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A two-stage combustion is one of the Mitsubishi GDI™ technologies for a quick catalyst warm-up on a cold-start. However, when the combustion is continued for a long time, an increase in the fuel consumption is a considerable problem. To solve the problem, a stratified slight-lean combustion is newly introduced for utilization of catalysis. The stratified mixture with slightly lean overall air-fuel ratio is prepared by the late stage injection during the compression stroke. By optimizing an interval between the injection and the spark timing, the combustion simultaneously supplies substantial CO and surplus O2 to a catalyst while avoiding the soot generation and the fouling of a spark plug. The CO oxidation on the catalyst is utilized to reduce the cold-start emissions. Immediately after the cold-start, the catalyst is preheated for the minimum time to start the CO oxidation by using the two-stage combustion. Following that, the stratified slight-lean combustion is performed.

An extensive effort has been made, at Mitsubishi Motors, in the technology field of new catalysts and of the catalyst reaction control for the purpose of further improvement of the emission control with the GDI engines [1-2]. A new NOx-trap catalyst has been developed to satisfy the required higher catalyst performance under high-temperature condition. The new catalyst contains potassium (K) of excellent NOx-storage capacity under high-temperature region in the catalytic atmosphere, and to retain K stability zeolite is mixed in the catalyst layer as well as the substrate is coated with silica (SiO2). This new catalyst has been proven of the improved NOx conversion efficiency, and solved the long-pending problems particularly those experienced under high-temperature operation.

NOx adsorber has already been used for the after-treatment system of series production vehicle installed with a lean burn or direct injection engine [1,2,3]. In order to improve NOx adsorbability at high temperatures, many researchers have recently been trying an addition of potassium (K) as well as other conventional NOx adsorbents. Potassium, however, reacts easily with the cordierite honeycomb substrate at high temperatures, and not only causes a loss in NOx adsorbability but also damages the substrate. Three new technologies have been proposed in consideration of the above circumstances. First, a new concept of K-capture is applied in washcoat design, mixed with zeolite, to improve thermal stability of K and to keep high NOx conversion efficiency, under high temperatures, of NOx adsorber catalyst. Second, another new technology, pre-coating silica over the boundary of a substrate and washcoat, is proposed to prevent the reaction between potassium and cordierite.

In the next few years, the USA, EU, and Japan plan to introduce very stringent exhaust emissions regulations for heavy–duty diesel engines, in order to enhance the protection air quality. This builds upon the heavy–duty diesel engine exhaust emissions regulations already in effect. At the same time, improvement in fuel consumption of heavy–duty diesel engines will be very important for lowering vehicle operating costs, conserving fossil fuel resources, and reduction of CO2 (greenhouse gas) levels. This paper presents a detailed review of a quiescent combustion system for a heavy–duty diesel engine, which offers breakthrough performance in terms of the exhaust emissions – fuel consumption trade–off, compared with the more conventional swirl supported combustion system. This conclusion is supported by experimental results comparing quiescent and swirl supported versions of various combustion system configurations.

In this study, the oxidation stability, soot dispersancy, antiwear performance, and friction-reducing capability of friction modifiers (FMs) were evaluated, and an SAE 5W-30 fully synthetic oil with MoDTC type FMs was developed for heavy-duty diesel engines. In several engine tests, it was confirmed that the developed oil can double the oil drain interval in comparison with API CD SAE 30, even when EGR is applied, and improves the fuel efficiency.

GDI (Gasoline Direct Injection) engine adopting new combustion control technologies was developed and introduced into Japanese domestic market in August of 1996. In order to extend its application to the European market, various system modifications have been performed. Injectors are located with a smaller angle to the vertical line in order to improve the combustion stability in the higher speed range. A new combustion control method named “two-stage mixing” is adopted to suppress the knock in the low speed range. As a result of this new method, the compression ratio was increased up to 12.5 to 1 while increasing the low-end torque significantly. Taking the high sulfur gasoline in the European market into account, a selective reduction lean-NOx catalyst with improved NOx conversion efficiency was employed. A warm-up catalyst can not be used because the selective reduction lean NOx catalyst requires HC for the NOx reduction.

