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Technical Paper

Stress Generation in Large Pouch Cells Under Cycling and Abuse Conditions

2024-04-09
2024-01-2196
Pouch cells are increasingly popular form factors for the construction of energy storage systems in electric vehicles of all classes. Knowledge of the stress generated by these higher capacity pouch cells is critical to properly design battery modules and packs for both normal and abnormal operation. Existing literature predominantly offers data on smaller pouch cells with capacities of less than 10 Ah, leaving a gap in our understanding of the behavior of these larger cells. This experimental study aimed to bridge this knowledge gap by measuring loads and stresses in constrained 65 Ah pouch cells under both cycling and abuse conditions. To capture the desired responses, a load cell was located within a robust fixture to measure cell stress in real time after the application of a preload of approximately 30 kilograms or 294 N, equivalent to a pressure of 0.063 bar, with a fixed displacement.
Technical Paper

Further Advances in Demonstration of a Heavy-Duty Low NOX System for 2027 and Beyond

2024-04-09
2024-01-2129
Multiple areas in the U.S. continue to struggle with achieving National Ambient Air Quality Standards for ozone. These continued issues highlight the need for further reductions in NOX emission standards in multiple industry sectors, with heavy-duty on-highway engines being one of the most important areas to be addressed. Starting in 2014, CARB initiated a series of technical demonstration programs aimed at examining the feasibility of achieving up to a 90% reduction in tailpipe NOX, while at the same time maintaining a path towards GHG reductions that will be required as part of the Heavy-Duty Phase 2 GHG program. These programs culminated in the Stage 3 Low NOX program, which demonstrated low NOX emissions while maintaining GHG emissions at levels comparable to the baseline engine.
Technical Paper

CARB Off-Road Low NOx Demonstration Program - Engine Calibration and Initial Test Results

2024-04-09
2024-01-2130
Off-road diesel engines remain one of the most significant contributors to the overall oxides of nitrogen (NOX) inventory and the California Air Resources Board (CARB) has indicated that reductions of up to 90% from current standards may be necessary to achieve its air quality goals. In recognition of this, CARB has funded a program aimed at demonstrating emission control technologies for off-road engines. This program builds on previous efforts to demonstrate Low NOX technologies for on-road engines. The objective was to demonstrate technologies to reduce tailpipe NOX and particulate matter (PM) emissions by 90 and 75%, respectively, from the current Tier 4 Final standards. In addition, the emission reductions were to be achieved while also demonstrating a 5 to 8.6% carbon dioxide (CO2) reduction and remaining Greenhouse Gas (GHG) neutral with respect to nitrous oxide (N2O) and methane (CH4).
Technical Paper

Evaluating the Impact of Oil Viscoelasticity on Bearing Friction

2023-10-31
2023-01-1648
In this work, a novel bearing test rig was used to evaluate the impact of oil viscoelasticity on friction torque and oil film thickness in a hydrodynamic journal bearing. The test rig used an electric motor to rotate a test journal, while a hydraulic actuator applied radial load to the connecting rod bearing. Lubrication of the journal bearing was accomplished via a series of axial and radial drillings in the test shaft and journal, replicating oil delivery in a conventional engine crankshaft. Journal bearing inserts from a commercial, medium duty diesel engine (Cummins ISB) were used. Oil film thickness was measured using high precision eddy current sensors. Oil film thickness measurements were taken at two locations, allowing for calculation of minimum oil film thickness. A high-precision, in-line torque meter was used to measure friction torque. Four test oils were prepared and evaluated.
Technical Paper

Post-Mortem Analysis of DAAAC and Conventionally Aged Aftertreatment Systems

2023-10-31
2023-01-1656
Upcoming regulations from CARB and EPA will require diesel engine manufacturers to validate aftertreatment durability with full useful life aged components. To this end, the Diesel Aftertreatment Accelerated Aging Cycle (DAAAC) protocol was developed to accelerate aftertreatment aging by accounting for hydrothermal aging, sulfur, and oil poisoning deterioration mechanisms. Two aftertreatment systems aged with the DAAAC protocol, one on an engine and the other on a burner system, were directly compared to a reference system that was aged to full useful life using conventional service accumulation. After on-engine emission testing of the fully aged components, DOC and SCR catalyst samples were extracted from the aftertreatment systems to compare the elemental distribution of contaminants between systems. In addition, benchtop reactor testing was conducted to measure differences in catalyst performance.
Technical Paper

