Search Results

Styrene, or ethylbenzene, is mainly used as a monomer for the production of polymers, most notably Styrofoam. In the synthetis of styrene, the feedstock of benzene and ethylene is converted into aromatic oxygenates such as benzaldehyde, 2-phenyl ethanol and acetophenone. Benzaldehyde and phenyl ethanol are low value side streams, while acetophenone is a high value intermediate product. The side streams are now principally rejected from the process and burnt for process heat. Previous in-house research has shown that such aromatic oxygenates are suitable as diesel fuel additives and can in some cases improve the soot-NOx trade-off. In this study acetophenone, benzaldehyde and 2-phenyl ethanol are each added to commercial EN590 diesel at a ratio of 1:9, with the goal to ascertain whether or not the lower value benzaldehyde and 2-phenyl ethanol can perform on par with the higher value acetophenone. These compounds are now used in pure form.

This paper presents a large eddy simulation study of the liquid spray mixing with hot ambient gas in a constant volume vessel under engine-like conditions with the injection pressure of 1500 bar, ambient density 22.8 kg/m₃, ambient temperature of 900 K and an injector nozzle of 0.09 mm. The simulation results are compared with the experiments carried out by Pickett et al., under similar conditions. Under modern direct injection diesel engine conditions, it has been argued that the liquid core region is small and the droplets after atomization are fine so that the process of spray evaporation and mixing with the air is controlled by the heat and mass transfer between the ambient hot gas and central fuel flow. To examine this hypothesis a simple spray breakup model is tested in the present LES simulation. The simulations are performed using an open source compressible flow solver, in OpenFOAM.

Unburned hydrocarbon (UHC) and carbon monoxide (CO) emission sources are examined in an optical, light-duty diesel engine operating under low load and engine speed, while employing a highly dilute, partially premixed low-temperature combustion (LTC) strategy. The impact of engine load and charge dilution on the UHC and CO sources is also evaluated. The progression of in-cylinder mixing and combustion processes is studied using ultraviolet planar laser-induced fluorescence (UV PLIF) to measure the spatial distributions of liquid- and vapor-phase hydrocarbon. A separate, deep-UV LIF technique is used to examine the clearance volume spatial distribution and composition of late-cycle UHC and CO. Homogeneous reactor simulations, utilizing detailed chemical kinetics and constrained by the measured cylinder pressure, are used to examine the impact of charge dilution and initial stoichiometry on oxidation behavior.

Power supply systems play a very important role in applications of everyday life. Mainly, for low power generation, there are two ways of producing energy: electrochemical batteries and small engines. In the last few years many improvements have been carried out in order to obtain lighter batteries with longer duration but unfortunately the energy density of 1 MJ/kg seems to be an asymptotic value. If the energy source is an organic fuel with an energy density of around 29 MJ/kg and a minimum overall efficiency of only 3.5%, this device can surpass the batteries. Nowadays the most efficient combustion process is HCCI combustion which is able to combine high energy conversion efficiency and low emission levels with a very low fuel consumption. In this paper, an investigation has been carried out concerning the effects of the compression ratio on the performance and emissions of a mini, Vd = 4.11 [cm3], HCCI engine fueled with diethyl ether.

Experiments on a modern DI Diesel engine were carried out: The engine was fuelled with standard Diesel fuel, RME and a mixture of 85% standard Diesel fuel, 5% RME and 10% higher alcohols under low load conditions (4 bar IMEP). During these experiments, different external EGR levels were applied while the injection timing was chosen in a way to keep the location of 50% heat release constant. Emission analysis results were in accordance with widely known correlations: Increasing EGR rates lowered NOx emissions. This is explained by a decrease of global air-fuel ratio entailing longer ignition delay. Local gas-fuel ratio increases during ignition delay and local combustion temperature is lowered. Exhaust gas analysis indicated further a strong increase of CO, PM and unburned HC emissions at high EGR levels. This resulted in lower combustion efficiency. PM emissions however, decreased above 50% EGR which was also in accordance with previously reported results.

High-speed video imaging in a swirl-supported (Rs = 1.7), direct-injection heavy-duty diesel engine operated with moderate-to-high EGR rates reveals a distinct correlation between the spatial distribution of luminous soot and mean flow vorticity in the horizontal plane. The temporal behavior of the experimental images, as well as the results of multi-dimensional numerical simulations, show that this soot-vorticity correlation is caused by the presence of a greater amount of soot on the windward side of the jet. The simulations indicate that while flow swirl can influence pre-ignition mixing processes as well as post-combustion soot oxidation processes, interactions between the swirl and the heat release can also influence mixing processes. Without swirl, combustion-generated gas flows influence mixing on both sides of the jet equally. In the presence of swirl, the heat release occurs on the leeward side of the fuel sprays.

