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The degradation rate of a Li-ion battery is a complex function of temperature and charge/discharge rates over its lifetime. There is obviously a keen interest in predictive electrochemical ageing models that account for known degradation mechanisms, primarily linked with the Solid Electrolyte Interface (SEI) formation and Li-plating, which are highly dependent on the cell temperature. Typically, such ageing models are formulated and employed at pack or cell level, neglecting intra-cell and cell-to-cell thermal and electrical non-uniformities. On the other hand, thermal management techniques can mitigate ageing by maintaining the battery pack within the desired temperature window either by cooling or heating. Inevitably, the cooling of the battery pack by conventional heat exchangers will introduce temperature non-uniformities that may in turn result in undesired intra-cell and/or cell-to-cell health non-uniformities.

In the rapidly changing scenario of the energy transition, data-driven tools for kinetic mechanism development and testing can greatly support the evaluation of the combustion properties of new potential e-fuels. Despite the effectiveness of kinetic mechanism generation and optimization procedures and the increased availability of experimental data, integrated methodologies combining data analysis, kinetic simulations, chemical lumping, and kinetic mechanism optimization are still lacking. This paper presents an integrated workflow that combines recently developed automated tools for kinetic mechanism development and testing, from data collection to kinetic model reduction and optimization. The proposed methodology is applied to build a consistent, efficient, and well-performing kinetic mechanism for the combustion of oxymethylene ethers (OMEs), which are promising synthetic e-fuels for transportation.

We present a framework for the robust optimization of the heat flux distribution for an anti-ice electro-thermal ice protection system (AI-ETIPS) and iced airfoil performance analysis under uncertain conditions. The considered uncertainty regards a lack of knowledge concerning the characteristics of the cloud i.e. the liquid water content and the median volume diameter of water droplets, and the accuracy of measuring devices i.e., the static temperature probe, uncertain parameters are modeled as uniform random variables. A forward uncertainty propagation analysis is carried out using a Monte Carlo approach. The optimization framework relies on a gradient-free algorithm (Mesh Adaptive Direct Search) and three different problem formulations are considered in this work. Two bi-objective deterministic optimizations aim to minimize power consumption and either minimize ice formations or the iced airfoil drag coefficient.

This work has the objective to present the extension of a novel quasi-dimensional model, developed to simulate the combustion process in diesel Compression Ignition (CI) engines, to describe this process when Dimethyl ether (DME) is used as fuel. DME is a promising fuel in heavy-duty CI engines application thanks to its high Cetane Number (CN), volatility, high reactivity, almost smokeless combustion, lower CO2 emission and the possibility to be produced with renewable energy sources. In this paper, a brief description of the thermodynamic model will be presented, with particular attention to the implementation of the Tabulated Kinetic Ignition (TKI) model, and how the various models interact to simulate the combustion process. The model has been validated against experimental data derived from constant-volume DME combustion, in this case the most important parameters analyzed and compared were the Ignition Delay (ID) and Flame Lift Off Length (FLOL).

The current European fleet of vehicles is ageing and lifetime mileages are rising proportionally. Consequently, a substantial fraction of the vehicle fleet is currently operating at mileages well beyond current durability legislation (≤ 160,000 km). Emissions inventories and models show substantial increases in emissions with increasing mileage, but knowledge of the effect of emissions control system deterioration at very high mileages is sparse. Emissions testing has been conducted on matched pairs (or more) of diesel and gasoline (and CNG) vehicles, of low and high mileage, supplementing the results with in-house data, in order to explore high mileage emission deterioration factors (DF). The study isolated, as far as possible, the effect of emissions deterioration with mileage, by using nominally identical vehicle models and controlling other variables.

Dimethyl ether (DME) represents a promising fuel for heavy-duty engines thanks to its high cetane number, volatility, absence of aromatics, reduced tank-to-wheel CO2 emissions compared to Diesel fuel and the possibility to be produced from renewable energy sources. However, optimization of compression-ignition engines fueled with DME requires suitable computational tools to design dedicated injection and combustion systems: reduced injection pressures and increased nozzle diameters are expected compared to conventional Diesel engines, which influences both the air-fuel mixing and the combustion process. This work intends to evaluate the validity of two different combustion models for the prediction of performance and pollutant emissions in compression-ignition engines operating with DME. The first one is the Representative Interactive Flamelet while the second is the Approximated Diffusive Flamelet.

Modeling combustion of transportation fuels remains a difficult task due to the extremely large number of species constituting commercial gasoline and diesel. However, for this purpose, multi-component surrogate fuel models with a reduced number of key species and dedicated reaction subsets can be used to reproduce the physical and chemical traits of diesel and gasoline, also allowing to perform CFD calculations. Recently, a detailed surrogate fuel kinetic model, named C3 mechanism, was developed by merging high-fidelity sub-mechanisms from different research groups, i.e. C0-C4 chemistry (NUI Galway), linear C6-C7 and iso-octane chemistry (Lawrence Livermore National Laboratory), and monocyclic aromatic hydrocarbons (MAHs) and polycyclic aromatic hydrocarbons (PAHs) (ITV-RWTH Aachen and CRECK modelling Lab-Politecnico di Milano).

