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The reduction of cycle-to-cycle variations (CCV) is a prerequisite for the development and control of spark-ignition engines with increased efficiency and reduced engine-out emissions. To this end, Large-Eddy Simulations (LES) can improve the understanding of stochastic in-cylinder phenomena during the engine design process, if the employed modeling approach is sufficiently accurate. In this work, an inhouse code has been used to investigate CCV in a direct-injected spark ignition (DISI) engine under fuel-lean conditions with respect to a stoichiometric baseline operating point. It is shown that the crank angle when a characteristic fuel mass fraction is burned, e.g. MFB50, correlates with the equivalence ratio computed as a local average in the vicinity of the spark plug. The lean operating point exhibits significant CCV, which are shown to be correlated also with the in-cylinder subfilter-scale (SFS) kinetic energy.

With accelerating exhaust gas regulations in recent years, not only CO / HC / NOx but also PN regulation represented by Euro 6 d, China 6 are getting stricter. PN reduction by engine combustion technology development also progresses, but considering RDE, PN reduction by after treatment technology is also indispensable. To reduce PN exhausted from the gasoline engine, it is effective to equip GPF with a filter structure. Considering the installation of GPF in limited space, we developed a system that so far replaces the second TWC with GPF for the TWC 2 bed system. In order to replace the second TWC with GPF, we chose the coated GPF with filtering and TWC functions. Since the initial pressure drop and the catalyst amount (purification performance) of coated GPF have a conflicting relationship, we developed the coated GPF that can achieve both the low initial pressure drop and high purification performance.

In recent years along with stringent the regulations, vehicles equipped with gasoline particulate filter (GPF) have started to launch. Compared to bare GPF, coated GPF (cGPF) requires not only PN filtration efficiency, low pressure drop, but also purification performance. In the wall flow type cGPF having a complicated the pore shape, the pore structure further irregularly changes depending on the coated state of the catalyst, so it is difficult to understand the matter of in-wall. In order to advance of cGPF function, it was researched that revealing the relevance between pore structure change in the wall and GPF function. Therefore, to understand the catalyst coated state difference, cGPF of several coating methods were prepared, and their properties were evaluated by various analyses, and performance was tested.

To evaluate the relationship between the exhaust gas purification performance and the catalyst pore properties related to gas diffusion, an elementary reaction model was combined with gas diffusion into catalyst pores, referred to as the pseudo-2D gas diffusion/reaction model. It was constructed for Pt/Al2O3 + CeO2 catalyst as lean NOx catalyst. The gas diffusion was described as macro pore diffusion between the catalyst particles and meso pore diffusion within the particle. The kinetic model was composed of 26 reactions of NO/CO/O2 chemistry including 17 Pt/Al2O3 catalyst reactions and 9 CeO2 reactions. Arrhenius parameters were optimized using activity measurement results from various catalysts with various pore properties, meso pore volume and diameter, macro pore volume and diameter, particle size, and washcoat thickness. Good agreement was achieved between the measured and calculated values.

In recent years, fuel efficiency has been improved by using many technologies such as downsizing engine, turbocharger and direct injection to reduce CO2 emissions from vehicle. However, the temperature of the exhaust gas from the engines using these technologies becomes lower than that form conventional one. That increases the difficulty for three-way catalyst (TWC) to purify CO, HC and NOx enough because TWC is not warmed up just after engine starting. In order to reduce cold emission mentioned above, we have been studying the warmup strategy of which the key property is thermal mass of TWC. To achieve early warmup, thermal mass of TWC is reduced by lightening the weight of (1) substrate and (2) catalytic materials, namely washcoat amount. Along with the strategy, we have developed TWC with lightweight substrate and applied it from the 2016 model year CIVIC.

We studied a simple and cost effective controlled auto ignition (CAI) combustion engine in order to achieve simultaneous reduction of NOx and soot, which are issues in diffusion combustion. The engine type was a uniflow scavenging 2-stroke engine, and the fuel used was diesel, as is common in diesel engines. We examined the position of the injector that effectively forms the premixture and realized stable operation with diesel fuel by the low pressure fuel injection device for port fuel injection (PFI), and it was found that the CAI combustion ignition timing can be controlled through setting the air/fuel ratio that obtains the optimal ignition timing per operation conditions.

Honda diesel engine vehicles that go on the market in 2018 will be equipped with a newly developed silver (Ag)-type catalyzed diesel particulate filter (cDPF). Ag has high particulate matter (PM) oxidation performance, but conventional catalyst-carrying methods cause weak contact property between PM and Ag; therefore, the newly Ag-type cDPF was developed on the concept of enhancing the property of contact between PM and the catalyst to realize contact property enhancement at the macro, meso, and nano scales. As a result, the newly developed catalyst showed an enhancement of T90 performance by a factor of approximately 2 relative to the conventional Ag-type catalyst in fresh condition. Durability in the environment of an automobile in use was examined through hydrothermal aging, lean-rich (L/R) aging, sulfur (S) poisoning, and ash deposition. The results have confirmed that hydrothermal aging is the greatest factor in deterioration.

