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Technical Paper

Effect of Properties and Additives of Gasoline on Low-Speed Pre-Ignition in Turbocharged Engines

2022-08-30
2022-01-1077
Gasoline-related factors that affect low-speed pre-ignition (LSPI) include the distillation properties of gasoline, manganese (Mn), ethanol, diesel fuel, detergent for aftermarket, and iron (Fe). The combined effect of Mn with ethanol or high calcium engine oil (high-Ca oil) has not been sufficiently clarified. Therefore, appropriate countermeasures for LSPI have not yet been implemented. To clarify the effect of the gasoline properties and additives on LSPI, engine tests were conducted using gasoline with different “PM Index” values, an indicator of distillation properties, different concentrations of Mn, ethanol, diesel fuel, detergent, Fe, and high-Ca oil. The results showed that the LSPI frequency tended to increase with the PM Index, Mn up to 60 ppm, diesel fuel up to 2 vol.%, and detergent up to three times the standard amount.
Technical Paper

Study of Simple Detection of Gasoline Fuel Contaminants Contributing to Increase Particulate Matter Emissions

2020-04-14
2020-01-0384
The reduction of particulate emissions is one of the most important challenges facing the development of future gasoline engines. Several studies have demonstrated the impact of fuel chemical composition on the emissions of particulate matter, more particularly, the detrimental effect of high boiling point components such as heavy aromatics. Fuel contamination is likely to become a critical issue as new regulations such as Real Driving Emissions RDE involves the use of market fuel. The objective of this study is to investigate several experimental approaches to detect the presence of Diesel contamination in Gasoline which is likely to alter pollutant emissions. To achieve this, a fuel matrix composed of 12 fuels was built presenting diesel fuel in varying concentrations from 0.1 to 2% v/v. The fuel matrix was characterized using several original techniques developed in this study.
Technical Paper

Spray Characteristics of Gasoline-Ethanol Fuel Blends under Flash-Boiling Conditions

2019-04-02
2019-01-0297
The spray structure and vaporization processes of flash-boiling sprays in a constant volume chamber under a wide range of superheated conditions were experimentally investigated by a high speed imaging technique. The Engine Combustion Network’s Spray G injector was used. Four fuels including gasoline, ethanol, and gasoline-ethanol blends E30 and E50 were investigated. Spray penetration length and spray width were correlated to the degree of the superheated degree, which is the ratio of the ambient pressure to saturated vapor pressure (pa/ps). It is found that parameter pa/ps is critical in describing the spray transformation under flash-boiling conditions. Three distinct stages namely the slight flash-boiling, the transition flash-boiling, and the flare flash-boiling are identified to describe the transformation of spray structures.
Technical Paper

Critical Analysis of PM Index and Other Fuel Indices: Impact of Gasoline Fuel Volatility and Chemical Composition

2018-09-10
2018-01-1741
Among the challenges for the future facing the development of gasoline engines, one of the most important is the reduction of particles emissions. This study proposes a critical and objective evaluation of the influence of fuel characteristics on gasoline particles emission through the use of Fuel Particle Indices. For this, a selected fuel matrix composed of 22 fuels was built presenting different volatility and chemical composition (content in total aromatics, heavy cuts and ethanol). To represent the fuel sooting tendency, seven Fuel Particle Indices were selected based on a literature review, namely, Particulate Matter Index (PMI), Particulate Number index (PNI), Threshold Sooting index (TSI), Smoke point (SP), Oxygen Extended Sooting Index (OESI), Simplified index 1 and 2 (sPMI 1, sPMI 2). These indices were computed on the fuel matrix and compared on the basis of three main axes. First, the sensitivity to fuel variation.
Technical Paper

Effects of EGR Constituents and Fuel Composition on DISI Engine Knock: An Experimental and Modeling Study

2018-09-10
2018-01-1677
The use of exhaust gas recirculation (EGR) in spark ignition engines has been shown to have a number of beneficial effects under specific operating conditions. These include reducing pumping work under part load conditions, reducing NOx emissions and heat losses by lowering peak combustion temperatures, and by reducing the tendency for engine knock (caused by end-gas autoignition) under certain operating regimes. In this study, the effects of EGR addition on knocking combustion are investigated through a combined experimental and modeling approach. The problem is investigated by considering the effects of individual EGR constituents, such as CO2, N2, and H2O, on knock, both individually and combined, and with and without traces species, such as unburned hydrocarbons and NOx. The effects of engine compression ratio and fuel composition on the effectiveness of knock suppression with EGR addition were also investigated.
Technical Paper

