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In transportation sector, higher engine thermal efficiency is currently required to solve the energy crisis and environmental problems. In spark ignition (SI) engine, lean-burn strategy is the promising approach to improve thermal efficiency and lower emissions. Olefins are the attractive component for gasoline additives, because they are more reactive and have advantage in lean limit extension. However, owing to lower research octane number (RON), it is expected to exhibit the drawback to reducing the anti-knock performance. The experiments were performed using a single-cylinder engine for 6 fuel types including gasoline blends which have difference in RON varying between 90.4 and 100.2. The results showed that adding olefin content to the premium gasoline provided unfavorable effect on auto-ignition as the auto-ignition happened at unburned gas temperature of 808 K which was 52 K lower at excess air of 2.0. Thus, it reduced anti-knock performance.

The Real Driving Emissions (RDE) test method has been introduced after 2017 to regulate the vehicle emissions in real-world driving situations by means of on-board emissions measurements. This paper aims to estimate the detailed on-board gaseous emissions from a light-duty direct-injection gasoline vehicle simultaneously using both portable emissions measurement system (PEMS) and sensor-based emissions measurement system (SEMS). Test route is typical urban route and tests environment factors followed the RDE regulation. Carbon dioxide (CO2), carbon monoxide (CO), nitrogen oxides (NOx), and ammonia (NH3) emissions were analyzed according to cold start once and followed by hot start conditions. The mass emissions of gas components were calculated based on the exhaust flowrate obtained from OBD parameters, NH3 emission was calculated based on NO sensor’s data. Two drivers participated in the tests and their emissions difference has been compared.

In recent years, particulate matter (PM) emitted from direct-injection gasoline vehicles is becoming an increasingly concerning problem. In addition, it is often reported that ammonia (NH3) is emitted from gasoline vehicles equipped with a three-way catalyst. These emissions might be largely emitted especially when driving in on-road driving conditions. In this study, we investigated the emissions, NOx, NH3, and PM/PN (particulate number) of a light-duty direct-injection gasoline vehicle when driving on actual roads. Using a small direct-injection gasoline vehicle equipped with a three-way catalyst, experiment was conducted 8 times on the same route, and these emissions were measured. In this study, vehicle specific power (VSP) was introduced, which can be calculated using vehicle parameters, vehicle speed, and road gradient. The effects of parameters acquired through on-board diagnostics (OBD) port and VSP on emissions were investigated.

Diesel engines have better fuel economy over comparable gasoline engines and are useful for the reduction of CO2 emissions. However, to meet stringent emission standards, the technology for reducing NOx and particulate matter (PM) in diesel engine exhaust needs to be improved. A conventional selective catalytic reduction (SCR) system consists of a diesel oxidation catalyst (DOC), diesel particulate filter (DPF), and urea-SCR catalyst. Recently, more stringent regulations have led to the development of SCR systems with a larger volume and increased the cost of such systems. In order to solve these problems, an SCR catalyst-coated DPF (SCR/DPF) is proposed. An SCR/DPF system has lower volume and cost compared to the conventional SCR system. The SCR/DPF catalyst has two functions: combustion of PM and reduction of NOx emissions.

Dimethyl ether (DME) is a promising alternative fuel for compression ignition (CI) engines. DME features good auto ignition characteristics and soot-free combustion. In order to develop an injection system suitable for DME, it is necessary to understand its fuel properties. Sound speed is an important fuel property that affects the injection characteristics. However, the measurement data under high-pressures corresponding to those in fuel injection systems are lacking. The critical temperature of DME is lower than that of diesel fuel, and is close to the injection condition. It is important to understand the behavior of the sound speed around the critical point, since the sound speed at critical point is extremely low. In this study, sound speed in DME in a wide pressure and temperature range of 1 MPa to 80 MPa, 298.15 K to 413.15 K, including the vicinity of the critical point, was measured. The sound speed in DME decreases as either the pressure falls or the temperature rises.

Dimethyl Ether (DME) is one of the major candidates for the alternative fuel for compression ignition (CI) engines. However, DME spray combustion characteristics are not well understood. There is no spray model validated against spray experiments at high-temperature and high-pressure relevant to combustion chambers of engines. DME has a lower viscosity and lower volumetric modulus of elasticity. It is difficult to increase injection pressure. The injection pressure remains low at 60 MPa even in the latest DME engine. To improve engine performance and reduce emissions from DME engines, establishing the DME spray model applicable to numerical engine simulation is required. In this study, high-speed observation of DME sprays at injection pressures up to 120 MPa with a latest common rail DME injection system was conducted in a constant volume combustion vessel, under ambient temperature and pressure of 6 MPa-920 K.

