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Degradation of the deNOx performance has been found in in-use heavy-duty vehicles with a urea-SCR system in Japan. The causes of the degradation were studied, and two major reasons are suggested here: HC poisoning and deactivation of pre-oxidation catalysts. Hydrocarbons that accumulated on the catalysts inhibited the catalysis. Although they were easily removed by a simple heat treatment, the treatment could only partially recover the original catalytic performance for the deNOx reaction. The unrecovered catalytic activity was found to result from the decrease in conversion of NO to NO2 on the pre-oxidation catalyst. The pre-oxidation catalyst was thus studied in detail by various techniques to reveal the causes of the degradation: Exhaust emission tests for in-use vehicles, effect of heat treatment on the urea-SCR systems, structural changes and chemical changes in active components during the deactivation were systematically investigated.

The use of biofuel is essential for the reduction of greenhouse gas emission. This paper highlights the use of biodiesel as a means of reducing greenhouse gas emission from the diesel engine of heavy-duty vehicles. Biodiesel is fatty acid methyl ester (FAME) obtained through ester exchange reaction by adding methanol to oil, such as rapeseed oil, soybean oil, palm oil, etc. The CO₂ emission from combustion of biodiesel is defined to be equivalent to the CO₂ volume absorbed by its raw materials or plants in their course of growth. On the other hand, however, biodiesel is known to increase the NOx emission when compared with operating with conventional diesel fuel, then suppressing this increase is regarded as a critical issue. This study is intended to identify the fuel properties of biodiesel free from increase in the NOx emission.

Real-time analysis of benzene in automobile exhaust gas was performed using the Jet-REMPI (supersonic jet / resonance enhanced multi-photon ionization) method. Real-time benzene concentration of two diesel trucks and one gasoline vehicle driving in Japanese driving modes were observed under ppm level at 1 s intervals. As a result, it became obvious that there were many differences in their emission tendencies, because of their car types, driving conditions, and catalyst conditions. In two diesel vehicle, benzene emission tendencies were opposite. And, in a gasoline vehicle, emission pattern were different between hot and cold conditions due to the catalyst conditions.

The emission reduction from diesel engines is one of major issues in heavy duty diesel engines. Super Clean Diesel (SCD) Engine for heavy-duty trucks has also been researched and developed since 2002. The main specifications of the SCD Engine are six cylinders in-line and 10.5 l with a turbo-intercooled and cooled EGR system. The common rail system, of which the maximum injection pressure is 200 MPa, is adopted. The turbocharger is capable of increasing boost pressure up to 501.3 kPa. The EGR system consists of both a high-pressure loop (HP) EGR system and a low-pressure loop (LP) EGR system. The combination of these EGR systems reduces NOx and PM emissions effectively in both steady-state and transient conditions. The emissions of the SCD Engine reach NOx=0.2 g/kWh and PM=0.01 g/kWh with aftertreatment system. The adopted aftertreatment system includes a Lean NOx Trap (LNT) and Diesel Particulate Filter (DPF).

The use of biodiesel fuels as an alternative fuel for petroleum diesel fuel is very effective for the reduction of CO2 emission, because biodiesel is produced from renewable biomass resources. Biodiesel is usually blended to conventional diesel fuel in various proportions. It is possible that this biodiesel blending causes the problems on emission characteristics of modern diesel engine, because it could be confirmed that the application of neat biodiesel to modern diesel engines whose control parameters were optimized for conventional diesel fuel deteriorated the emission performances. It is necessary to clarify the effect of biodiesel blending on exhaust emissions of modern diesel engine. Rapeseed oil methyl ester (RME) was selected as a biodiesel used in this study.

The biomass fuel is expected to solve the global warming due to a carbon neutral. A rapeseed oil methyl ester (RME) as biomass fuel was selected, and also a low sulfur diesel fuel is tested as reference fuel in this study. The experiments were carried out to improve diesel emissions and engine performance using high boost and high rate EGR system and a common rail injection system in a single cylinder engine. The diesel emissions and engine performance have been measured under the experimental conditions such as charging boost pressure from atmospheric pressure to 401.3kPa maximum and changing EGR rate from 0% to 40% maximum. RME contain about 10 mass % oxygen in the fuel molecule. Furthermore, RME does not contain aromatic hydrocarbons in the fuel. Due to these chemical properties, RME can be used at 40% high EGR condition.

Application of biodiesel fuel (BDF) to diesel engine is very effective to reduce CO2 emission, because bio-diesel is carbon neutral in principle. However, when biodiesel was applied to conventional diesel engines without modification for biodiesel, NOx emission was increased by the change in fuel characteristics. It is necessary to introduce some strategies into diesel engines fuelled with biodiesel for lower NOx emission than conventional diesel fuel case. The purpose of this study is to reveal that exhaust gas recirculation (EGR) is one of the solutions for the reduction of NOx emission and meeting the future emission regulations when using biodiesel. Neat Rapeseed oil methyl ester (RME) as a biodiesel (B100) was applied to diesel engines equipped with high pressure loop (HPL) EGR system and low pressure loop (LPL) EGR system. Cooled HPL EGR was increased during steady-state operations and JE05 transient mode tests.

Application of biodiesel fuel (BDF) to diesel engine is very effective to reduce CO2 emission, because biodiesel is carbon neutral in principle. However, biodiesels yield an increase in NOx emission from conventional diesel engine, compared with diesel fuel case. Therefore, some strategies are needed for meeting the future emission regulations when using biodiesel. In this study, rapeseed oil methyl ester (RME) was applied to diesel engine equipped with exhaust gas recirculation (EGR) system and NOx storage reduction (NSR) catalyst. NOx reduction rate of NSR catalyst was drastically decreased by using RME, even if injection quantity of RME for rich spike was enhanced. However, an increase in EGR rate could reduce NOx emission without the deterioration in smoke and PM emissions.