Proceedings of Real Driving Emission (RDE) Measurement in China

2018-04-03
2018-01-0653
Light-duty China-6, which is among the most stringent vehicle exhaust emission standards globally, mandates the monitoring and reporting of real driving emissions (RDE) from July, 2023. In the process of regulation promulgation and verification, more than 300 RDE tests have been performed on over 50 China-5 and China-6 certified models. This technical paper endeavors to summarize the experience of RDE practice in China, and discuss the impacts of some boundary conditions (including vehicle dynamic parameters, data processing methods, hybrid propulsion and testing altitude) on the result of RDE measurement. In general, gasoline passenger cars confront few challenges to meet the upcoming RDE NOx requirement, but some China-5 certified samples, even powered by naturally-aspirated engines may have PN issues. PN emissions from some GDI-hybrid powertrain systems also need further reduction to meet China-6 RDE requirements.
Technical Paper

Soot and PAH Formation Characteristics of Methanol-Gasoline Belnds in Laminar Coflow Diffusion Flames

2018-04-03
2018-01-0357
Particulate matter emissions are becoming a big issue for GDI engines as the emission regulations being more stringent. Methanol has been considered to be an important alternative fuel to reduce soot emissions. To understand the effect of methanol addition on soot and polycyclic aromatic hydrocarbons (PAHs) formation, the 2-D distributions of soot volume fraction and different size PAHs relative concentrations in methanol/gasoline laminar diffusion flames were measured by TC-LII and PLIF techniques. The effect of methanol was investigated under the conditions of the same carbon flow and the same flame height. The methanol volume fraction was set as M0/20/40/60/80. The results showed that the natural luminescent flame lift-off height and soot lift-off height increases consistently with the increasing methanol content due to the increase of outlet velocity of fuel vapor.
Journal Article

Effects of High Boiling Point Fuel Additives on Deposits in a Direct Injection Gasoline Engine

2017-10-08
2017-01-2299
The effects of high boiling point fuel additives on deposits were investigated in a commercial turbocharged direct injection gasoline engine. It is known that high boiling point substances have a negative effect on deposits. The distillation end points of blended fuels containing these additives may be approximately 15°C higher than the base fuel (end point: 175°C). Three additives with boiling points between 190 and 196°C were examined: 4-tert-Butyltoluene (TBT), N-Methyl Aniline (NMA), and 2-Methyl-1,5-pentanediamine (MPD). Aromatics and anilines, which may be added to gasoline to increase its octane number, might have a negative effect on deposits. TBT has a benzene ring. NMA has a benzene ring and an amino group. MPD, which has no benzene ring and two amino groups, was selected for comparison with the former two additives.
Technical Paper

Effect of Ethanol Addition on Soot Formation of Gasoline in Laminar Diffusion Flames

2017-10-08
2017-01-2396
Soot emission, known as PM (particulate matter), is becoming a big issue for GDI engines as the emission regulations being increasingly stricter. It is found that ethanol, as an oxygenated bio-fuel, can reduce the soot emission when added to gasoline. In order to fully understand the effect of ethanol on soot reducing, the soot characteristics of ethanol/gasoline blends were studied on laminar diffusion flames. In this experiment, the blending ratio of ethanol/gasoline was set as E0/20/40/60/80. Considering the carbon content decreasing due to ethanol addition, carbon mass flow rate was remained constant. The two-dimensional distributions of soot volume fraction were measured quantitatively by using two-color laser induced incandescence technique. The results showed that ethanol is able to decrease the soot significantly, but the effect of ethanol on soot reduction is weakened with the increasing ethanol ratio.
Journal Article

An Intake Valve Deposit (IVD) Engine Test Development to Investigate Deposit Build-Up Mechanism Using a Real Engine

2017-10-08
2017-01-2291
In emerging markets, Port Fuel Injection (PFI) technology retains a higher market share than Gasoline Direct Injection (GDI) technology. In these markets fuel quality remains a concern even despite an overall improvement in quality. Typical PFI engines are sensitive to fuel quality regardless of brand, engine architecture, or cylinder configuration. One of the well-known impacts of fuel quality on PFI engines is the formation of Intake Valve Deposits (IVD). These deposits steadily accumulate over time and can lead to a deterioration of engine performance. IVD formation mechanisms have been characterized in previous studies. However, no test is available on a state-of-the-art engine to study the impact of fuel components on IVD formation. Therefore, a proprietary engine test was developed to test several chemistries. Sixteen fuel blends were tested. The deposit formation mechanism has been studied and analysed.
Technical Paper