The major problems of the various mixture formation concepts for direct injection gasoline engines that have been proposed up to the present were caused by the difficulties of preparing the mixture with adequate strength at spark plug in wide range of engine operating conditions. Novel combustion control technologies proposed by Mitsubishi is one of the solution for these problems. By adopting upright straight intake ports to generate air tumble, an electromagnetic swirl injector to realize optimized spray dispersion and atomization and a compact piston cavity to maintain charge stratification, it has become possible to achieve super-lean stratified combustion for higher thermal efficiency under partial loads as well as homogeneous combustion to realize higher performance at full loads. GDI™ (Gasoline Direct Injection) engine adopting these technologies is developed. At partial loads, fuel economy improvement exceeding 30 % is realized.

In this study three EGR methods were applied to a 12 liter turbocharged and intercooled Dl diesel engine, and the exhaust emission and fuel consumption characteristics were compared. One method is the Low Pressure Route system, in which the EGR is taken from down stream of the turbine to the compressor entrance. The other two systems are variations of the High Pressure Route system, in which the EGR is taken from the exhaust manifold to the intake manifold. One of the two High Pressure Route EGR systems is with back pressure valve located at downstream of the turbine and the other uses a variable geometry(VG) turbocharger. It was found that the High Pressure Route EGR system using VG turbocharger was the most effective and practical. With this method the EGR area could be enlarged and NOx reduced by 22% without increase in smoke or fuel consumption while maintaining an adequate excess air ratio.

In this study a new water injection system was applied to an 11 liter naturally aspirated DI diesel engine in order to reduce exhaust emissions. In this system, the water and fuel were arranged in the injection nozzle during the time between injections as fuel, water and then fuel. The fuel and water were then injected into the cylinder in that order. The tests were conducted at several engine operating conditions from the Japanese 13 mode test cycle to clarify effects of water injection on exhaust emissions and fuel consumption. The results showed that NOx reduction was directly proportional to the relative amount of water injection, regardless of engine speed and load. By using the optimal relative amount of water injection at each engine operating condition, total NOx and particulate matter (PM) in the Japanese 13 mode test cycle were reduced by 50% and 25%, respectively, without a fuel consumption penalty.

Diesel emission control is being addressed worldwide to help preserve the global environment. In 1994, emission controls in the U.S. called for reduction of diesel particulate matter (PM) to 10 to 20% of 1986's initial limit. In the same year, we developed and marketed small and medium duty trucks which were equipped with PM reduction systems that oxidize soluble organic fraction (SOF) contained in the PM, in order to satisfy these new regulations. Prior to their marketing, a catalyst was selected from among several types of candidate catalysts. Durability tests were performed using a catalytic converter-equipped small duty truck to verify the durability of the chosen catalyst. The durability test course was set up combining urban areas and expressways in the southern part of California, U.S.A.. The cumulative total distance covered on the test course reached 200,000 km. During the durability test, the catalyst was evaluated by measurement of PM emission using a chassis dynamometer.

In the diesel engine industry, the growing trends are toward wider use of electronically controlled high pressure fuel injection equipment to provide better engine performance, while conforming to the stringent exhaust emission standards. Although there have been some recent announcements of a diesel engine that applies an electronically controlled common rail type fuel injection system, there is little literature published about any attempt to reduce both exhaust emissions and noise and to improve engine performance by varying injection pressure and injection timing independently and introducing pilot injection in combination. This paper describes the details of a study made on the parameters associated with injection timing, injection pressure and pilot injection and the procedures for their optimization, with an electronically controlled common rail type fuel injection system installed in an in-line 6-cylinder 6.9 liter turbocharged and intercooled DI diesel engine.

In order to reduce exhaust emission and combustion noise and to improve fuel consumption, the effects of the combustion system parameters of a diesel engine, such as injection pressure, injection nozzle hole diameter, swirl ratio, and EGR rate on exhaust emissions, combustion noise and fuel consumption are investigated and described in detail by analyzing rate of heat release, needle valve lift and injection pressure. Based on these results, reduction of exhaust emission and combustion noise and improvement of fuel consumption are described in the latter part of this paper. These results are shown as follows. The smaller nozzle hole diameter is effective for reducing smoke and PM, and by optimizing the injection timing and swirl ratio, NOx can also be reduced. In addition to the above, by applying EGR and higher injection pressure it is possible to improve the fuel consumption with the remaining low NOx and PM.

