.

A comprehensive experimental and theoretical approach was undertaken to understand the phenomenon of pre-ignition and to assess parameters to improve or even eliminate it completely. Oil mixing with fuel was identified as the leading theory of self ignition of the fuel. End of compression temperature has to meet a minimum level for pre-ignition to take place. In this work a comprehensive list of parameters were identified that have a direct and crucial role in the onset of pre-ignition including liner wetting, injection targeting, stratification, mixture motion and oil formulation. Many secondary effects were identified including ring dynamics, ring tension, spark plug electrode temperature and coolant temperature. CFD has been extensively used to understand test results including wall film, A/F ratio distribution and temperature at the end of compression when looked at in the context of fuel evaporation and mixing.

Corrosion inhibitors (CIs) have been used for years to protect the supply and distribution hardware used for transportation of fuel from refineries. The impact of these inhibitors on spark ignited fuel systems, specifically intake valve deposits, is known and presented in open literature. However, the relationship of the additive concentrations to the powertrain intake valve deposit performance is not understood. This paper has two purposes: to present and discuss a market place survey of corrosion inhibitors and how they vary in concentration in the final blended fuel; and, to show how the variation in the concentrations of the CIs impact the operation and performance of vehicles, specifically, the effects on intake valve deposit formation. Commercially available corrosion inhibitor packages for both gasoline and ethanol blended fuels, specifically E85 fuels, were studied for their chemical compositions, and their impact on valves for a port fuel injection (PFI) engine.

Engine knock has been studied extensively over the years. Its undesired effects on drivability, its potential to damage an engine, and its impact on limiting the compression ratio are the main reasons why it remains a current topic of research. This paper focuses on exploiting the connection between auto-ignition and knock. A new method based on the frequency analysis of the heat release traces is proposed to detect and estimate auto-ignition/knock robustly. Filtering the heat release signal with the appropriate bandwidth is crucial to avoid misdetection. The filter settings used in this paper are found using spectral analysis of the heat release signal. By using the proposed method, it is possible to detect auto-ignition/knock even under the presence of undesired sensor resonance effects and noise from mechanical and electrical sources.

Ethanol for use in automotive fuels can be made from renewable feedstocks, which contributes to its increased use in recent years. There are many differences in physical and chemical properties between ethanol and petrochemicals refined from fossil oil. One of the differences is its energy content. The energy content, or heating value, is an important property of motor fuel, since it directly affects vehicle fuel economy. While the energy content can be measured by combustion of the fuel in a bomb, the test is time-consuming and expensive. It is generally satisfactory and more convenient to estimate that property from other commonly-measured fuel properties. Several standardized empirical methods have been developed in the past for estimating the energy content of hydrocarbon fuels such as gasoline, diesel fuel, and jet fuel.

A laser sheet imaging system with Mie-scattering and Laser Induced Fluorescence (LIF) was used to investigate the spray characteristics of gasoline, methanol and ethanol fuels. A range of conditions found in today's gasoline engines were investigated including that observed during engine cold-start. Both a swirl injector and a multi-hole fuel injector were examined for each of the three fuels. A combination of the second harmonic (532 nm) and the fourth harmonic (266 nm) was generated simultaneously using a Nd:YAG laser system to illuminate the spray. The Mie-scattering technique was used to characterize the liquid phase of the spray while the LIF technique was used to detect a combination of liquid and vapor phases. While gasoline naturally fluoresced, the dopant TEA was added to the methanol and ethanol fuels as a fuel tracer. The Mie-scattering and LIF signals were captured simultaneously using a CCD camera along with an image doubler.

Economic market forces and increasing environmental awareness of gasoline have led to interest in developing alternatives to gasoline, and extending the current global supply for transportation fuels. One viable strategy is the use of alternative alcohol fuels for combustion engines, with ethanol and methanol in various concentration ranges proposed and in-use. Utilizing and citing data from this review, a comprehensive overview of the materials selection and engineering challenges facing metals, plastics and elastomers are presented. The engineering approach and solution-sets discussed will focus on production feasibility and implementation. The effects from the fuel chemistry and quality of fuel ethanol produced on the related vehicle components are discussed.

About 10 years ago in the US, an automotive OEM consortium formed the Oxygenated Fuels Task Force which in turn created the SAE Cooperative Research Project Group 2 to develop a simple rational method for qualifying materials. At that time the focus was Methanol/Gasoline blends. This work resulted in SAE J1681, Gasoline/Methanol Mixtures for Materials Testing. Recently this document was rewritten to make it the single, worldwide, generic source for fuel system test fluids. The paper will describe the rationale for selecting the fuel surrogate fluids and why this new SAE standard should replace all existing test fuel or test fluid standards for fuel system materials testing.