In this paper a fast NOx model is presented which can be used for engine optimization, aftertreatment control or virtual mapping. A cylinder pressure trace is required as input data. High calculation speed is obtained by using table interpolation to calculate equilibrium temperatures and species concentrations. Test data from a single-cylinder engine and from a complete six-cylinder engine have been used for calibration and validation of the model. The model produces results of good agreement with emission measurements using approximately 50 combustion product zones and a calculation time of one second per engine cycle. Different compression ratios, EGR rates, injection timing, inlet pressures etc. were used in the validation tests.

Emissions standards are becoming increasingly harder to reach without the use of exhaust aftertreatment systems such as Selective Catalytic Reduction and particulate filters. In order to make efficient use of these systems it is important to have accurate models of engine-out emissions. Such models are also useful for optimizing and controlling next-generation engines without aftertreatment using for example exhaust gas recirculation (EGR). Engines are getting more advanced using systems such as common rail fuel injection, variable geometry turbochargers (VGT) and EGR. With these new technologies and active control of the injection timing, more sophisticated models than simple stationary emission maps must be used to get adequate results. This paper is focused on the calculation of engine-out NOx and engine parameters such as cylinder pressure, temperature and gas flows.

In this paper the combustion chamber wall temperature was measured by the use of thermographic phosphor. The temperature was monitored over a large time window covering a load transient. Wall temperature measurement provide helpful information in all engines. This temperature is for example needed when calculating heat losses to the walls. Most important is however the effect of the wall temperature on combustion. The walls can not heat up instantaneously and the slowly increasing wall temperature following a load transient will affect the combustion events sucseeding the transient. The HCCI combustion process is, due to its dependence on chemical kinetics more sensitive to wall temperature than Otto or Diesel engines. In depth knowledge about transient wall temperature could increase the understanding of transient HCCI control. A “black box” state space model was derived which is useful when predicting transient wall temperature.

A five-cylinder diesel engine, converted to a single cylinder operated optical engine is run in Homogeneous Charge Compression Ignition (HCCI) mode. A blend of iso-octane and n-heptane is used as fuel. An experimental study of the horizontal boundary layer between the main combustion and the non-reacting surface of the combustion chamber is conducted as a function of speed, load, swirl and injection strategy. The combustion behaviour is monitored by chemiluminescence measurements. For all cases an interval from -10 to 16 crank angles after top dead center (CAD ATDC) in steps of one CAD are studied. One image-intensified camera observes the boundary layer up close from the side through a quartz cylinder liner while a second camera has a more global view from below to see more large scale structure of the combustion. The averaged chemiluminescence intensity from the HCCI combustion is seen to scale well with the rate of heat release.

Autoignition of a homogeneous mixture is very sensitive to operating conditions. Therefore fast combustion phasing control is necessary for reliable operation. There are several means to control the combustion phasing of a Homogeneous Charge Compression Ignition (HCCI) engine. This paper presents cycle-to-cycle cylinder individual control results from a six-cylinder HCCI engine using a Variable Valve Actuation (VVA) system. As feedback signal, the crank angle for 50% burned, based on cylinder pressure, is used. Three control structures are evaluated, Model Predictive Control (MPC), Linear Quadratic Gaussian control (LQG) and PID control. In the control design of the MPC and LQG controller, dynamic models obtained by system identification were used. Successful experiments were performed on a port-injected six-cylinder heavy-duty Diesel engine operating in HCCI mode.

Exhaust Emissions from lean burn natural gas engines may not always be as low as the potential permits, especially engines with open loop lambda control. These engines can produce much higher emissions than a comparable diesel engine without exhaust gas after treatment. Even if the engine has closed loop lambda control, emissions are often unacceptably high for future emission regulations. A three way catalyst is, today, the best way to reduce hazardous emissions. The drawback is that the engine has to operate with a stoichiometric mixture and this leads to; higher heat losses, higher pumping work at low to medium loads, higher thermal stress on the engine and higher knock tendency (requiring lower compression ratio, and thus lower brake efficiency). One way to reduce these drawbacks is to dilute the stoichiometric mixture with EGR. This paper compares lean burn operation with operation at stoichiometric conditions diluted with EGR, and using a three way catalyst.

Piston temperature experiments were conducted in a single-cylinder heavy-duty Diesel research engine, based on the Volvo Powertrain D12C engine both by use of optical temperature sensitive phosphor and of thermocouples mounted on the piston surface. In the former case, a thin coating of a suitable thermographic phosphor was applied to the areas on the piston surface to be investigated. The optical measurements of piston temperatures made involved use of an optical window and of an endoscope. The possibility of using optical fibres into guide light in and out of the engine was also investigated. Results of the optical and of the thermocouple measurements were compared and were also related to more global data with the aim of exploring the use of thermographic phosphors for piston- temperature measurements in Diesel engines. Thermographic phosphors thermometry was found to represent an alternative to the thermocouple method since it easily can be applied to various piston geometries.