An Update on Continuing Progress Towards Heavy-Duty Low NOX and CO2 in 2027 and Beyond

2023-04-11
2023-01-0357
Despite considerable progress towards clean air in previous decades, parts of the United States continue to struggle with the challenge of meeting the ambient air quality targets for smog-forming ozone mandated by the U.S. EPA, with some of the most significant challenges being seen in California. These continuing issues have highlighted the need for further reductions in emissions of NOX, which is a precursor for ozone formation, from a number of key sectors including the commercial vehicle sector. In response, the California Air Resources Board (CARB) embarked on a regulatory effort culminating in the adoption of the California Heavy-Duty Low NOX Omnibus regulation.[1] This regulatory effort was supported by a series of technical programs conducted at Southwest Research Institute (SwRI).
Journal Article

Low Ambient Temperature Impact on a Low NOX Demonstration System

2023-04-11
2023-01-0361
In 2020, CARB adopted the low NOX omnibus ruling, which provided revisions to on-road heavy duty engine compliance standards and certification practices. As part of the updates to the regulation, CARB has introduced a new in-use vehicle testing process that broadens the operation modes tested and considers the manufacturer’s intended vehicle application. Compared to the previous method, or the Not-to-Exceed approach, cold start and low ambient temperature provisions were included as part of the updates. The inclusion of low temperature operation requires the OEMs to design a robust engine and aftertreatment package that extends NOX conversion performance. The following work discusses the NOX emissions performance impact in a low temperature ambient environment. The engine and aftertreatment system evaluated was designed to comply with CARB’s low NOX regulations. The cycles tested included the CARB Southern NTE cycle and an FTP-LLC protocol.
Technical Paper

DAAAC Protocol for Durability Demonstration of Diesel Aftertreatment Systems: Emissions Performance Validation

2022-08-30
2022-01-1015
Aftertreatment durability demonstration is a required validation exercise for on-road medium and heavy-duty diesel engine certification. The demonstration is meant to validate emissions compliance for the engine and aftertreatment system at full useful life or FUL. Current certification practices allow engine manufacturers to complete partial aging and then extrapolate emissions performance results to FUL. While this process reduces the amount of service accumulation time, it does not consider changes in the aftertreatment deterioration rate. Rather, deterioration is assumed to occur at a linear rate, which may lead to false conclusions relating to emissions compliance. With CARB and EPA’s commitment to the reduction of criteria emissions, emphasis has also been placed on revising the existing certification practices. The updated practices would require engine manufacturers to certify with an aftertreatment system aged to FUL.
Journal Article

Development of Steady State NO2:NOX Control via an Independent Nitric Decomposition System for the Exhaust Composition Transient Operation Laboratory

2022-03-29
2022-01-0548
Southwest Research Institute (SwRI) utilizes the burner-based Exhaust Composition Transient Operation LaboratoryTM (ECTO-Lab) to accurately simulate transient engines and replicate real exhaust that is produced by light and heavy-duty engines for aftertreatment aging and evaluations. This system can generate and dose NOX over transient cycles from a range of 20 ppm to 1200 ppm where the NOX is generated by the in-situ decomposition and combustion of a fuel-bound, nitrogen containing compound. During the combustion and decomposition of the nitrogen containing compound over 95 % of the NOX generated is in the form of NO. To authentically simulate exhaust gases, it is necessary to account for the distribution of the NO to the NO2. Since previous work has established that the decomposition of nitric acid can be utilized as a method to generate NO2, the objective of this project was to develop control of NO and NO2 within SwRI’s ECTO-Lab through the decomposition of nitric acid.
Technical Paper

Development of a Novel Dynamically Loaded Journal Bearing Test Rig

2021-09-21
2021-01-1218
In this work, a dynamically loaded hydrodynamic journal bearing test rig is developed and introduced. The rig is a novel design, using a hydraulic actuator with fast acting spool valves to apply load to a connecting rod. This force is transmitted through the connecting rod to the large end bearing which is mounted on a spinning shaft. The hydraulic actuator allows for fully variable control and can be used to apply either static load in compression or tension, or dynamic loading to simulate engine operation. A variable speed electric motor controls shaft speed and is synchronized to the hydraulic actuator to accurately simulate loading to represent all four engine strokes. A high precision torque meter enables direct measurements of friction torque, while shaft position is measured via a high precision encoder.
Journal Article

