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Electric vehicles (EVs) are a promising and proven technology for achieving sustainable mobility with zero carbon emissions, very low noise pollution, and reducing the dependency on fossil fuels. Global EV sales have been increasing by ~110 % since 2015, with a significant rise in 2021 (~6.75 mils EV registered) mainly led by China, the US, and Europe, amplifying the EV market share to 8.3% compared to 4.2% in 2020. Future developments aimed at designing better batteries and charging technologies that reduce charging time, reduce initial battery cost, and increased flexibility. In India, EVs are emerging significantly due to stringent Carbon di Oxide (CO2) reduction drives, increasing crude oil prices, and the availability of cheaper renewable energy. Leveraging government promotional policies, evolving the entire ecosystem, globally advantageous manufacturing costs, and competitive engineering skills form the perfect blend for India.

In order to decarbonize and lower the overall emissions of the transport sector, immediate and cost-effective powertrain solutions are needed. Natural gas offers the advantage of a direct reduction of carbon dioxide (CO2) emissions due to its better Carbon to Hydrogen ratio (C/H) compared to common fossil fuels, e.g. gasoline or diesel. Moreover, an optimized engine design suiting the advantages of natural gas in knock resistance and lean mixtures keeping in mind the challenges of power density, efficiency and cold start manoeuvres. In the public funded project MethMag (Methane lean combustion engine) a gasoline fired three-cylinder-engine is redesigned based on this change of requirements and benchmarked against the previous gasoline engine.

DME has been considered an alternative fuel to diesel fuel with promising benefits because of its high reactivity and volatility. Research shows that an engine fueled with DME will produce zero smoke emissions. However, the storage and the handling of the fuel are underlying difficulties owing to its high vapour pressure (530 kPa @ 20 °C). In lieu, OME1 fuel, a derivate of DME, offers advantages exhibited with DME fuel, all the while being a liquid fuel for engine application. In this work, engine tests are performed to realize the combustion behaviour of DME and OME1 fuel on a single-cylinder research engine with a compression ratio of 9.2:1. The dilution ratio of the mixture is progressively increased in two manners, allowing more air in the cylinder and applying exhaust gas recirculation (EGR). The high reactivity of DME suits the capability to be used in compression ignition combustion whereas OME1 must be supplied with a supplemental spark to initiate the combustion.

The lack of electrical conductivity on materials, which are used in automotive fuel systems, can lead to electrostatic charges buildup in the components of such systems. This accumulation of energy can reach levels that exceed their capacity to withstand voltage surges, which considerably increases the risk of electrical discharges or sparks. Another important factor to consider is the conductivity of the commercially available fuels, such as biodiesel, which contributes to dissipate these charges to a proper grounding point in automobiles. From 2013, the diesel regulation in Brazil have changed and the levels of sulfur in the composition of diesel were reduced considerably, changing its natural characteristic of promoting electrostatic discharges, becoming more insulating.

The new European test procedure, called the worldwide harmonized light vehicle test procedure (WLTP), deviates in some details from the current NEDC-based test which will have an impact on the determination of the official EU fuel consumption values for the new vehicles. The adaptation to the WLTP faces automakers with new challenges for meeting the stringent EU fuel consumption and CO2 emissions standards. This paper investigates the main changes that the new test implies to a mid-size sedan electrified vehicle design and quantifies their impact on the vehicles fuel economy. Three common electrified powertrain architectures including series, parallel P2, and powersplit are studied. A Pontryagin’s Minimum Principle (PMP) optimization-based energy management control strategy is developed to evaluate the energy consumption of the electrified vehicles in both charge-depleting (CD) and charge-sustaining (CS) modes.

Medium duty vehicles come in many design variations, which makes testing them all for CO2 impractical. As a result there are multiple ways of reporting CO2 emissions. Actual tests may be performed, data substitution may be used, or CO2 values may be estimated using an analytical correction. The correction accounts for variations in road load force coefficients (f0, f1, f2), weight, and axle ratio. The EPA Analytically Derived CO2 equation (EPA ADC) was defined using a limited set of historical data. The prediction error is shown to be ±130 g/mile and the sensitivities to design variables are found to be incorrect. Since the absolute CO2 is between 500 and 1,000 g/mi, the equation has limited usefulness. Previous work on light duty vehicles has demonstrated a linear relationship between vehicle fuel consumption, powertrain properties and total vehicle work. This relationship improves the accuracy and avoids co-linearity and non-orthogonality of the input variables.

During the course of emissions and fuel economy (FE) testing, vehicles that are calibrated to meet Tier 3 emissions requirements currently must demonstrate compliance on Tier 3 E10 fuel while maintaining emissions capability with Tier 2 E0 fuel used for FE label determination. Tier 3 emissions regulations prescribe lower sulfur E10 gasoline blends for the U.S. market. Tier 3 emissions test fuels specified by EPA are required to contain 9.54 volume % ethanol and 8-11 ppm sulfur content. EPA Tier 2 E0 test fuel has no ethanol and has nominal 30 ppm sulfur content. Under Tier 3 rules, Tier 2 E0 test fuel is still used to determine FE. Tier 3 calibrations can have difficulty meeting low Tier 3 emissions targets while testing with Tier 2 E0 fuel. Research has revealed that the primary cause of the high emissions is deactivation of the aftertreatment system due to sulfur accumulation on the catalysts.

