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Technical Paper

Development of a Methodology to Separate Thermal from Oil Aging of a Catalyst Using a Gasoline-Fueled Burner System

2003-03-03
2003-01-0663
Typically, an engine/dynamometer thermal aging cycle contains combinations of elevated catalyst inlet temperatures, chemical reaction-induced thermal excursions (simulating misfire events), and average air/fuel ratio's (AFR's) to create a condition that accelerates the aging of the test part. In theory, thermal aging is predominantly a function of the time at an exposure temperature. Therefore, if a burner system can be used to simulate the exhaust AFR and catalyst inlet and bed temperature profile generated by an engine running an accelerated aging cycle, then a catalyst should thermally age the same when exposed to either exhaust stream. This paper describes the results of a study that examined the aging difference between six like catalysts aged using the Rapid Aging Test (RAT) cycle (an accelerated thermal aging cycle). Three catalysts were aged using a gasoline-fueled engine aging stand; the other three were aged using a computer controlled burner system.
Technical Paper

Comparison of Petroleum and Alternate-Source Diesel Fuel Effects on Light-Duty Diesel Emissions

1983-10-31
831712
Exhaust emission data from several fuel effects studies were normalized and subjected to statistical analyses. The goal of this work was to determine whether emission effects of property variation in alternate-source fuels were similar, less pronounced, or more pronounced than the effects of property variation in petroleum fuels. A literature search was conducted, reviewing hundreds of studies and finally selecting nine which dealt with fuel property effects on emissions. From these studies, 15 test cases were reported. Due to the wide variety of vehicles, fuels, test cycles, and measurement techniques used in the studies, a method to relate them all in terms of general trends was developed. Statistics and methods used included bivariate correlation coefficients, regression analysis, scattergrams and goodness-of-fit determinations.
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