THC Concentration Estimation Model using FTIR Spectrum

2021-09-21
2021-01-1226
A novel total hydrocarbon (THC) emission concentration estimation model is proposed for reduction of engine development cost and simplification of exhaust measurements. The proposed method uses the absorbance spectra of a Fourier transform infrared (FTIR) spectrometer, which contains the information on a wide variety of hydrocarbons, as input. The model is based on machine learning algorithms including the least absolute shrinkage and selection operator (LASSO) regression and bagging techniques. To train the model, we created a dataset containing pairs of a spectrum of engine exhaust gas and the THC concentration. In addition, we incorporate absorbance spectra of individual hydrocarbon components and several inorganic components so that the model learns the contribution of each hydrocarbon to THC concentration and to ignore interferences of irrelevant gas components.
Technical Paper

Combination of Mixed Metal Oxides with Cu-Zeolite for Enhanced Soot Oxidation on an SCRoF

2021-09-05
2021-24-0071
A push for more stringent emissions regulations has resulted in larger, increasingly complex aftertreatment solutions. In particular, oxides of nitrogen (NOX) and particulate matter (PM) have been controlled using two separate systems, selective catalytic reduction (SCR) and the catalyze diesel particulate filter (CDPF), or the functionality has been combined into a single device producing the SCR on filter (SCRoF). The SCRoF forgoes beneficial NO2 production present in the CDPF to avoid NH3 oxidation which occurs when using platinum group metals (PGM) for oxidation. In this study, mixed-metal oxides are shown to oxidize NO to NO2 without appreciable NH3 oxidation. This selectivity leads to enhanced performance when combined with a typical Cu-zeolite catalyst.
Journal Article

CARB Low NOX Stage 3 Program - Final Results and Summary

2021-04-06
2021-01-0589
Despite considerable progress over the last several decades, California continues to face some of the most significant air quality problems in the United States. These continued issues highlight the need for further mobile source NOX reductions to help California and other areas meet ambient air quality targets mandated by the U.S. EPA. Beginning in 2014, the California Air Resources Board (CARB) launched a program aimed at demonstrating technologies that could enable heavy-duty on-highway engines to reach tailpipe NOX levels up to 90% below the current standards, which were implemented in 2010. At the same time, mandated improvements to greenhouse gas emissions (GHG) require that these NOX reductions be achieved without sacrificing fuel consumption and increasing GHG emissions.
Technical Paper

Comparison of Partial and Total Dilution Systems for the Measurement of Polycyclic Aromatic Hydrocarbons and Hydrocarbon Speciation in Diesel Exhaust

2020-09-15
2020-01-2190
Two methods of sampling exhaust emissions are typically used for characterizing emissions from diesel engines: total dilution which uses a constant volume sampling (CVS) system and partial flow dilution which relies on proportionally diluting a small part from the main exhaust stream. The CVS dilutes the entire exhaust flow to a constant volumetric flowrate which allows for proportional sampling of the exhaust species during transient engine operation. For partial dilution sampling during transient engine operation, obtaining a proportional sample is more rigorous and dilution of the extracted sample must be continuously changed throughout the cycle in order for the extracted sample flowrate to be proportional to the continuously changing exhaust flow. Typically, regulated emissions measured using both methods for an engine platform have shown good correlation. The focus for this work was on the experimental investigation of the two methods for the measurement of unregulated species.
Journal Article

Use of Nitric Acid to Control the NO2:NOX Ratio within the Exhaust Composition Transient Operation Laboratory Exhaust Stream

2020-04-14
2020-01-0371
The Exhaust Composition Transient Operation LaboratoryTM (ECTO-LabTM) is a burner system developed at Southwest Research Institute (SwRI) for simulation of IC engine exhaust. The current system design requires metering and combustion of nitromethane in conjunction with the primary fuel source as the means of NOX generation. While this method affords highly tunable NOX concentrations even over transient cycles, no method is currently in place for dictating the speciation of nitric oxide (NO) and nitrogen dioxide (NO2) that constitute the NOX mixture. NOX generated through combustion of nitromethane is dominated by NO, and generally results in an NO2:NOX ratio of < 5 %. Generation of any appreciable quantities of NO2 is therefore dependent on an oxidation catalyst to oxidize a fraction of the NO to NO2.
Technical Paper