Estimating Ozone Potential of Pipe-out Emissions from Euro-3 to Euro-5 Passenger Cars Fueled with Gasoline, Alcohol-Gasoline, Methanol and Compressed Natural Gas

2016-04-05
2016-01-1009
Along with the booming expansion of private car preservation, many Chinese cities are now struggling with hazy weather and ground-level ozone contamination. Although central government has stepped up efforts to purify skies above China, counter-strategies to curb ground-level ozone is comparatively weak. By using maximum incremental reactivity (MIR) method, this paper estimated the ozone forming potential for twenty-five Euro-3 to Euro-5 passenger cars burning conventional gasoline, methanol-gasoline, ethanol-gasoline, neat methanol and compressed natural gas (CNG). The results showed that, for all the fuel tested, VOC/NOx ratios and SR values decreased with the upgrading of emission standard. Except for Euro-3 M100 and Euro-4 M85, SR values for alternative fuel were to different degrees smaller than those for gasoline. When the emission standard was shifted from Euro-4 to Euro-5, OFP values estimated for gasoline vehicle decreased.
Technical Paper

Engine Oil Formulation Technology to Prevent Pre-ignition in Turbocharged Direct Injection Spark Ignition Engines

2015-09-01
2015-01-2027
Engine oil formulation is known to affect low speed pre-ignition (LSPI), which creates technical restrictions on downsized turbocharged engines. Calcium, which is used to ensure detergency and anti-rust performance, is reported to increase LSPI events. Therefore, new formulation technologies are needed to satisfy both LSPI prevention performance and other conventional performance areas. The authors focused on two approaches: enhancement of LSPI prevention performance by adding a booster component and substitution of calcium for a less reactive component to balance performance areas including LSPI prevention. We have verified the effectiveness of these approaches by increasing the dosage of molybdenum used as a friction modifier as well as replacing calcium detergent with a magnesium detergent. These formulation strategies can be applicable for future ILSAC GF-6 engine oil, where a specification for LSPI prevention performance is expected to be implemented.
Technical Paper

Mechanism of Turbocharger Coking in Gasoline Engines

2015-09-01
2015-01-2029
Turbocharged downsized gasoline engines have been widely used in the market as one of the measures to improve fuel economy. Coking phenomena in the lubricating circuit of the turbocharger unit is a well-known issue that may affect turbocharger efficiency and durability. Laboratory rig test such as ASTM D6335 (TEOST 33C) has been used to predict this phenomenon as a part of engine oil performance requirements. On the other hand, laboratory tests sometimes have difficulty reproducing the actual mechanism of coking caused by engine oil degradation. Accumulation of insoluble material is one of the important gasoline engine oil degradation modes. The influence of temperature and insoluble concentration were investigated based on actual used engine oils collected in the field.
Technical Paper

Regulated, Carbonyl Emissions and Particulate Matter from a Dual-Fuel Passenger Car Burning Neat Methanol and Gasoline

2015-04-14
2015-01-1082
As a probable solution to both energy and environmental crisis, methanol and methanol gasoline have been used as gasoline surrogates in several provinces of China. Most recently, the Ministry of Environmental Protection of China is drafting a special emission standard for methanol-fueled light-duty vehicles. Given the scarcity of available data, this paper evaluated regulated emissions, carbonyl compounds and particulate matter from a China-5 certificated gasoline/methanol dual-fuel vehicle over New European Driving Cycle (NEDC). The results elucidated that in context with gasoline mode, CO emitted in methanol mode decreased 11.2%, while no evident changes of THC and NOx emissions were noticed with different fueling regimes. The total carbonyls and formaldehyde have increased by 39.5% and 19.8% respectively after switching from gasoline to methanol. A remarkable decrease of 65.6% in particulate matter was observed in methanol mode.
Technical Paper

Study on Haptic Maneuver Guidance by Periodic Knocks on Accelerator Pedal

2015-03-10
2015-01-0039
This study proposes a method for presenting maneuver request information of accelerator pedal to a driver via the accelerator pedal itself. By applying periodic force like vibration on an accelerator pedal, information is transferred to the driver without displacing the accelerator pedal. In this study, the authors focus on a saw-tooth wave as the periodic force. When the saw-tooth-waved force is applied on the accelerator pedal, a human driver feels as if the accelerator pedal is knocked by someone periodically. In addition, information about the quantity of requested maneuver can be transferred by the amplitude of the saw-tooth wave. Based on these facts, the saw-tooth wave is modified and optimized empirically with ten human drivers so that the information of direction is transferred most reliably. In addition, the relationship between the amplitude of the saw-tooth wave and requested quantity of the pedal maneuver that the drivers feel is formulated.
Journal Article