A new type of catalytic converter has been developed for the coming TLEV (Transitional Low Emission Vehicle) standards. It is a “Front Curve Catalytic Converter (FCCC)” using a curved cordierite ceramic honeycomb substrate. During this development, an optimum location and volume of the front curve catalytic converter were determined from the view points of thermal deterioration of the catalyst and hydrocarbon conversion performance. Based on CAE (Computer Aided Engineering) analysis, the best curvature radius of the substrate was selected to minimize a pressure drop of the front curve catalytic converter. The emission conversion and light-off performances of the front curve catalytic converter were compared with a conventional straight design. A series of durability tests; hot vibration, engine dynamometer and vehicle fleet tests were also conducted to confirm the reliability of the new front curve catalytic converter.

The authors used a mass spectrometer to determine an SOF reduction mechanism of a diesel oxidation catalyst. The results indicate that SOF reduction lies in the catalytic conversion of high molecular organic matter to low molecular organic matter. And unregulated emissions are also reduced through this conversion. It is also found that the SOF reduction performance is highly dependent up on the condition of the wash coat. There is some limitation to improving diesel oxidation catalyst performance because of the sulfur content found in diesel fuel. Finally, the authors have determined what we think are the specifications of the presently best catalytic converter.

A fuel control method to reduce the harmful exhaust gas from SI engines is proposed. As is well known, both the amplitude and the frequency of the limit cycle in a conventional air-fuel ratio control system are determined uniquely by parameters in the system. And this limits our making full use of the oxygen storage effect of TWC. A simple model of TWC reaction revealed the relationship between maximum conversion efficiency and both the amplitude and the frequency in a air fuel control system. It also revealed that TWC conversion efficiency attained to maximum levels when both the amplitude and the frequency of the limit cycle are selected so as to make full use of the oxygen storage effect of TWC. In order to achieve this, it is necessary to vary both the amplitude and the frequency arbitrarily.

A flexible fuel vehicle (FFV) was evaluated through various tests for its potential as an alternative to the conventional gasoline vehicle. This paper presents the systems incorporated in the FFV and the test results. 50,000 mile emission durability tests were also performed and the potential of the FFV as a “Low Emission Vehicle” was assessed. As the result of extensive engineering work, we successfully developed a Galant FFV which exhibits very good durability and reliability. The emission control system which we have developed demonstrated that the vehicle has a good potential to comply with the California formaldehyde emission standard of 15 mg/mile. However, due to the large portion of unburnt methanol in the tail-pipe emissions, FFVs will have more difficulty than gasoline vehicles in meeting non-methane organic gas (NMOG) standards applicable to “Low Emission Vehicles”.

Protection of the Earth's environment by means of energy saving and cleaning up of air pollution on a global scale is one of the most important subjects in the world today. Because of this, the requirements for better fuel economy and cleaner exhaust emissions of internal combustion engines have been getting stronger, and, in particular, simultaneous reduction in nitrogen oxides (NOx) and particulate matter (PM) from heavy-duty diesel engines (HDDEs) without degrading fuel economy has become a major subject. Mitsubishi Motors Corporation (MM) has been selling diesel-powered heavy-duty trucks in the U.S. market since 1985 and has agressively carried out development work for meeting the 1991 model year exhaust emission standards.

A new prototype oxygen storage componented oxygen sensor has been developed which shows significant emission reductions of a 3-way catalyst system. This sensor is composed of ceria, as an oxygen storage component and supported pellets as a buffer layer surrounding the protective coating of the sensor element. This sensor offers a more rapid response than conventional ones under lean and rich fuel mixture excursions, which is caused by CO or O2 electrode poisoning.

The accuracy of real-time A/F measurement at engine test benches has been improved with a modified equation to calculate A/F from exhaust gas composition. In addition to CO, CO2, total hydrocarbon (THC) and O2, the proposed equation includes NO and NO2 concentration as variables. In an attempt to improve the accuracy of the assumed constants in the equation, experiments have been conducted using automotive exhaust H2O and H2 analyzers. The accuracy of the proposed equation was proven through experiments and it was also found useful for precise evaluation of three-way catalyst or oxygen sensor characteristics.

A particulate trap oxidizer system to reduce diesel particulate emissions has been developed. This system consists of a ceramic foam filter with an optimum volume, shape, and mesh number in terms of collection efficiency, pressure loss and particulate blow-off; a catalyst with a low activated-temperature for particulate incineration and with no sulfate formation during highway driving; and a regeneration system which prevents particulate overcollection during long-term continuous low-load/low-speed driving where it is difficult to achieve self-burning of particulates with a catalytic reaction. This paper describes the development of the particulate trap oxidizer system with these technologies and presents the results of practicability evaluations and 50,000-mile vehicle durability tests.