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The goal of reducing the impact of road transportation on the environment can be reached by different approaches. The use of non-fossil synthetic fuels from renewable energy sources in the entire fleet of internal combustion engine vehicles is only one promising pathway to minimize the vehicle’s carbon footprint during the use phase. The steadily tightening emissions legislation confront the developers of future combustion engines with major challenges: Historically, the chemical and physical improvement of the combustion process, tail pipe emissions reduction and the development of optimized after-treatment systems were linked to improvements in fuel quality. In order to further decrease exhaust gas emissions, the optimization of the chemical composition of renewable fuels are a basic requirement.

CO2 emission constraints taking effect from 2020 lead to further investigations of technologies to lower knock sensitivity of gasoline engines, main limiting factor to increase engine efficiency and thus reduce fuel consumption. Moreover the RDE cycle demands for higher power operation, where fuel enrichment is needed for component protection. To achieve high efficiency, the engine should be run at stoichiometric conditions in order to have better emission control and reduce fuel consumption. Among others, water injection is a promising technology to improve engine combustion efficiency, by mainly reducing knock sensitivity and to keep high conversion rates of the TWC over the whole engine map. The comprehension of multiple thermodynamic effects of water injection through 3D-CFD simulations and their exploitation to enhance the engine combustion efficiency is the main purpose of the analysis.