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Degradation of the deNOx performance has been found in in-use heavy-duty vehicles with a urea-SCR system in Japan. The causes of the degradation were studied, and two major reasons are suggested here: HC poisoning and deactivation of pre-oxidation catalysts. Hydrocarbons that accumulated on the catalysts inhibited the catalysis. Although they were easily removed by a simple heat treatment, the treatment could only partially recover the original catalytic performance for the deNOx reaction. The unrecovered catalytic activity was found to result from the decrease in conversion of NO to NO2 on the pre-oxidation catalyst. The pre-oxidation catalyst was thus studied in detail by various techniques to reveal the causes of the degradation: Exhaust emission tests for in-use vehicles, effect of heat treatment on the urea-SCR systems, structural changes and chemical changes in active components during the deactivation were systematically investigated.

Compared with petroleum fuel, liquefied petroleum gas (LPG) demonstrates advantages in low CO2 emission because of propane and butane, which are the main components of LPG, making H/C ratio higher. In addition, LPG is suitable for high efficient operation of a spark ignition (SI) engine due to its higher research octane number (RON). Because of these advantages, that is, diversity of energy source and reduction of CO2, in the past several years, LPG vehicles have widely used as the alternate to gasoline vehicles all over the world. Consequently, it is absolutely essential for the performance increase of LPG vehicles to comprehend the combustion characteristics of LPG and to obtain the guideline for engine design and calibration. In this study, an LPG-SI engine was built up by converting fuel supply system of an in-line 4-cylinder gasoline engine, which has 1997 cm3 displacement with MPI system, to LPG liquid fuel injection system [1].

Real-time analysis of benzene in automobile exhaust gas was performed using the Jet-REMPI (supersonic jet / resonance enhanced multi-photon ionization) method. Real-time benzene concentration of two diesel trucks and one gasoline vehicle driving in Japanese driving modes were observed under ppm level at 1 s intervals. As a result, it became obvious that there were many differences in their emission tendencies, because of their car types, driving conditions, and catalyst conditions. In two diesel vehicle, benzene emission tendencies were opposite. And, in a gasoline vehicle, emission pattern were different between hot and cold conditions due to the catalyst conditions.

The emission reduction from diesel engines is one of major issues in heavy duty diesel engines. Super Clean Diesel (SCD) Engine for heavy-duty trucks has also been researched and developed since 2002. The main specifications of the SCD Engine are six cylinders in-line and 10.5 l with a turbo-intercooled and cooled EGR system. The common rail system, of which the maximum injection pressure is 200 MPa, is adopted. The turbocharger is capable of increasing boost pressure up to 501.3 kPa. The EGR system consists of both a high-pressure loop (HP) EGR system and a low-pressure loop (LP) EGR system. The combination of these EGR systems reduces NOx and PM emissions effectively in both steady-state and transient conditions. The emissions of the SCD Engine reach NOx=0.2 g/kWh and PM=0.01 g/kWh with aftertreatment system. The adopted aftertreatment system includes a Lean NOx Trap (LNT) and Diesel Particulate Filter (DPF).

Repeatabilities of PM measurements on a heavy-duty diesel engine equipped with a diesel particulate filter (DPF) using a filter weighing method and a number counting method with a full flow dilution system and a partial flow system were evaluated. The filter method with partial flow exhibited the best repeatability. However, a good correlation between the full flow and the partial flow number counting results suggests that the fluctuations observed using the number counting method were caused by changes in the engine exhaust. Applying a strict preconditioning procedure should improve the repeatability of the number counting method because this method is more sensitive than the filter weighing method. In addition, the effects of the specifications for the number counting method were evaluated. The results indicate that the hose length from the tip of the sampling probe to the inlet of the number counting system had a negligible effect.

The formation pathway for poly aromatic hydrocarbons (PAHs) has been studied by not only fundamental chemists but also motor engineers due to the formation of nanoparticle precursors and soot in vehicle emissions. In this study, the formation process of up to triple-ring PAHs was investigated using a flow tube reactor. The gaseous products from the pyrolysis of benzene were analyzed by using GC-MS in the temperature range of 850 - 1277 K and pressure range of 50 - 760 mmHg. We found that PAH products formed at temperatures greater than 1050 K, and the formation process was pressure dependent.