Lean-burn is an effective means of reducing CO2 emissions. To date, Homogenous Lean Charge Spark Ignition (HLSI) combustion, which lowers emissions of both CO2 and NOx, has been studied. Although HLSI realizes lower emission, it is a major challenge for lean-burn engines to meet SULEV regulations, so we have developed a new aftertreatment system for HLSI engines. It consists of three types of catalysts that have different functions, as well as special engine control methods. As the first stage in achieving SULEV emissions, this study focused on enhancing performance under lean conditions. HLSI engine exhaust gases contain high concentrations of hydrocarbons, including a large amount of paraffin, which are difficult to purify, rather than low concentrations of NOx. Therefore, the key point in low emissions is to purify not only NOx, but also high concentrations of paraffin at the same time.

The aim of this study is to clarify the mixture formation in the combustion chamber of our developed natural gas engine incorporating the sub-chamber injection system, in which natural gas is directly injected into a combustion sub-chamber in order to completely separate rich mixture in the sub-chamber, suitable for ignition, from ultra-lean mixture in the main chamber. Mixture distributions in chambers with and without sub-chamber were numerically simulated at a variety of operating conditions. The commercial software of Fluent 16.0 was used to conduct simulations based on Reynolds averaged Navier-Stokes equations in an axial 2 dimensional numerical domain considering movements of piston. Non-reactive flow in the combustion chamber was simulated before the ignition timing at an engine speed of 2000 rpm. The turbulence model employed here is standard k-ε model. Air-fuel ratio is set with a lean condition of 30.

We developed a copper catalyst using zero Platinum group metals (hereafter PGMs) to fit motorcycle specific emission gas environment. Though many research reports to develop catalyst without using PGMs that are precious and costly resources are available, no reports had proven Base Metal Catalyst development to meet actual emission regulation equivalent to PGM catalysts. Compared to conventional PGM catalysts, higher temperature is required to keep high catalytic conversion efficiency by utilizing properties of this Base Metal Catalyst. Thus, this Base Metal Catalyst is located in cross coupling position, though it is rare case in motorcycle. This catalyst location could cause negative impacts on engine knocking, engine performance and drivability. This time, to overcome such negative impacts we optimized whole exhaust system, including parts around catalyst.

For the purpose of developing onboard gasoline reforming technology for higher octane number fuel on demand, octane number enhancement of gasoline surrogate by aerobic oxidation using N-hydroxyphthalimide catalyst was investigated. At first, octane numbers of the oxygen-containing products from alkane and aromatic compound were estimated using a fuel ignition analyzer. As a result, not only alcohol but also ketones and aldehydes have higher octane numbers than the original alkanes and aromatic compound. Next, gasoline surrogate was oxidized aerobically with N-hydroxyphthalimide derivative catalyst and cobalt catalyst at conditions below 100 °C. As a result, fuel molecules were oxidized to produce alcohols, ketones, aldehydes, and carboxylic acids. N-hydroxyphthalimide derivative catalyst with higher solubility in gasoline surrogate has higher oxidation ability. Furthermore, the estimated octane number of the oxidized gasoline surrogate improves 17 RON.

Compression ignition combustion with a lean mixture has high potential in terms of high theoretical thermal efficiency and low NOx emission characteristics due to low combustion temperatures. In particular, a Dual-Fuel concept is proposed to achieve high ignition timing controllability and an extended operation range. This concept controls ignition timing by adjusting the fraction of two fuels with different ignition characteristics. However, a rapid combustion process after initial ignition cannot be avoided due to the homogenous nature of the fuel mixture, because the combustion process depends entirely on the high reaction rate of thermal ignition. In this study, the effect of mixture stratification in the cylinder on the combustion process after ignition based on the Dual-Fuel concept was investigated. Port injection of one fuel creates the homogeneous mixture, while direct injection of the other fuel prepares a stratified mixture in the cylinder at the compression stroke.

Nowadays, highly super charging is required corresponded to downsizing concept for improving thermal efficiency in direct-injected spark ignition (DISI) engine. However, highly super charging increases the possibility of super-knock caused by pre-ignition. Recently, in many studies, the reason of pre-ignition has been investigated but the reason why pre-ignition leads such strong knocking called super-knock has not been investigated. In DISI engine, it is estimated that there is more inhomogeneity of equivalence ratio and temperature of air-fuel mixture than it in port injection SI engine. In this study, factors which decide self-ignition timing was reviewed and the influence of inhomogeneity of air-fuel mixture to super-knock was investigated based on numerical calculation.