Semi-Volatile Organic Compounds from a Combined Dual Port Injection/Direct-Injection Technology Light-Duty Gasoline Vehicle

2019-09-09
2019-24-0051
Gasoline direct injection (GDI) has changed the exhaust composition in comparison with the older port fuel injection (PFI) systems. More recently, light-duty vehicle engine manufactures have combined these two technologies to take advantage of the knock benefits and fuel economy of GDI with the low particulate emission of PFI. These dual injection strategy engines have made a change in the combustion emission composition produced by these engines. Understanding the impact of these changes is essential for automotive companies and aftertreatment developers. A novel sampling system was designed to sample the exhaust generated by a dual injection strategy gasoline vehicle using the United States Federal Test Procedure (FTP). This sampling system was capable of measuring the regulated emissions as well as collecting the entire exhaust from the vehicle for measuring unregulated emissions.
Technical Paper

Evaluation of Gasoline Additive Packages to Assess Their Ability to Clean Up Intake Valve Deposits in Automotive Engines

2019-04-02
2019-01-0261
The majority of passenger car and light-duty trucks, especially in North America, operate using port-fuel injection (PFI) engines. In PFI engines, the fuel is injected onto the intake valves and then pulled into the combustion chamber during the intake stroke. Components of the fuel are unstable in this environment and form deposits on the upstream face of the intake valve. These deposits have been found to affect a vehicle’s drivability, emissions and engine performance. Therefore, it is critical for the gasoline to be blended with additives containing detergents capable of removing the harmful intake valve deposits (IVDs). Established standards are available to measure the propensity of IVD formation, for example the ASTM D6201 engine test and ASTM D5500 vehicle test.
Technical Paper

Combined Benefits of Variable Valve Actuation and Low-Pressure EGR on SI Engine Efficiency Part 2: High Load

2019-04-02
2019-01-0237
The abnormal autoignition of the unburned gas, namely knock, at high loads is a major challenge for modern spark ignited engines. Knock prevents the application of high compression ratios due to the increased unburned gas temperature, and it becomes increasingly severe for downsized engines with high specific powers. The current paper reports on the potential of utilizing continuously variable valve actuation (VVA) and low-pressure exhaust gas recirculation (EGR) to reduce knock tendency at high loads. Five speed / load points were investigated on a 1.6 L turbocharged gasoline direct injection engine. The brake specific fuel consumption (BSFC) response to the valve phasing and the intake valve lift was investigated with the design of experiment (DoE) approach. The DoE was conducted using a Box-Behnken surface response model. The results exhibited insensitive response of BSFC to intake valve lift and overlap.
Technical Paper

Evaluation of Diesel Spray with Non-Circular Nozzle - Part I: Inert Spray

2019-01-15
2019-01-0065
Numerous studies have characterized the impact of high injection pressure and small nozzle holes on spray quality and the subsequent impact on combustion. Higher injection pressure or smaller nozzle diameter usually reduce soot emissions owing to better atomization quality and fuel-air mixing enhancement. The influence of nozzle geometry on spray and combustion of diesel continues to be a topic of great research interest. An alternate approach impacting spray quality is investigated in this paper, specifically the impact of non-circular nozzles. The concept was explored experimentally in an optically accessible constant-volume combustion chamber (CVCC). Non-reacting spray evaluations were conducted at various ambient densities (14.8, 22.8, 30 kg/m3) under inert gas of Nitrogen (N2) while injection pressure was kept at 100 MPa. Shadowgraph imaging was used to obtain macroscopic spray characteristics such as spray structure, spray penetration, and the spray cone angle.
Technical Paper

Polycyclic Aromatic Hydrocarbons in Diesel Engine Exhaust Both with and without Aftertreatment

2018-09-10
2018-01-1812
Since the conception of the internal combustion engine, smoky and ill-smelling exhaust was prevalent. Over the last century, significant improvements have been made in improving combustion and in treating the exhaust to reduce these effects. One group of compounds typically found in exhaust, polycyclic aromatic hydrocarbons (PAH), usually occurs at very low concentrations in diesel engine exhaust. Some of these compounds are considered carcinogenic, and most are considered hazardous air pollutants (HAP). Many methods have been developed for sampling, handling, and analyzing PAH. For this study, an improved method for dilute exhaust sampling was selected for sampling the PAH in diesel engine exhaust. This sampling method was used during transient engine operation both with and without aftertreatment to show the effect of aftertreatment.
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