The biomass fuel is expected to solve the global warming due to a carbon neutral. A rapeseed oil methyl ester (RME) as biomass fuel was selected, and also a low sulfur diesel fuel is tested as reference fuel in this study. The experiments were carried out to improve diesel emissions and engine performance using high boost and high rate EGR system and a common rail injection system in a single cylinder engine. The diesel emissions and engine performance have been measured under the experimental conditions such as charging boost pressure from atmospheric pressure to 401.3kPa maximum and changing EGR rate from 0% to 40% maximum. RME contain about 10 mass % oxygen in the fuel molecule. Furthermore, RME does not contain aromatic hydrocarbons in the fuel. Due to these chemical properties, RME can be used at 40% high EGR condition.

Application of biodiesel fuel (BDF) to diesel engine is very effective to reduce CO2 emission, because bio-diesel is carbon neutral in principle. However, when biodiesel was applied to conventional diesel engines without modification for biodiesel, NOx emission was increased by the change in fuel characteristics. It is necessary to introduce some strategies into diesel engines fuelled with biodiesel for lower NOx emission than conventional diesel fuel case. The purpose of this study is to reveal that exhaust gas recirculation (EGR) is one of the solutions for the reduction of NOx emission and meeting the future emission regulations when using biodiesel. Neat Rapeseed oil methyl ester (RME) as a biodiesel (B100) was applied to diesel engines equipped with high pressure loop (HPL) EGR system and low pressure loop (LPL) EGR system. Cooled HPL EGR was increased during steady-state operations and JE05 transient mode tests.

The object of this study is to investigate an on-board diagnostic method to detect the deterioration of a three-way catalyst (TWC) under actual vehicle operating conditions, including the acceleration state. The signal data of two oxygen sensors were processed by the fast Fourier transformation (FFT) method. As a result, we found that the power spectrum of the signal waves can be the index of catalyst deterioration degree. Furthermore, it was confirmed that the difference between the power spectrum of the upstream oxygen sensor signal and one of the downstream oxygen sensor signal named ΔPower is effective index for detection of deteriorated catalyst under acceleration conditions.

Application of biodiesel fuel (BDF) to diesel engine is very effective to reduce CO2 emission, because biodiesel is carbon neutral in principle. However, biodiesels yield an increase in NOx emission from conventional diesel engine, compared with diesel fuel case. Therefore, some strategies are needed for meeting the future emission regulations when using biodiesel. In this study, rapeseed oil methyl ester (RME) was applied to diesel engine equipped with exhaust gas recirculation (EGR) system and NOx storage reduction (NSR) catalyst. NOx reduction rate of NSR catalyst was drastically decreased by using RME, even if injection quantity of RME for rich spike was enhanced. However, an increase in EGR rate could reduce NOx emission without the deterioration in smoke and PM emissions.

A prototype CNG engine for heavy-duty trucks has been developed. The engine had sufficient output in practical use, and the green-house gas emission rate was below that of the base diesel engine. Furthermore, the NOx emission rate was reduced to 0.16 g/kWh in the JE05 mode as results of having fully adjusted air fuel ratio control. The measured emission characteristics of particles from the prototype CNG engine demonstrated that oil consumption was related to the number of particles. Moreover, when oil consumption is at an appropriate level, the accumulation mode particles are significantly reduced, and the nuclei mode particles are fewer than those of diesel-fueled engines.

In recent years, attention has focused on smokeless, sulfur-free dimethyl ethyl (DME) as a clean fuel for heavy-duty diesel vehicles [1]. In this development, the DME engine applied for 20-ton GVW truck was developed under the auspices of the Ministry of Land, Infrastructure and Transport of Japan, the first known instance worldwide. With careful design of the fuel system considering DME's unique fuel characteristics and suitable combustion improvement, higher torque was obtained with DME, compared to diesel fueling. and also use of the proper EGR and catalyst, exhaust emissions levels were generally less than one-fourth of new long-term regulation value promulgated in 2005 Japan.

Urea SCR (Selective Catalytic Reduction) system has high potential of reducing NOx. But such as system durability and safety under deteriorated catalysts conditions have not been well enough clarified because it is new technology for vehicles. In this paper, current NOx emission level of an engine equipped with urea SCR system is discussed and then exhaust emission characteristics were analyzed when the SCR catalyst and/or oxidation catalyst lose their functions. When both SCR and oxidation catalyst were de-activated, not only NOx but also PM increased remarkably, which were much more than the engine-out emissions. Oxidation catalyst downstream of SCR catalyst was effective to suppress such deteriorations.