2,5-dimethylfuran (DMF) and 2-methylfuran (MF) have attracted attention as new biofuels. To utilize furans as alternative fuels, fundamental studies on the combustion characteristics are required. In this study, the ignition delay times of DMF were measured using a rapid compression machine and compared with those of gasoline and ethanol. To investigate the effect of the addition of DMF to gasoline, the ignition delay times of DMF-gasoline surrogate fuel blends were also measured. The ignition delay times of DMF were longer than those of gasoline and shorter than those of ethanol. The simulation results using the DMF kinetic model were in reasonable agreement with those of the experiments.

DiMethyl Ether (DME) has been known to be an outstanding fuel for combustion in diesel cycle engines for nearly twenty years. DME has a vapour pressure of approximately 0.5MPa at ambient temperature (293K), thus it requires pressurized fuel systems to keep it in liquid state which are similar to those for Liquefied Petroleum Gas (mixtures of propane and butane). The high vapour pressure of DME permits the possibility to optimize the fuel injection characteristic of direct injection diesel engines in order to achieve a fast evaporation and mixing with the charged gas in the combustion chamber, even at moderate fuel injection pressures. To understand the interrelation between the fuel flow inside the nozzle spray holes tests were carried out using 2D optically accessed nozzles coupled with modelling approaches for the fuel flow, cavitation, evaporation and the gas dynamics of 2-phase (liquid and gas) flows.

One way to reduce CO2 in the atmosphere is to use biodiesel fuel (BDF) [1]. BDF has the advantage of low smoke combustion, since its molecules contain oxygen. Meanwhile, BDF has the drawbacks of high viscosity and a high pour point that make it difficult to use at low temperatures. Dimethyl ether (DME) can be made from biomass, as well as from natural gas or coal; therefore, it is regarded as one of the biomass fuels. DME has low viscosity and a low boiling point, and smoke-free combustion can be obtained, since it has no carbon-carbon bond [2]. On the other hand, it has the disadvantage of low lubricity due to its low viscosity. When these fuels are blended together, the weaknesses of the fuels can be overcome. The objective of this research is to show that blending these two fuels is an effective way of bringing biomass-derived fuels into practical use.

Homogeneous charge compression ignition (HCCI) combustion of methane was performed using dimethyl ether (DME) as an ignition improver. The ignition mechanisms of the methane/DME/air HCCI process were investigated on the basis of the chemical kinetics. The engine test was also conducted to verify the calculation results, and to determine the operation range. Analysis of the results showed that DME was an excellent ignition improver for methane, having two functions of temperature rise and OH radical supply. It was also shown that the operation range was extended to an overall equivalence ratio of 0.54 without knocking, by controlling DME quantity.

In this study, advantages of GTL fueled DI diesel engine were observed, then, some cautionary areas, notably the aptitude for sealing materials, were investigated. Some advantages of using GTL as a diesel engine fuel include reduction of soot emission levels, power output and fuel consumption with GTL to conventional diesel fuel operation is equivalent, super-low sulfur content of GTL and its liquid state at normal temperature and pressure. However, there are some problems with putting GTL fuel on the market, such as lubricity, aptitude for sealing materials, high cetane index and high pour point. It is necessary to use additives to improve GTL's lubricity, and selecting the most appropriate type of lubricity improver is also important. The influence of GTL on the swelling properties of standard rubber materials seem basically the same, but it is necessary to notice on used rubbers.

For better understanding of the combustion characteristics in a direct injection dimethyl ether (DME) engine, the chemiluminescences of a burner flame and in-cylinder flame were analyzed using the spectroscopic method. The emission intensities of chemiluminescences were measured by a photomultiplier after passing through a monochrome-spectrometer. For the burner flame, line spectra were found nearby the wave length of 310 nm, 430 nm and 515 nm, arising from OH, CH and C2 radicals, respectively. For the in-cylinder flame, a strong continuous spectrum was found from 340 nm wave length to 550 nm. Line spectra were also detected nearby 310 nm, 395 nm and 430 nm, arising from OH, HCHO, and C2 radicals, respectively, partially overlapping with the continuous spectrum. Of these line spectra, 310 nm of OH radical did not overlapped with the continuous spectrum.

To date, the DME combustion mechanism has been investigated by in-cylinder gas sampling, numerical calculations and observation of combustion radicals. It has been possible to quantify the emission intensities of in-cylinder combustion using a monochromator, and to observe the emitting species as images by using band-pass filters. However, the complete band images were not observed since the broadband (thermal) intensity may be stronger than band spectra intensities. Emission intensities of DME combustion radicals from a pre-mixed burner flame have been measured using a spectroscope and photomultiplier. Results were compared to other fuels, such as n-butane and methane, then, in this study, to better understand the combustion characteristics of DME, emission intensities near CH bands of an actual DI diesel engine fueled with DME were measured, and band spectra emitted from the engine were defined. Near TDC, emission intensities did not vary with wavelength.