EGR (Exhaust gas recirculation) can reduce the pumping loss and improve the thermal efficiency of spark ignition engines. The techniques for combustion enhancement under high EGR rate condition has been required for further improvement of the thermal efficiency. In order to develop the technique of combustion enhancement by turbulence, the influences of turbulence scale on combustion properties, such as probability of flame propagation, EGR limit of flame propagation, flame quenching and combustion duration were investigated under the condition of same turbulence intensity. Experiments were carried out for stoichiometric spherically propagating turbulent i-C8H18/Air/N2 flames using a constant volume vessel. It was clarified that all of these combustion properties were affected by the turbulence scale. The development of spherically propagating turbulent flame during flame propagation was affected by the turbulence scale.

A new concept for trapping NOx and HC during cold start, the NOx Trap Three-Way Catalyst (N-TWC), is proposed. N-TWC adsorbs NOx at room temperature, and upon reaching activation temperature under suitable air-fuel ratio conditions, it reduces the adsorbed NOx. This allows a reduction in NOx emissions during cold start. N-TWC's reduction mechanism relies on NOx adsorption sites which are shown to be highly dispersed palladium on acid sites in the zeolite. Testing on an actual vehicle equipped with N-TWC confirmed that N-TWC is able to reduce emissions of NOx and HC during cold start, which is a challenge for conventional TWCs.

Recently, automotive emission regulations are being further tightened, such as the Tier III/LEV III in the U.S. As a result, reducing cost of after-treatment systems to meet these strict regulations has become an urgent issue, and then the demand for high-precision air-fuel ratio (A/F) control which can achieve this cost reduction is high [1]. On the other hand, in order to meet rapidly changing market needs, it is becoming difficult to keep enough development periods that enable sufficient calibration by trial-and-error, such as feedback-gain calibration. This leads to an increase in three-way catalytic converter costs in some cases. For these reasons, it is necessary to construct control system that can make full use of hardware capabilities, can shorten development periods regardless of the skill level of engineers.

Downsizing or higher compression ratio of SI engines is an appropriate way to achieve considerable improvements of part load fuel efficiency. As the compression ratio directly impacts the engine cycle thermal efficiency, it is important to increase the compression ratio in order to reduce the specific fuel consumption. However, when operating a highly boosted / downsized SI engine at full load, the actual combustion process deviates strongly from the ideal Otto cycle due to the increased effective loads requiring ignition timing delay to suppress abnormal combustion phenomena such as engine knocking. This means that for an optimal design of an SI engine between balances must be found between part load and full load operation. If the knocking characteristic can be accurately predicted beforehand when designing the combustion chamber, a reduction of design time and /or an increase in development efficiency would be possible.

Regulations that limit emissions of pollutants from gasoline-powered cars and trucks continue to tighten. More than 75% of emissions through an FTP-75 regulatory test are released in the first few seconds after cold-start. A factor that controls the time to catalytic light-off is the heat capacity of the catalytic converter substrate. Historically, substrates with thinner walls and lower heat capacity have been developed to improve cold-start performance. Another approach is to increase porosity of the substrate. A new material and process technology has been developed to significantly raise the porosity of thin wall substrates (2-3 mil) from 27-35% to 55% while maintaining strength. The heat capacity of the material is 30-38% lower than existing substrates. The reduction in substrate heat capacity enables faster thermal response and lower tailpipe emissions. The reliance on costly precious metals in the washcoat is demonstrated to be lessened.

Catalyst simulation, which can analyze the complicated reaction pathway of exhaust gas purifications and identify the rate-determining step, is an essential tool in the development of catalyst materials. This requires an elementary reaction model which describes the detailed processes, i.e. adsorption, decomposition, and others. In our previous work, the elementary reaction model on Pt/CeO2 catalyst was constructed. In this study, we focused on extending the Zeolite catalyst and including the gas diffusivity through the catalyst layer. The reaction rate of a Zeolite catalyst was expressed by an Arrhenius equation, and the elementary reaction model was composed of 17 reactions. Each Arrhenius parameter was optimized by the catalytic activity measurements. The constructed model was validated with NOx conversion in cyclic experiments which were repeated with Lean phase (NOx adsorption) and Rich phase (NOx reduction).

With the increasing number of automobiles, the worldwide problem of air pollution is becoming more serious. The necessity of reducing tail-pipe emissions is as high as ever, and in countries all over the world the regulations are becoming stricter. The emissions at times such as after engine cold start, when the three-way catalyst (TWC) has not warmed up, accounts for the majority of the emissions of these pollutants from vehicles. This is caused by the characteristic of the TWC that if a specific temperature is not exceeded, TWC cannot purify the emissions. In other words, if the catalyst could be warmed up at an early stage after engine start, this would provide a major contribution to reducing the emissions. Therefore, this research is focused on the substrate weight and investigated carrying out major weight reduction by making the porosity of the substrate larger than that of conventional products.