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Technical Paper

Three-Way Catalytic Reaction in an Electric Field for Exhaust Emission Control Application

2021-04-06
2021-01-0573
To prevent global warming, further reductions in carbon dioxide are required. It is therefore important to promote the spread of electric vehicles powered by internal combustion engines and electric vehicles without internal combustion engines. As a result, emissions from hybrid electric vehicles equipped with internal combustion engines should be further reduced. Interest in catalytic reactions in an electric field with a higher catalytic activity compared to conventional catalysts has increased because this technology consumes less energy than other electrical heating devices. This study was therefore undertaken to apply a catalytic reaction in an electric field to an exhaust emission control. First, the original experimental equipment was built with a high voltage system used to conduct catalytic activity tests.
Technical Paper

Study of Simple Detection of Gasoline Fuel Contaminants Contributing to Increase Particulate Matter Emissions

2020-04-14
2020-01-0384
The reduction of particulate emissions is one of the most important challenges facing the development of future gasoline engines. Several studies have demonstrated the impact of fuel chemical composition on the emissions of particulate matter, more particularly, the detrimental effect of high boiling point components such as heavy aromatics. Fuel contamination is likely to become a critical issue as new regulations such as Real Driving Emissions RDE involves the use of market fuel. The objective of this study is to investigate several experimental approaches to detect the presence of Diesel contamination in Gasoline which is likely to alter pollutant emissions. To achieve this, a fuel matrix composed of 12 fuels was built presenting diesel fuel in varying concentrations from 0.1 to 2% v/v. The fuel matrix was characterized using several original techniques developed in this study.
Technical Paper

Effect of High RON Fuels on Engine Thermal Efficiency and Greenhouse Gas Emissions

2019-04-02
2019-01-0629
Historically, greenhouse gas (GHG) emissions standards for vehicles have focused on tailpipe emissions. However, sound environmental policy requires a more holistic well-to-wheels (WTW) assessment that includes both production of the fuel and its use in the vehicle. The present research explores the net change in WTW GHG emissions associated with moving from regular octane (RO) to high octane (HO) gasoline. It considers both potential increases in refinery emissions from producing HO fuel and potential reductions in vehicle emissions through the use of fuel-efficient engines optimized for such fuel. Three refinery configurations of varying complexity and reforming capacity were studied. A set of simulations covering different levels of HO gasoline production were run for each refinery configuration.
Technical Paper

Development of High Accuracy NOx Sensor

2019-04-02
2019-01-0749
This paper presents an improvement in the accuracy of NOx sensors at high NOx concentration regions by optimizing the manufacturing process, sensor electrode materials and structure, in order to suppress the deterioration mechanism of sensor electrodes. Though NOx sensors generally consist of Pt/Au alloy based oxygen pump electrodes and Pt/Rh alloy based sensor electrodes, detailed experimental analysis of aged NOx sensors showed changes in the surface composition and morphology of the sensor electrode. The surface of the sensor electrode was covered with Au, which is not originally contained in the electrode, resulting in a diminished active site for NOx detection on the sensor electrode and a decrease in sensor output. Theoretical analysis using CAE with molecular dynamics supported that Au tends to be concentrated on the surface of the sensor electrode.
Technical Paper

Application of Models of Short Circuits and Blow-Outs of Spark Channels under High-Velocity Flow Conditions to Spark Ignition Simulation

2018-09-10
2018-01-1727
This report describes the implementation of the spark channel short circuit and blow-out submodels, which were described in the previous report, into a spark ignition model. The spark channel which is modeled by a particle series is elongated by moving individual spark particles along local gas flows. The equation of the spark channel resistance developed by Kim et al. is modified in order to describe the behavior of the current and the voltage in high flow velocity conditions and implemented into the electrical circuit model of the electrical inductive system of the spark plug. Input parameters of the circuit model are the following: initial discharge energy, inductance, internal resistance and capacitance of the spark plug, and the spark channel length obtained by the spark channel model. The instantaneous discharge current and the voltage are obtained as outputs of the circuit model.
Technical Paper

Critical Analysis of PM Index and Other Fuel Indices: Impact of Gasoline Fuel Volatility and Chemical Composition

2018-09-10
2018-01-1741
Among the challenges for the future facing the development of gasoline engines, one of the most important is the reduction of particles emissions. This study proposes a critical and objective evaluation of the influence of fuel characteristics on gasoline particles emission through the use of Fuel Particle Indices. For this, a selected fuel matrix composed of 22 fuels was built presenting different volatility and chemical composition (content in total aromatics, heavy cuts and ethanol). To represent the fuel sooting tendency, seven Fuel Particle Indices were selected based on a literature review, namely, Particulate Matter Index (PMI), Particulate Number index (PNI), Threshold Sooting index (TSI), Smoke point (SP), Oxygen Extended Sooting Index (OESI), Simplified index 1 and 2 (sPMI 1, sPMI 2). These indices were computed on the fuel matrix and compared on the basis of three main axes. First, the sensitivity to fuel variation.
Technical Paper

Effects of EGR Constituents and Fuel Composition on DISI Engine Knock: An Experimental and Modeling Study