The prototype solid particle counting system (SPCS) has been used to study solid particle emission from gasoline and diesel vehicles. As recommended by the PMP draft proposal, exhaust is diluted by a Constant Volume Sampler (CVS). The SPCS takes the sample from the CVS tunnel. Transient test cycles such as EPA FTP 75, EPA HWFET (EPA Highway Fuel Economy Cycle), and NEDC (New European Driving Cycle) were tested. The repeatability of the instrument was evaluated on the diesel vehicle for three continuous days. The instrument exhibits good repeatability. The differences for the EPA ftp 75, the EPA HWFET, and the NEDC in three continuous tests are ± 3.5%. The instrument is very sensitive as well and detects the driving differences. A large number of solid particles are found during the hard acceleration from both the gasoline and the diesel vehicles. Solid particle emissions decrease quickly at deceleration and when vehicles approach constant speed.

Homogeneous Charge Compression Ignition (HCCI) is effective for the simultaneous reduction of soot and NOx emissions from diesel engine. In general, high octane number and volatility fuels (gasoline components or gaseous fuels) are used for HCCI operation, because very lean mixture must be formed during ignition delay of the fuel. However, it is necessary to improve fuel injection systems, when these fuels are used in diesel engine. The purpose of the present study is the achievement of HCCI combustion in DI diesel engine without the large-scale improvements of engine components. Various high octane number fuels are mixed with diesel fuel as a base fuel, and the mixed fuels are directly applied to DI diesel engine. At first, the cylinder pressure and heat release rate of each mixed fuel are analyzed. The ignition delay of HCCI operation decreases with an increase in the operation load, although that of conventional diesel operation does not almost varied.

Particulate Matter (PM) from diesel engines is thought to be seriously hazardous for human health. Generally, it is said that the hazard depends on the total number and surface area of particles rather than total mass of PM. In the conventional gravimetric method, only the total mass of PM is measured. Therefore, it is very important to measure not only the mass of PM but also size and number density of particulates. Laser-Induced Incandescence (LII) is a useful diagnostic for transient measurement of soot particulate volume fraction and primary particle size. On the other hand, Scanning Mobility Particle Sizer (SMPS) is also used to measure the size distribution of soot aggregate particulates at a steady state condition. However, the measurement processes and the phenomena used to acquire the information on soot particulate are quite different between the LII and SMPS methods. Therefore, it is necessary to understand the detailed characteristics of both LII and SMPS.

A new PM measurement method, such as particle measurement equipments, samplings and so on, is being studied at present for a type approval test in the future. Particles emitted from diesel engines, especially the particles that are called “Nuclei Mode Particles” are very unstable and easily influenced by the engine operating conditions and the measurement conditions. Most of nuclei mode particles are said to consist of volatile organic particles with mainly high carbon numbers. It is said that a continuous regenerative type DPF (Diesel Particulate Filter) consisting of oxidation catalyst and ceramic filter will prevail in the near future. These particles may be able to be reduced by an oxidation catalyst in this DPF.

The regulation of particulate matter (PM) from diesel engines is coming to be very stringent at present. The usage of diesel particulate filter (DPF) is now under consideration in many heavy-duty diesel vehicle manufacturers to reduce PM emission from a diesel engine. The possibility that very fine particles may pass through DPF is suggested. The understanding of fine particles emission behaviors and the countermeasure of reducing particle emissions from DPF will come to be important in near future. The behavior of particle size distribution after DPF has not been studied enough yet. In this study, fine particles generated by a diesel engine are introduced to honeycomb type and SiC (Silicon Carbite) fiber type DPFs and the collection performances of fine particles by various DPFs with different surface structures have been examined.

Recently, particulate matter (PM) emission from internal combustion engines, especially particles having the diameter of less than 100 nm (Nano-particles) are being considered for their potential hazards posed to human health and the environment. Nano-particles are unstable and easily influenced by the conditions of engine operation and measurement techniques. In this study, the influences of cooling and dilution processes on nano- particles are presented to understand the generation and dilution mechanisms, and to further development of an accurate measurement method. It is found that the thermo-dilurter is necessary for measuring the nano-particles with higher accuracy. Accurate measurement of nano-particles requires immediate dilution of the exhaust gases by hot air.

Nitrous oxide (N2O) is a strong green house effect gas and three-way catalyst is one of the major sources. N2O is mostly emitted at temperatures during the process of light off in the catalyst and the frequency of this temperature range over total temperature range distribution affects strongly on N2O emission. The effect of cold ambient on N2O emission was analyzed based on N2O-catalyst temperature characteristics and catalyst temperature data gained by road driving test at north part of Japan in winter. As results, N2O emission may drastically increase in colder cities and winter city traffic conditions.