A known problem of the HCCI engine is its lack of direct control and its requirements of feedback control. Today there exists several different means to control an HCCI engine, such as dual fuels, variable valve actuation, inlet temperature and compression ratio. Independent of actuation method a sensor is needed. In this paper we perform closed-loop control based on two different sensors, pressure and ion current sensor. Results showing that they give similar control performance within their operating range are presented. Also a comparison of two methods of designing HCCI timing controller, manual tuning and model based design is presented. A PID controller is used as an example of a manually tuned controller. A Linear Quadratic Gaussian controller exemplifies model based controller design. The models used in the design were estimated using system identification methods. The system used in this paper performs control on cycle-to-cycle basis. This leads to fast and robust control.

Homogeneous Charge Compression Ignition (HCCI) holds great promises for good fuel economy and low emissions of NOX and soot. The concept of HCCI is premixed combustion of a highly diluted mixture. The dilution limits the combustion temperature and thus prevents extensive NOX production. Load is controlled by altering the quality of the charge, rather than the quantity. No throttling together with a high compression ratio to facilitate auto ignition and lean mixtures results in good brake thermal efficiency. However, HCCI also presents challenges like how to control the combustion and how to achieve an acceptable load range. This work is focused on solutions to the latter problem. The high dilution required to avoid NOX production limits the mass of fuel relative to the mass of air or EGR. For a given size of the engine the only way to recover the loss of power due to dilution is to force more mass through the engine.

This paper discusses the effects of cooled EGR on a turbo charged multi cylinder HCCI engine. A six cylinder, 12 liter, Scania D12 truck engine is modified for HCCI operation. It is fitted with port fuel injection of ethanol and n-heptane and cylinder pressure sensors for closed loop combustion control. The effects of EGR are studied in different operating regimes of the engine. During idle, low speed and no load, the focus is on the effects on combustion efficiency, emissions of unburned hydrocarbons and CO. At intermediate load, run without turbocharging to achieve a well defined experiment, combustion efficiency and emissions from incomplete combustion are still of interest. However the effect on NOx and the thermodynamic effect on thermal efficiency, from a different gas composition, are studied as well. At high load and boost pressure the main focus is NOx emissions and the ability to run high mean effective pressure without exceeding the physical constraints of the engine.

Ion current measurements can give information useful for controlling the combustion stability in a multi-cylinder engine. Operation near the dilution limit (air or EGR) can be achieved and it can be optimized individually for the cylinders, resulting in a system with better engine stability for highly diluted mixtures. This method will also compensate for engine wear, e.g. changes in volumetric efficiency and fuel injector characteristics. Especially in a port injected engine, changes in fuel injector characteristics can lead to increased emissions and deteriorated engine performance when operating with a closed-loop lambda control system. One problem using the ion-current signal to control engine stability near the lean limit is the weak signal resulting in low signal to noise ratio. Measurements presented in this paper were made on a turbocharged 9.6 liter six cylinder natural gas engine with port injection.

A comparison of scanning mobility particle sizer (SMPS) and laser-induced incandescence (LII) measurements of diesel particulate matter (PM) was performed. The results reveal the significance of the aggregate nature of diesel PM on interpretation of size and volume fraction measurements obtained with an SMPS, and the accuracy of primary particle size measurements by LII. Volume fraction calculations based on the mobility diameter measured by the SMPS substantially over-predict the space-filling volume fraction of the PM. Correction algorithms for the SMPS measurements, to account for the fractal nature of the aggregate morphology, result in a substantial reduction in the reported volume. The behavior of the particulate volume fraction, mean and standard deviation of the mobility diameter, and primary particle size are studied as a function of the EGR for a range of steady-state engine speeds and loads for a turbocharged direct-injection diesel engine.

“Hot Bulb engines” was the popular name of the early direct injected 2-stroke oil engine, invented and patented by Carl W. Weiss 1897. This paper covers engines of this design, built under license in Sweden by various manufacturers. The continuous development is demonstrated through examples of different combustion chamber designs. The material is based on official engine performance evaluations on stationary engines and farm tractors from 1899 to 1995 made by the National Machinery Testing Institute in Sweden (SMP). Hot-bulb, diesel and spark ignited engines are compared regarding efficiency, brake mean effective pressure and specific power (power per displaced volume). The evaluated hot-bulb engines had a fairly good efficiency, well matching the contemporary diesel engines. At low mean effective pressures, the efficiency of the hot-bulb engines was even better than that of subsequent diesel engines.

SI Engine knock is caused by autoignition in the unburnt part of the mixture (end-gas) ahead of the propagating flame. Autoignition of the end-gas occurs when the temperature and pressure exceeds a critical limit when comparatively slow reactions-releasing moderate amounts of heat-transform into ignition and rapid heat release. In this paper the difference in the heat released in the end-gas-by low temperature chemistry-between lean, rich, stochiometric, and stoichiometric mixtures diluted with cooled EGR was examined by measuring the temperature in the end-gas with Dual Broadband Rotational CARS. The measured temperature history was compared with an isentropic temperature calculated from the cylinder pressure trace. The experimentally obtained values for knock onset were compared with results from a two-zone thermodynamic model including detailed chemistry modeling of the end-gas reactions.