Characteristics of dimethyl ether spray formation were observed using schlieren photography, and the combustion characteristics and performance of a dimethyl ether-operated diesel engine were investigated. Accordingly, this paper describes the basic characteristics of engine performance and the potential for decreased exhaust emissions, as well as discussing problems concerning the practical application of dimethyl ether-operated diesel engines.

Computational analysis on the mechanism and control method for DME fueled HCCI type combustion was carried out on the basis of the chemical kinetics. The calculation results were verified experimentally using a single cylinder test engine. Analysis of the results showed that DME oxidation is governed by production/consumption behavior of OH, because DME oxidation is initiated by dehydrogenation with OH radicals. It was also shown that the overall oxidation reaction could be controlled by adding substances which react competitively with OH in the dehydrogenation reactions of DME. Of the substances we tested, formaldehyde was most effective. It was confirmed by engine testing that by adding a small amount of formaldehyde to the DME/air mixture, the heat evolved in the low temperature reactions was reduced and the reaction appearance timing was retarded.

To better understand the combustion characteristics of DME, emission intensities of DME combustion radicals from a pre-mixed burner flame were measured by a spectroscope and photomultiplier, Results were compared to other fuels, such as methane and butane. Large peaks in the band spectra from pre-mixed and diffusion DME flames were found near 310 nm, 430 nm, and 515 nm, arising from OH, CH and C2, respectively. The DME emission intensities decreased with increasing the equivalence ratio in this study. Notably, the relative decrease in the C2 band spectra peak was greater than that of the OH band. Comparing the pre-mixed DME and butane flames, the butane band spectra peaks were similar in shape, but much stronger than those for DME. However, it was remarkable that CH and C2 band spectra peaks decreased only slightly with increase in equivalence ratio compared to the DME case.

In this study, spray images of LPG Blended Fuels (LBF) for DI diesel engines were observed using a constant volume chamber at high ambient temperature and pressure, and the spray characteristics of the fuel were investigated. The LBF spray started to vaporize at the injector tip and the outer downstream regions of the spray, like diesel fuel, because of the high temperature at these areas. There were more vaporized areas compared to diesel fuel. Sufficient fuel injection volume and volatility of LBF resulted in good fuel-air mixture, then, THC emissions decreased compared to diesel fuel at high load engine test conditions. Butane spray image could not be observed at the injector tip. It seems that the high temperature of the injector tip caused the butane spray to vaporize rapidly. Spray tip penetration with LBF and butane were equal or greater than with diesel fuel. The high volatility of LBF and butane had no noticeable effect on spray penetration.

In this study, the main properties of two types of gas-to-liquid (GTL) fuels were investigated. Then, performance and emission characteristics of a compression ignition engine fueled with GTLs were investigated by comparison with diesel fuel. GTL1 was composed of 100% paraffin by volume, and GTL2 was composed of 99.8% paraffin and 0.2% aromatics by volume. Most GTL fuel properties were comparable to those of diesel fuel, while both fuels have a higher cetane number and lower sulphur. A diesel engine could be operated with GTL fueling without any special engine modifications. Our tests showed that with the high cetane number of GTLs, the ignition delay was shorter, and combustion started earlier than with diesel fuel. With GTL1 operation, THC and soot emissions were lower than with diesel fuel operation, and even lower with GTL2 fueling.

In this study, engine performances and exhaust emissions characteristics of compression ignition engine fueled with GTL were investigated by comparison with diesel fuel. Diesel engine could be operated fueled with GTL without any special modify for the test engine. With the high cetane number of GTL, the ignition lag was shorter, and the combustion started earlier than that of diesel fuel. Brake thermal efficiency operated with GTL increased at middle load conditions due to incomplete combustion emission such as CO and THC were lower than that of diesel fuel operation. NOx emission with GTL was comparable to diesel fuel, and there was a little decrease at high load. With GTL, soot emission was lower than with diesel fuel at above middle load condition. It seemed to be a reason of soot reduction that there was little sulphur contained in GTL.

Recently, dimethyl ether (DME) has been attracting much attention as a clean alternative fuel, since the thermal efficiency of DME powered diesel engine is comparable to diesel fuel operation and soot free combustion can be achieved. In this experiment, the effect of ambient pressure on DME spray was investigated with observation of droplet size such as Sauter mean diameter (SMD) by the shadowgraph and image processing method. The higher ambient pressure obstructs the growth of DME spray, therefore faster breakup was occurred, and liquid column was thicker with increasing the ambient pressure. Then engine performances and exhaust emissions characteristics of DME diesel engine were investigated with various compression ratios. The minimum compression ratio for the easy start and stable operation was obtained at compression ratio of about 12.