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Proton exchange membrane fuel cell (PEMFC) system is considered as one of the most popular power sources because of its high energy density, fast dynamic response and zero pollution. However, the start-up at low temperature (e.g. - 30 °C) is still a major challenge for its wide application due to water freezing in Membrane Electrode Assembly (MEA). In this paper, a cold start test process in an environment cabin with auxiliary heat was carried out for a full power automotive PEMFC system, including normal operation, shutdown purge and cold start processes analysis from -30°C. Rated power of this stack is 100kW at the current density of 1.4A/cm2 and relevant maximum output power can reach to 120kW. In order to reduce the damage of high potential to MEA, on-load purge with a current of 30A is conducted to removing extra water in stack for improving cold start ability. Based on corresponding control strategy, cold start was realized successfully within 110s.

Water and thermal management is an essential issue that influences performance and durability of a polymer electrolyte membrane fuel cell (PEMFC). Water content in membrane decides its ionic conductivity and membrane swelling favors the ionic conductivity, resulting in decreases in the membrane’s ohmic resistance and improvement in the output voltage. However, if excessive liquid water can’t be removed out of cell quickly, it will fill in the pores of catalyst layer (CL) and gas diffusion layer (GDL) then flooding may occur. It is essential to keep the water content in membrane at a proper level. In this work, a transient isothermal one-dimensional model is developed to investigate effects of the relative humidity of inlet gas and cell temperature on performance of a PEMFC.

Centrifugal compressors used in polymer electrolyte membrane fuel cell systems are different from turbochargers in internal combustion engines, because they are required to work at high speed, low mass flow rate, narrow range which nears surge boundaries. In order to meet these requirements, a centrifugal compressor’s volute is designed, analyzed and optimized on its cross-section area, shape of volute tongue and tapered angle of exit. The numerical results show that surge boundary of the compressor is influenced by spiral area significantly and that volute tongue has a major impact on aerodynamic performances at high mass flow rates.

Startup from subzero temperature is one of the major challenges for polymer electrolyte membrane fuel cell (PEMFC) to realize commercialization. Below the freezing point (0°C), water will freeze easily, which blocks the reactant gases into the reaction sites, thus leading to the start failure and material degradation. Therefore, for PEMFC in vehicle application, finding suitable ways to reach successful startup from subfreezing environment is a prerequisite. As it’s difficult and complex for experimental studies to measure the internal quantities, mathematical models are the effective ways to study the detailed transport process and physical phenomenon, which make it possible to achieve detailed prediction of the inner life of the cell. However, review papers only on cold start numerical models are not available. In this study, an extensive review on cold start models is summarized featuring the states and phase changes of water, heat and mass transfer.

A passive thermal management system (TMS) using composite phase change material (PCM) for large-capacity, rectangular lithium-ion batteries is designed. A battery module consisting of six Li-ion cells connected in series was investigated as a basic unit. The passive TMS for the module has three configurations according to the contact area between cells and the composite PCM, i.e., surrounding, front-contacted and side-contacted schemes. Firstly, heat generation rate of the battery cell was calculated using the Bernardi equation based on experimentally measured heat source terms (i.e. the internal resistance and the entropy coefficient). Physical and thermal properties such as density, phase change temperature, latent heat and thermal conductivity of the composite PCM were also obtained by experimental methods. Thereafter, thermal response of the battery modules with the three TMS configurations was simulated using 3D finite element analysis (FEA) modeling in ANSYS Fluent.