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A study was performed in the spring of 2001 to chemically characterize exhaust emissions from trucks and buses fueled by various test fuels and operated with and without diesel particle filters. This study was part of a multi-year technology validation program designed to evaluate the emissions impact of ultra-low sulfur diesel fuels and passive diesel particle filters (DPF) in several different heavy-duty vehicle fleets operating in Southern California. The overall study of exhaust chemical composition included organic compounds, inorganic ions, individual elements, and particulate matter in various size-cuts. Detailed descriptions of the overall technology validation program and chemical speciation methodology have been provided in previous SAE publications (2002-01-0432 and 2002-01-0433).

Blending of 20% biodiesel with petroleum diesel is well known to cause a significant reduction in PM emissions but also can cause NOx emissions to increase by 1 to 3 percent. This study has examined a number of approaches for NOx reduction for 20% biodiesel/petroleum diesel blends (B20). These approaches included blending with a nominally 10% aromatic diesel, zero aromatic Fisher-Tropsch (FT) diesel, and use of fuel additives. Biodiesel produced from soybean oil and from yellow grease was examined. Testing was conducted in at 1991 DDC Series 60 truck engine using the U.S. heavy-duty FTP. Emissions of NOx, PM, CO, and THC are reported. Relative to certification diesel the B20 fuels exhibited 20% lower PM emissions but 3.3 and 1% higher NOx emissions for soy and yellow grease based blends, respectively. The 10% aromatic fuel exhibited 12% lower PM and 6% lower NOx. FT diesel had the lowest emissions with a 33% reduction in PM and 16% lower NOx.

A recently completed program was developed to evaluate ultra-low sulfur diesel fuels and passive diesel particle filters (DPF) in several different truck and bus fleets operating in Southern California. The primary test fuels, ECD and ECD-1, are produced by ARCO, a BP company, and have less than 15 ppm sulfur content. A test fleet comprised of heavy-duty trucks and buses were retrofitted with one of two types of catalyzed diesel particle filters, and operated for one year. As part of this program, a chemical characterization study was performed in the spring of 2001 to compare the exhaust emissions using the test fuels with and without aftertreatment. A detailed speciation of volatile organic hydrocarbons (VOC), polycyclic aromatic hydrocarbons (PAH), nitro-PAH, carbonyls, polychlorodibenzo-p-dioxins (PCDD) and polychlorodibenzo-p-furans (PCDF), inorganic ions, elements, PM10, and PM2.5 in diesel exhaust was performed for a select set of vehicles.

The Fischer-Tropsch (FT) process can be used to synthesize diesel fuels from a variety of energy sources, including coal, natural gas and biomass. Diesel fuels produced from the FT process are essentially sulfur-free, have very low aromatic content, and have excellent ignition characteristics. Because of these favorable attributes, FT diesel fuels may offer environmental benefits over transportation fuels derived from crude oil. Previous tests have shown that FT diesel fuel can be used in unmodified engines and have been shown to lower regulated emissions. Whereas exhaust emissions reductions from these previous studies have been impressive, this paper demonstrates that far greater exhaust emissions reductions are possible if the diesel engine is optimized to exploit the properties of the FT fuels. A Power Stroke 7.3 liter turbocharged diesel engine has been modified for use with FT diesel.

Emissions from heavy-duty vehicles may be reduced through the introduction of clean diesel formulations, and through the use of catalyzed particulate matter filters that can enjoy increased longevity and performance if ultra-low sulfur diesel is used. Twenty over-the-road tractors with Detroit Diesel Series 60 engines were selected for this study. Five trucks were operated on California (CA) specification diesel (CARB), five were operated on ARCO (now BP Amoco) EC diesel (ECD), five were operated on ARCO ECD with a Johnson-Matthey Continuously Regenerating Technology (CRT) filter and five were operated on ARCO ECD with an Engelhard Diesel Particulate Filter (DPX). The truck emissions were characterized using a transportable chassis dynamometer, full-scale dilution tunnel, research grade gas analyzers and filters for particulate matter (PM) mass collection. Two test schedules, the 5 mile route and the city-suburban (heavy vehicle) route (CSR), were employed.

Alternative compression ignition engine fuels are of interest both to reduce emissions and to reduce U.S. petroleum fuel demand. A Malaysian Fischer-Tropsch gas-to-liquid fuel was compared with California #2 diesel by characterizing emissions from over the road Class 8 tractors with Caterpillar 3176 engines, using a chassis dynamometer and full scale dilution tunnel. The 5-Mile route was employed as the test schedule, with a test weight of 42,000 lb. Levels of oxides of nitrogen (NOx) were reduced by an average of 12% and particulate matter (PM) by 25% for the Fischer-Tropsch fuel over the California diesel fuel. Another distillate fuel produced catalytically from Fischer-Tropsch products originally derived from natural gas by Mossgas was also compared with 49-state #2 diesel by characterizing emissions from Detroit Diesel 6V-92 powered transit buses, three of them equipped with catalytic converters and rebuilt engines, and three without.