Future LEV-III tailpipe (TP) emission regulations pose an enormous challenge forcing the fleet average of light-duty vehicles produced in the 2025 model year to perform at the super ultralow emission vehicle (SULEV-30) certification levels (versus less than 20% produced today). To achieve SULEV-30, regulated TP emissions of non-methane organic gas (NMOG) hydrocarbons (HCs) and oxygenates plus oxides of nitrogen (NOx) must be below a combined 30 mg/mi (18.6 mg/km) standard as measured on the federal emissions certification cycle (FTP-75). However, when flex-fuel vehicles use E85 fuel instead of gasoline, NMOG emissions at cold start are nearly doubled, before the catalytic converter is active. Passive HC traps (HCTs) are a potential solution to reduce TP NMOG emissions. The conventional HCT design was modified by changing the zeolite chemistry so as to improve HC retention coupled with more efficient combustion during the desorption phase.

In the development of HC traps (HCT) for reducing vehicle cold start hydrocarbon (HC)/nitrogen oxide (NOx) emissions, zeolite-based adsorbent materials were studied as key components for the capture and release of the main gasoline-type HC/NOx species in the vehicle exhaust gas. Typical zeolite materials capture and release certain HC and NOx species at low temperatures (<200°C), which is lower than the light-off temperature of a typical three-way catalyst (TWC) (≥250°C). Therefore, a zeolite alone is not effective in enhancing cold start HC/NOx emission control. We have found that a small amount of Pd (<0.5 wt%) dispersed in the zeolite (i.e., BEA) can significantly increase the conversion efficiency of certain HC/NOx species by increasing their release temperature. Pd was also found to modify the adsorption process from pure physisorption to chemisorption and may have played a role in the transformation of the adsorbed HCs to higher molecular weight species.

Fuel cell vehicles are entering the automotive market with significant potential benefits to reduce harmful greenhouse emissions, facilitate energy security, and increase vehicle efficiency while providing customer expected driving range and fill times when compared to conventional vehicles. One of the challenges for successful commercialization of fuel cell vehicles is transitioning the on-board fuel system from liquid gasoline to compressed hydrogen gas. Storing high pressurized hydrogen requires a specialized structural pressure vessel, significantly different in function, size, and construction from a gasoline container. In comparison to a gasoline tank at near ambient pressures, OEMs have aligned to a nominal working pressure of 700 bar for hydrogen tanks in order to achieve the customer expected driving range of 300 miles.

Phthalates have been extensively used in rubbers formulation as plasticizer additive for PVC and NBR promoting processing parameters or for cost reduction. The most commonly used plasticizer in PVC compounds was di-2-ethylhexyl phthalate (DEHP) currently not recommend due toxicity. DEHP is listed as prohibited to the Global Automotive Declarable Substance List (GADSL). Phthalates alternatives are already available but the compatibility in automotive fuel system with biodiesel was not extensively understood. This aspect is important since plasticizer may migrate and change rubber properties. Tri-2-ethylhexyl trimellitate (TOTM) and di-2-ethylhexyl terephthalate (DEHT) were selected in this work as alternative additives to a rubber formulation since is not listed to GADSL and have good potential as plasticizer.

This study investigates a system and a method to enhance fuel cell vehicle robustness during vehicle start/stop cycle by mitigating cathode half-cell potential spikes. Multiple dynamic hydrogen reference electrodes were installed in the fuel cell under test to observe changes of anode and cathode half-cell potentials during simulated system startup and shutdown conditions. Multiple reference electrodes were used to measure localized anode and cathode half-cell potentials in an active area. A 1.4-1.8 V half-cell potential spike at the cathode in the startup condition was observed due to a hydrogen/air boundary formed within the anode flow field. Various system solutions have been studied to contain the cathode half-cell potential spikes, such as purging with inert gas, or inserting a shunt resistor as a shorting component between the anode and the cathode. In this study, a method of connecting an electrical load prior to flowing hydrogen fuel to the cell was tested.

Auto stop-start (Engine stop-start, ESS) has become a widely used feature to reduce fuel consumption and CO2 emissions particularly in congested cities. Typically, vehicles equipped with such systems include two DC power sources that are coupled in parallel: a primary and a secondary power source. The primary power source supplies energy to the starter to crank the engine, while the secondary power source supplies energy to the rest of the vehicle electric loads. During an auto-stop event, a controllable switch decouples the two power sources. Moreover, operating current, voltage and the State of Charge (SOC) are monitored to ensure enough energy for the next auto-start event. When any of these operating parameters are below the threshold values, the controllable switch opens to isolate the two batteries and then the engine is automatically started.

