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A study was performed in the spring of 2001 to chemically characterize exhaust emissions from trucks and buses fueled by various test fuels and operated with and without diesel particle filters. This study was part of a multi-year technology validation program designed to evaluate the emissions impact of ultra-low sulfur diesel fuels and passive diesel particle filters (DPF) in several different heavy-duty vehicle fleets operating in Southern California. The overall study of exhaust chemical composition included organic compounds, inorganic ions, individual elements, and particulate matter in various size-cuts. Detailed descriptions of the overall technology validation program and chemical speciation methodology have been provided in previous SAE publications (2002-01-0432 and 2002-01-0433).

A recently completed program was developed to evaluate ultra-low sulfur diesel fuels and passive diesel particle filters (DPF) in several different truck and bus fleets operating in Southern California. The primary test fuels, ECD and ECD-1, are produced by ARCO, a BP company, and have less than 15 ppm sulfur content. A test fleet comprised of heavy-duty trucks and buses were retrofitted with one of two types of catalyzed diesel particle filters, and operated for one year. As part of this program, a chemical characterization study was performed in the spring of 2001 to compare the exhaust emissions using the test fuels with and without aftertreatment. A detailed speciation of volatile organic hydrocarbons (VOC), polycyclic aromatic hydrocarbons (PAH), nitro-PAH, carbonyls, polychlorodibenzo-p-dioxins (PCDD) and polychlorodibenzo-p-furans (PCDF), inorganic ions, elements, PM10, and PM2.5 in diesel exhaust was performed for a select set of vehicles.

Emissions of six 32 passenger transit buses were characterized using one of the West Virginia University (WVU) Transportable Heavy Duty Emissions Testing Laboratories, and the fixed base chassis dynamometer at the Colorado Institute for Fuels and High Altitude Engine Research (CIFER). Three of the buses were powered with 1997 ISB 5.9 liter Cummins diesel engines, and three were powered with the 1997 5.9 liter Cummins natural gas (NG) counterpart. The NG engines were LEV certified. Objectives were to contrast the emissions performance of the diesel and NG units, and to compare results from the two laboratories. Both laboratories found that oxides of nitrogen and particulate matter (PM) emissions were substantially lower for the natural gas buses than for the diesel buses. It was observed that by varying the rapidity of pedal movement during accelerations in the Central Business District cycle (CBD), CO and PM emissions from the diesel buses could be varied by a factor of three or more.