In this work, the possibility to perform a cold-flow simulation as a way to improve the accuracy of the starting conditions for a combustion simulation is examined. Specifically, a dual-fuel marine engine running on methanol/diesel and natural gas/diesel fueling conditions is investigated. Dual-fuel engines can provide a short-term solution to cope with the more stringent emission legislations in the maritime sector. Both natural gas and methanol appear to be interesting alternative fuels that can be used as main fuel in these dual-fuel engines. Nevertheless, it is observed that combustion problems occur at part load using these alternative fuels. Therefore, different methods to increase the combustion efficiency at part load are investigated. Numerical simulations prove to be very suitable hereto, as they are an efficient way to study the effect of different parameters on the combustion characteristics.

Computational fluid dynamics (CFD) modeling has many potentials for the design and calibration of modern and future engine concepts, including facilitating the exploration of operation conditions and casting light on the involved physical and chemical phenomena. As more attention is paid to the matching of different fuel types and combustion strategies, the use of detailed chemistry in characterizing auto-ignition, flame stabilization processes and the formation of pollutant emissions is becoming critical, yet computationally intensive. Therefore, there is much interest in using tabulated approaches to account for detailed chemistry with an affordable computational cost. In the present work, the tabulated flamelet progress variable approach (TFPV), based on flamelet assumptions, was investigated and validated by simulating constant-volume Diesel combustion with primary reference fuels - binary mixtures of n-heptane and iso-octane.

Brake calipers for high-end cars are typically realized using Aluminum alloys, with Silicon as the most common alloying element. Despite the excellent castability and machinability of Aluminum-Silicon alloys (AlSix), anodization is often required in order to increase its corrosion resistance. This is particularly true in Chlorides-rich environments where Aluminum can easily corrode. Even if anodization process is known for almost 100 years, anodization of AlSix -based materials is particularly challenging due to the presence of eutectic Silicon precipitates. These show a poor electric conductivity and a slow oxidation kinetics, leading to inhomogeneous anodic layers. Continuous research and process optimization are required in order to develop anodic layers with enhanced morphological and electrochemical properties, targeting a prolonged resistance of brake calipers under endurance corrosive tests (e.g. >1000 hours Neutral Salt Spray (NSS) tests).

The electrochemical performance of a lithium-ion battery is strongly affected by the temperature. During charge and discharge cycles, batteries are subjected to an increment of temperature that can accelerate aging and loss of efficiency if critical values are reached. Knowing the thermal parameters that affect the heat exchange between the battery surface and the surrounding environment (air, cooling fins, plates, etc…) is fundamental to their thermal management. In this work, thermal imaging is applied to a laminated lithium-polymers battery as a non-invasive temperature-indication method. Measurements are taken during the discharge phase and the following cooling down until the battery reaches the ambient temperature. The 2d images are used to analyze the homogeneity of the temperature distribution on the battery surface. Then, experimental results are coupled with mathematical correlations.

The numerical reconstruction of the liquid jet generated by a multi-hole injector, operating in flash-boiling conditions, has been developed by means of a Eulerian- Lagrangian CFD code and validated thanks to experimental data collected with schlieren and Mie scattering imaging techniques. The model has been tested with different injection parameters in order to recreate various possible engine thermodynamic conditions. The work carried out is framed in the growing interest present around the gasoline direct-injection systems (GDI). Such technology has been recognized as an effective way to achieve better engine performance and reduced pollutant emissions. High-pressure injectors operating in flashing conditions are demonstrating many advantages in the applications for GDI engines providing a better fuel atomization, a better mixing with the air, a consequent more efficient combustion and, finally, reduced tailpipe emissions.

In recent years, the increase of gasoline fuel injection pressure is a way to improve thermal efficiency and lower engine-out emissions in GDI homogenous combustion concept. The challenge of controlling particulate formation as well in mass and number concentrations imposed by emissions regulations can be pursued improving the mixture preparation process and avoiding mixture inhomogeneity with ultra-high injection pressure values up to 100 MPa. The increase of the fuel injection pressure in GDI homogeneous systems meets the demand for increased injector static flow, while simultaneously improves the spray atomization and mixing characteristics with consequent better combustion performance. Few studies quantify the effects of high injection pressure on transient gasoline spray evolution. The aim of this work was to simulate with OpenFOAM the spray morphology of a commercial gasoline injected in a constant volume vessel by a prototypal GDI injector.

