Technical Paper
Effective Utilization of Pt Catalyst in Three-Way Catalytic System by Employing Calcined Ceria with Alumina
2024-04-09
2024-01-2133
To satisfy the stringent regulations for exhaust gas emissions from gasoline-powered vehicles, large amounts of Rh and Pd have often been employed in three-way catalysts (TWCs) as the main active components. On the other hand, Pt-based TWCs are not often used in gasoline vehicles because Pt is readily sintered by its exhaust gases at approximately 1000 °C [1, 2]. In general, Pt-based TWCs must be located away from large thermal loads to maintain the active sites for gas purification. Based on this background, we previously reported that employing a small amount of CeO2 calcined at 1000 °C (cal-CeO2) in Pt-based TWCs was one of the most effective approaches for improving the catalytic activity without increasing the amount of Rh and Pd [3]. The effect of cal-CeO2 was attributed to the higher redox performance and Pt dispersion derived from the strong interactions between Ce and Pt.