A prototype CNG engine for heavy-duty trucks has been developed. The engine had sufficient output in practical use, and the green-house gas emission rate was below that of the base diesel engine. Furthermore, the NOx emission rate was reduced to 0.16 g/kWh in the JE05 mode as results of having fully adjusted air fuel ratio control. The measured emission characteristics of particles from the prototype CNG engine demonstrated that oil consumption was related to the number of particles. Moreover, when oil consumption is at an appropriate level, the accumulation mode particles are significantly reduced, and the nuclei mode particles are fewer than those of diesel-fueled engines.

Autoignition in the homogeneous charge compression ignition (HCCI) process typically exhibits heat release in two stages called cool flame and thermal flame. The mechanisms governing these two stages were investigated using a DME-fueled HCCI engine and numerical simulations. Composition analysis after cool flame showed that the cool flame is explained by a chain reaction mechanism in which the chain terminator is the intermediate species formed in cool flame. In the case of thermal flame, although the chain reaction mechanism is complex, the behavior is clearly described by thermal explosion theory in which the rate-determining reaction is H2O2 decomposition.

The 1997 Kyoto protocol came into effect in February, 2005 to reduce greenhouse gases within the period 2008-2012 by at least 5 % with respect to 1990 levels. Application of biodiesel fuel (BDF) to diesel engine is very effective to reduce CO2 emission, because BDF is carbon neutral in principle. The purpose of this project is to produce a light-duty biodiesel truck which can be suitable for emission regulation in next generation. The effect of BDF on the performance and emissions of modern diesel engine which was equipped with the aftertreatment for PM and NOx emissions was investigated without modifications of engine components and parameters, as a first step for research and development of biodiesel engine. Rapeseed oil methyl ester (RME) was selected in behalf of BDF, and combustion characteristics, engine performance and exhaust emissions were made a comparison between RME and petroleum diesel fuel by steady operation and Japan transient mode (JE05) tests.

Homogeneous Charge Compression Ignition (HCCI) is effective for the simultaneous reduction of soot and NOx emissions in diesel engine. In general, high octane number fuels (gasoline components or gaseous fuels) are used for HCCI operation, because these fuels briefly form lean homogeneous mixture because of long ignition delay and high volatility. However, it is necessary to improve injection systems, when these high octane number fuels are used in diesel engine. In addition, the difficulty of controlling auto-ignition timing must be resolved. On the other hand, HCCI using diesel fuel (diesel HCCI) also needs ignition control, because diesel fuel which has a low octane number causes the early ignition before TDC. The purpose of this study is the ignition and combustion control of diesel HCCI. The effects of parameters (injection timing, injection pressure, internal/external EGR, boost pressure, and variable valve timing (VVT)) on the ignition timing of diesel HCCI were investigated.

Homogeneous Charge Compression Ignition (HCCI) is effective for the simultaneous reduction of soot and NOx emissions from diesel engine. In general, high octane number and volatility fuels (gasoline components or gaseous fuels) are used for HCCI operation, because very lean mixture must be formed during ignition delay of the fuel. However, it is necessary to improve fuel injection systems, when these fuels are used in diesel engine. The purpose of the present study is the achievement of HCCI combustion in DI diesel engine without the large-scale improvements of engine components. Various high octane number fuels are mixed with diesel fuel as a base fuel, and the mixed fuels are directly applied to DI diesel engine. At first, the cylinder pressure and heat release rate of each mixed fuel are analyzed. The ignition delay of HCCI operation decreases with an increase in the operation load, although that of conventional diesel operation does not almost varied.

Particulate Matter (PM) from diesel engines is thought to be seriously hazardous for human health. Generally, it is said that the hazard depends on the total number and surface area of particles rather than total mass of PM. In the conventional gravimetric method, only the total mass of PM is measured. Therefore, it is very important to measure not only the mass of PM but also size and number density of particulates. Laser-Induced Incandescence (LII) is a useful diagnostic for transient measurement of soot particulate volume fraction and primary particle size. On the other hand, Scanning Mobility Particle Sizer (SMPS) is also used to measure the size distribution of soot aggregate particulates at a steady state condition. However, the measurement processes and the phenomena used to acquire the information on soot particulate are quite different between the LII and SMPS methods. Therefore, it is necessary to understand the detailed characteristics of both LII and SMPS.

Flash-boiling occurs when a fuel is injected to a combustion chamber where the ambient pressure is lower than the saturation pressure of the fuel. It has been known that flashing is a favorable mechanism for atomizing liquid fuels. On the other hand, alternative fuels, such as gaseous fuels and oxygenated fuels, are used to achieve low exhaust emissions in recent years. In general, most of these alternative fuels have high volatility and flash-boiling takes place easily in fuel spray, when they are injected into the combustion chamber of an internal combustion engine under high pressure. In addition, fuel design concept the multicomponent fuel with high and low volatility fuels has been proposed in the previous study in order to control the spray and combustion processes in internal combustion engine. It is found that the multicomponent fuel produce flash-boiling with an increase in the initial fuel temperature.

Nitrous oxide (N2O) is a strong green house effect gas and three-way catalyst is one of the major sources. N2O is mostly emitted at temperatures during the process of light off in the catalyst and the frequency of this temperature range over total temperature range distribution affects strongly on N2O emission. The effect of cold ambient on N2O emission was analyzed based on N2O-catalyst temperature characteristics and catalyst temperature data gained by road driving test at north part of Japan in winter. As results, N2O emission may drastically increase in colder cities and winter city traffic conditions.