Isooctane sprays from a multi-hole GDI injector were investigated in a constant volume chamber by means of high speed imaging techniques. The tests were performed under inert conditions (nitrogen), at temperatures and densities ranging between representative operating conditions of late injection, flash boiling and early injection in a GDI engine. The global parameters of the sprays were obtained by processing Schlieren, Shadowgraph, DBI and Mie-scattering images through an in-house image processing method. Thus, the boundaries of the spray vapor phase can be easily detected with great accuracy, regardless of whether Schlieren or the less sensitive shadowgraph imaging is used. Furthermore, the boundaries of the liquid phase were also obtained from shadowgraph images and compared with those obtained through DBI and scattering. The results show that the signature of the liquid phase in a shadowgraph image can be distinguished from that of the vaporized fuel.

In the last years, increasing concerns about environmental pollution and fossil sources depletion led transport sectors research and development towards the study of new technologies capable to reduce vehicles emissions and fuel consumption. Direct-injection systems (DI) for internal combustion engines propose as an effective way to achieve these goals. This technology has already been adopted in Gasoline Direct Injection (GDI) engines and, lately, a great interest is growing for its use in natural gas fueling, so increasing efficiency with respect to port-fuel injection ones. Alone or in combination with other fuels, compressed natural gas (CNG) represents an attractive way to reduce exhaust emission (high H/C ratio), can be produced in renewable ways, and is more widespread and cheaper than gasoline or diesel fuels. Gas direct-injection process involves the occurrence of under-expanded jets in the combustion chamber.

A multi-objective optimal design of a brushless DC electric motor for a brake system application is presented. Fifteen design variables are considered for the definition of the stator and rotor geometry, pole pieces and permanent magnets included. Target performance indices (peak torque, efficiency, rotor mass and inertia) are defined together with design constraints that refer to components stress levels and temperature thresholds, not to be surpassed after heavy duty cycles. The mathematical models used for optimization refer to electromagnetic field and related currents computation, to thermo-fluid dynamic simulation, to local stress and vibration assessment. An Artificial Neural Network model, trained with an iterative procedure, is employed for global approximation purposes. This allows to reduce the number of simulation runs needed to find the optimal configurations. Some of the Pareto-optimal solutions resulting from the optimal design process are analysed.

The in-cylinder direct injection of natural gas can be a further step towards cleaner and more efficient internal combustion engines (ICE). However, the injector design and its characterization, both experimentally and by numerical simulation, is challenging because of the complex fluid dynamics related to gas compressibility and the small length scale. In this work, the under-expanded flow of methane from an outward-opening poppet-valve injector has been experimentally characterized by high-speed schlieren imaging. The investigation has been performed at ambient temperature and pressure and different nozzle pressure ratios (NPR) ranging from 10 to 18. The gaseous jet has been characterized in terms of its macroscale parameters. A scaling-law analysis of the results has been performed. The gas-dynamic structure at the nozzle exit has been also investigated.

Recently, it has been worth pointing out the relevance of alternative fuels in the improvement of air quality conditions and in the mitigation of global warming. In order to deal with these demands, in recent studies, it has been considered a great variety of alternative fuels. It goes without saying that the alternative fuels industry needs the best of the efficiency with a moderate layout. From this perspective, Liquefied Petroleum Gas (LPG) could represent a valid option, although it is not a renewable fuel. In terms of polluting emissions, the LPG can reduce nitrous oxides and smoke concentrations in the air, a capability that has a relevant importance for the modern pollution legislation. LPG is well known as an alternative fuel for Spark Ignition (SI) engines and, more recently, LPG systems have also been introduced in the Compression Ignition (CI) engines in dual-fuel configuration.

This work presents the results of an experimental investigation on a GDI injector, in order to analyze fuel injection process and atomization phenomenon, correlating imaging and vibro-acoustic diagnostic techniques. A single-hole, axially-disposed, 0.200 mm diameter GDI injector was used to spray commercial gasoline in a test chamber at room temperature and atmospheric backpressure. The explored injection pressures were ranged from 5.0 to 20.0 MPa. Cycle-resolved acquisitions of the spray evolution were acquired by a high-speed camera. Simultaneously, the vibro-acoustic response of the injector was evaluated. More in detail, noise data acquired by a microphone sensor were analyzed for characterizing the acoustic emission of the injection, while a spherical loudspeaker was used to excite the spray injection at a proper distance detecting possible fuel spray resonance phenomena.

The present work describes the numerical modeling of medium-speed marine engines, operating in a fumigated dual-fuel mode, i.e. with the second fuel injected in the ports. This engine technology allows reducing engine-out emissions while maintaining the engine efficiency and can be fairly easily retrofitted from current diesel engines. The main premixed fuel that is added can be a low-carbon one and can additionally be of a renewable nature, thereby reducing or even completely removing the global warming impact. To fully optimize the operational parameters of such a large marine engine, computational fluid dynamics can be very helpful. Accurately describing the combustion process in such an engine is key, as the prediction of the heat release and the pollutant formation is crucial. Auto-ignition of the diesel fuel needs to be captured, followed by the combustion and flame propagation of the premixed fuel.