Pre-Ignition of Gasoline-Air Mixture Triggered by a Lubricant Oil Droplet

2014-10-13
2014-01-2627
This paper presents the effects of a lubricant oil droplet on the start of combustion of a fuel-air mixture. Lubricant oil is thought to be a major source of low-speed pre-ignition in highly boosted spark ignition engines. However, the phenomenon has not yet been fully understood because its unpredictability and the complexity of the mixture in the engine cylinder make analysis difficult. In this study, a single oil droplet in a combustion cylinder was considered as a means of simplifying the phenomenon. The conditions under which a single oil droplet ignites earlier than the fuel-air mixture were investigated. Tests were conducted by using a rapid compression expansion machine. A single oil droplet was introduced into the cylinder through an injector developed for this study. The ignition and the flame propagation were observed through an optical window, using a high-speed video camera.
Journal Article

Engine Oil Development for Preventing Pre-Ignition in Turbocharged Gasoline Engine

2014-10-13
2014-01-2785
Gasoline engine downsizing combined with a turbocharger is one of the more effective approaches to improve fuel efficiency without sacrificing power performance. The benefit comes from lower pumping loss, lower mechanical friction due to ‘downsizing’ of the engine displacement and ‘down-speeding’ of the engine by using higher transmission gear ratios which is allowed by the higher engine torque at lower engine speeds. However abnormal combustion referred to as Low-Speed Pre-ignition (LSPI) is known to be able to occur in low-speed and high-torque conditions. It is a potential restriction to maximize the engine performance and its benefit, therefore prevention of LSPI is strongly desired for long-term durability of engine performance. According to recent technical reports, auto-ignition of an engine oil droplet in a combustion chamber is believed to be one of major contributing factors of LSPI and its formulations have a significant effect on LSPI frequency.
Journal Article

New Combustion Concept for Turbocharged Gasoline Direct-Injection Engines

2014-04-01
2014-01-1210
The advantages of gasoline direct-injection are intake air cooling due to fuel vaporization which reduces knocking, additional degrees of freedom in designing a stratified injection mixture, and capability for retarded ignition timing which shortens catalyst light-off time. Stratified mixture combustion designs often require complicated piston shapes which disturb the fluid flow in the cylinder, leading to power reduction, especially in turbocharged gasoline direct-injection engines. Our research replaced the conventional shell-type shallow cavity piston with a dog dish-type curved piston that includes a small lip to facilitate stratification and minimize flow disturbance. As a result, stable stratified combustion and increased power were both achieved.
Journal Article

Study of Low-Speed Pre-Ignition in Boosted Spark Ignition Engine

2014-04-01
2014-01-1218
This paper analyzes low-speed pre-ignition (LSPI), a sudden pre-ignition phenomenon that occurs in downsized boosted gasoline engines in low engine speed high-load operation regions. This research visualized the in-cylinder state before the start of LSPI combustion and observed the behavior of particles, which are thought to be the ignition source. The research also analyzed pre-ignition by injecting deposit flakes and other combustible particulate substances into the combustion chamber. The analysis found that these particles require at least two combustion cycles to reach a glowing state that forms an ignition source. As a result, deposits peeling from combustion chamber walls were identified as a new mechanism causing pre-ignition. Additionally, results also suggested that the well-known phenomenon in which the LSPI frequency rises in accordance with greater oil dilution may also be explained by an increase in deposit generation.
Journal Article

Onboard Gasoline Separation for Improved Vehicle Efficiency

2014-04-01
2014-01-1200
ExxonMobil, Corning and Toyota have collaborated on an Onboard Separation System (OBS) to improve gasoline engine efficiency and performance. OBS is a membrane based process that separates gasoline into higher and lower octane fractions, allowing optimal use of fuel components based on engine requirements. The novel polymer-ceramic composite monolith membrane has been demonstrated to be stable to E10 gasoline, while typically providing 20% yield of ∼100 RON product when using RUL 92 RON gasoline. The OBS system makes use of wasted exhaust energy to effect the fuel separation and provides a simple and reliable means for managing the separated fuels that has been demonstrated using several generations of dual fuel test vehicles. Potential applications include downsizing to increase fuel economy by ∼10% while maintaining performance, and with turbocharging to improve knock resistance.
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