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Degradation of the deNOx performance has been found in in-use heavy-duty vehicles with a urea-SCR system in Japan. The causes of the degradation were studied, and two major reasons are suggested here: HC poisoning and deactivation of pre-oxidation catalysts. Hydrocarbons that accumulated on the catalysts inhibited the catalysis. Although they were easily removed by a simple heat treatment, the treatment could only partially recover the original catalytic performance for the deNOx reaction. The unrecovered catalytic activity was found to result from the decrease in conversion of NO to NO2 on the pre-oxidation catalyst. The pre-oxidation catalyst was thus studied in detail by various techniques to reveal the causes of the degradation: Exhaust emission tests for in-use vehicles, effect of heat treatment on the urea-SCR systems, structural changes and chemical changes in active components during the deactivation were systematically investigated.

The emission reduction from diesel engines is one of major issues in heavy duty diesel engines. Super Clean Diesel (SCD) Engine for heavy-duty trucks has also been researched and developed since 2002. The main specifications of the SCD Engine are six cylinders in-line and 10.5 l with a turbo-intercooled and cooled EGR system. The common rail system, of which the maximum injection pressure is 200 MPa, is adopted. The turbocharger is capable of increasing boost pressure up to 501.3 kPa. The EGR system consists of both a high-pressure loop (HP) EGR system and a low-pressure loop (LP) EGR system. The combination of these EGR systems reduces NOx and PM emissions effectively in both steady-state and transient conditions. The emissions of the SCD Engine reach NOx=0.2 g/kWh and PM=0.01 g/kWh with aftertreatment system. The adopted aftertreatment system includes a Lean NOx Trap (LNT) and Diesel Particulate Filter (DPF).

In recent years, attention has focused on smokeless, sulfur-free dimethyl ethyl (DME) as a clean fuel for heavy-duty diesel vehicles [1]. In this development, the DME engine applied for 20-ton GVW truck was developed under the auspices of the Ministry of Land, Infrastructure and Transport of Japan, the first known instance worldwide. With careful design of the fuel system considering DME's unique fuel characteristics and suitable combustion improvement, higher torque was obtained with DME, compared to diesel fueling. and also use of the proper EGR and catalyst, exhaust emissions levels were generally less than one-fourth of new long-term regulation value promulgated in 2005 Japan.

Urea SCR (Selective Catalytic Reduction) system has high potential of reducing NOx. But such as system durability and safety under deteriorated catalysts conditions have not been well enough clarified because it is new technology for vehicles. In this paper, current NOx emission level of an engine equipped with urea SCR system is discussed and then exhaust emission characteristics were analyzed when the SCR catalyst and/or oxidation catalyst lose their functions. When both SCR and oxidation catalyst were de-activated, not only NOx but also PM increased remarkably, which were much more than the engine-out emissions. Oxidation catalyst downstream of SCR catalyst was effective to suppress such deteriorations.

Recently there has been much interest in Dimethyl Ether (DME) as a new fuel for diesel cycle engines. DME combines the advantages of a high cetane number with soot-free combustion, which makes it eminently suitable for compression engines. According to the latest engine test results, however, DME engine energy consumption was inferior to a diesel engine's under a heavy load. DME probably requires strong air-fuel mixing and short fuel injection. Some tests have reported that DME engine performance almost equals a diesel engine's by injecting high rail pressure DME into standard or slightly modified diesel common rail injection equipment. The effect, however, of higher injection pressure on the rates of heat release and spray distribution is unclear. In this study the rail pressure levels examined included 20, 25, 30, and 35 MPa. The results obtained from a single cylinder heavy-duty engine test show that the rate of heat release increases during the premixed combustion phase.

Fuel design for internal combustion engines has been proposed in our study. In this concept, the multicomponent fuel with high and low volatility fuels are used in order to control the spray and combustion processes in internal combustion engine. Therefore, it is necessary to understand the spray and combustion characteristics of the multicomponent fuels in detail. In the present study, the modeling of multicomponent spray vaporization was conducted using KIVA3V code. The physical fuel properties of multicomponent fuel were estimated using the source code of NIST Mixture Property Database. Peng-Robinson equation of state and fugacity calculation were applied to the estimation of liquid-vapor equilibrium in order to take account for non-ideal vaporization process. Two-zone model in which fuel droplet was divided into droplet surface and inner core was introduced in order to simply consider the temperature distribution in fuel droplet.

Nitrous oxide (N2O) is a strong green house effect gas and three-way catalyst is one of the major sources. N2O is mostly emitted at temperatures during the process of light off in the catalyst and the frequency of this temperature range over total temperature range distribution affects strongly on N2O emission. The effect of cold ambient on N2O emission was analyzed based on N2O-catalyst temperature characteristics and catalyst temperature data gained by road driving test at north part of Japan in winter. As results, N2O emission may drastically increase in colder cities and winter city traffic conditions.

In this study, an experimental investigation was conducted using a direct injection single-cylinder diesel engine equipped with a test common rail fuel injection system to clarify how dimethyl ether (DME) injection characteristics affect the heat release and exhaust emissions. For that purpose the common rail fuel injection system (injection pressure: 15 MPa) and injection nozzle (0.55 × 5-holes, 0.70 × 3-holes, same total holes area) have been used for the test. First, to characterize the effect of DME physical properties on the macroscopic spray behavior: injection quantity, injection rate, penetration, cone angle, volume were measured using high-pressure injection chamber (pressure: 4MPa). In order to clarify effects of the injection process on HC, CO, and NOx emissions, as well as the rate of heat release were investigated by single-cylinder engine test. The effects of the injection rate and swirl ratio on exhaust emissions and heat release were also investigated.