CO2 is an alternative to replace the conventional refrigerant (R134a) for the air-conditioning system, due to the high Global Warming Potential (GWP) of R134a. There are concerns with the use of CO2 as a refrigerant due to health risks associated with exposure to CO2, if the concentration of CO2 is over the acceptable threshold. For applications with CO2 as the refrigerant, the risk of CO2 exposure is increased due to the possibility of CO2 leakage into the cabin through the duct system; this CO2 is in addition to the CO2 generated from the respiration of the occupants. The initiation of the leak could be due to a crash event or a malfunction of the refrigerant system. In an automobile, where the interior cabin is a closed volume (with minimal venting), the increase in concentration can be detrimental to the customer but is hard to detect.

A fundamental requirement for natural gas (NG) and renewable methane (e.g. bio-methane or power-to-gas methane) as automotive fuel is reliable knock resistance; to enable optimization of dedicated NG engines with high compression ratio and high turbocharger boost (which enables considerable engine downsizing factors). In order to describe the knock resistance of NG, the Methane Number (MN) has been introduced. The lowest MN which generally can be found in any NG is 65, and the vast majority of NG (~ 99.8%) is delivered with a MN above 70. The MN of bio-methane and power-to-gas methane is usually far above 80. Thus, from an automotive point of view any methane fuel should at least provide a minimum Methane Number of 70 at any point of sale. But the European draft standard describing the automotive CNG fuel quality so far proposes a minimum MN limit of 65.

The automotive industry is rapidly expanding its Hybrid, Plug-in Hybrid and Battery Electric Vehicle product offerings in response to meet customer wants and regulatory requirements. One way for electrified vehicles to have an increasing impact on fleet-level CO2 emissions is for their sales volumes to go up. This means that electrified vehicles need to deliver a complete set of vehicle level attributes like performance, Fuel Economy and range that is attractive to a wide customer base at an affordable cost of ownership. As part of “democratizing” the Hybrid and plug-In Hybrid technology, automotive manufacturers aim to deliver these vehicle level attributes with a powertrain architecture at lowest cost and complexity, recognizing that customer wants may vary considerably between different classes of vehicles. For example, a medium duty truck application may have to support good trailer tow whereas a C-sized sedan customer may prefer superior city Fuel Economy.

An experimental study of the effects of partially-oxidized biodiesel fuel on the degradation of fresh fuel was performed. A blend of soybean oil fatty acid methyl esters (FAMEs) in petroleum diesel fuel (30% v:v biodiesel, B30) was aged under accelerated conditions (90°C with aeration). Aging conditions focused on three different degrees of initial oxidation: 1) reduced oxidation stability (Rancimat induction period, IP); 2) high peroxide values (PV); and 3) high total acid number (TAN). Aged B30 fuel was mixed with fresh B30 fuel at two concentrations (10% and 30% m:m) and degradation of the mixtures at the above aging conditions was monitored for IP, PV, TAN, and FAME composition. Greater content of aged fuel carryover (30% m:m) corresponded to stronger effects. Oxidation stability was most adversely affected by high peroxide concentration (Scenario 2), while peroxide content was most reduced for the high TAN scenario (Scenario 3).

Interest in natural gas as an alternative fuel source to petroleum fuels for light-duty vehicle applications has increased due to its domestic availability and stable price compared to gasoline. With its higher hydrogen-to-carbon ratio, natural gas has the potential to reduce engine out carbon dioxide emissions, which has shown to be a strong greenhouse gas contributor. For part-load conditions, the lower flame speeds of natural gas can lead to an increased duration in the inflammation process with traditional port-injection. Direct-injection of natural gas can increase in-cylinder turbulence and has the potential to reduce problems typically associated with port-injection of natural gas, such as lower flame speeds and poor dilution tolerance. A study was designed and executed to investigate the effects of direct-injection of natural gas at part-load conditions.

The compression ratio is a strong lever to increase the efficiency of an internal combustion engine. However, among others, it is limited by the knock resistance of the fuel used. Natural gas shows a higher knock resistance compared to gasoline, which makes it very attractive for use in internal combustion engines. The current paper describes the knock behavior of two gasoline fuels, and specific incylinder blend ratios with one of the gasoline fuels and natural gas. The engine used for these investigations is a single cylinder research engine for light duty application which is equipped with two separate fuel systems. Both fuels can be used simultaneously which allows for gasoline to be injected into the intake port and natural gas to be injected directly into the cylinder to overcome the power density loss usually connected with port fuel injection of natural gas.

Dimethyl ether (DME) is an alternative to diesel fuel for use in compression-ignition engines with modified fuel systems and offers potential advantages of efficiency improvements and emission reductions. DME can be produced from natural gas (NG) or from renewable feedstocks such as landfill gas (LFG) or renewable natural gas from manure waste streams (MANR) or any other biomass. This study investigates the well-to-wheels (WTW) energy use and emissions of five DME production pathways as compared with those of petroleum gasoline and diesel using the Greenhouse gases, Regulated Emissions, and Energy use in Transportation (GREET®) model developed at Argonne National Laboratory (ANL).