2018-09-10
2018-01-1677
The use of exhaust gas recirculation (EGR) in spark ignition engines has been shown to have a number of beneficial effects under specific operating conditions. These include reducing pumping work under part load conditions, reducing NOx emissions and heat losses by lowering peak combustion temperatures, and by reducing the tendency for engine knock (caused by end-gas autoignition) under certain operating regimes. In this study, the effects of EGR addition on knocking combustion are investigated through a combined experimental and modeling approach. The problem is investigated by considering the effects of individual EGR constituents, such as CO2, N2, and H2O, on knock, both individually and combined, and with and without traces species, such as unburned hydrocarbons and NOx. The effects of engine compression ratio and fuel composition on the effectiveness of knock suppression with EGR addition were also investigated.
Journal Article

Effects of High Boiling Point Fuel Additives on Deposits in a Direct Injection Gasoline Engine

2017-10-08
2017-01-2299
The effects of high boiling point fuel additives on deposits were investigated in a commercial turbocharged direct injection gasoline engine. It is known that high boiling point substances have a negative effect on deposits. The distillation end points of blended fuels containing these additives may be approximately 15°C higher than the base fuel (end point: 175°C). Three additives with boiling points between 190 and 196°C were examined: 4-tert-Butyltoluene (TBT), N-Methyl Aniline (NMA), and 2-Methyl-1,5-pentanediamine (MPD). Aromatics and anilines, which may be added to gasoline to increase its octane number, might have a negative effect on deposits. TBT has a benzene ring. NMA has a benzene ring and an amino group. MPD, which has no benzene ring and two amino groups, was selected for comparison with the former two additives.
Journal Article

An Intake Valve Deposit (IVD) Engine Test Development to Investigate Deposit Build-Up Mechanism Using a Real Engine

2017-10-08
2017-01-2291
In emerging markets, Port Fuel Injection (PFI) technology retains a higher market share than Gasoline Direct Injection (GDI) technology. In these markets fuel quality remains a concern even despite an overall improvement in quality. Typical PFI engines are sensitive to fuel quality regardless of brand, engine architecture, or cylinder configuration. One of the well-known impacts of fuel quality on PFI engines is the formation of Intake Valve Deposits (IVD). These deposits steadily accumulate over time and can lead to a deterioration of engine performance. IVD formation mechanisms have been characterized in previous studies. However, no test is available on a state-of-the-art engine to study the impact of fuel components on IVD formation. Therefore, a proprietary engine test was developed to test several chemistries. Sixteen fuel blends were tested. The deposit formation mechanism has been studied and analysed.
Technical Paper

The New Toyota Inline 4-Cylinder 2.5L Gasoline Engine

2017-03-28
2017-01-1021
In order to adapt to energy security and the changes of global-scale environment, further improvement of fuel economy and adaptation to each country’s severer exhaust gas emission regulation are required in an automotive engine. To achieve higher power performance with lower fuel consumption, the engine’s basic internal design such as an engine block and cylinder head were changed and the combustion speed was dramatically increased. Consequently, stroke-bore ratio and valve layout were optimized. Also, both flow coefficient and intake tumble ratio port were improved by adopting a laser cladded valve seat. In addition, several new technologies were adopted. The Atkinson cycle using a new Electrical VVT (Variable Valve Timing) and new combustion technology adopting new multi-hole type Direct fuel Injector (DI) improved engine power and fuel economy and reduced exhaust emissions.
Technical Paper

Development of High Accuracy Rear A/F Sensor

2017-03-28
2017-01-0949
New 2A/F systems different from usual A/F-O2 systems are being developed to cope with strict regulation of exhaust gas. In the 2A/F systems, 2A/F sensors are equipped in front and rear of a three-way catalyst. The A/F-O2 systems are ideas which use a rear O2 to detect exhaust gas leaked from three-way catalyst early and feed back. On the other hand, the 2A/F systems are ideas which use a rear A/F sensor to detect nearly stoichiometric gas discharged from the three-way catalyst accurately, and to prevent leakage of exhaust gas from the three-way catalyst. Therefore, accurate detection of nearly stoichiometric gas by the rear A/F sensor is the most importrant for the 2A/F systems. In general, the A/F sensors can be classified into two types, so called, one-cell type and two-cell type. Because the one-cell type A/F sensors don’t have hysteresis, they have potential for higher accuracy.
Journal Article

Development of Ignition Technology for Dilute Combustion Engines

2017-03-28
2017-01-0676
In recent years, from a viewpoint of global warming and energy issues, the need to improve vehicle fuel economy to reduce CO2 emission has become apparent. One of the ways to improve this is to enhance engine thermal efficiency, and for that, automakers have been developing the technologies of high compression ratio and dilute combustion such as exhaust gas recirculation (EGR), and lean combustion. Since excessive dilute combustion causes the failure of flame propagation, combustion promotion by intensifying in-cylinder turbulence has been indispensable. However, instability of flame kernel formation by gas flow fluctuation between combustion cycles is becoming an issue. Therefore, achieving stable flame kernel formation and propagation under a high dilute condition is important technology.
Journal Article

Friction Coefficient Variation Mechanism under Wet Condition in Disk Brake (Variation Mechanism Contributing Wet Wear Debris)

2016-09-18
2016-01-1943
This paper deals with friction under wet condition in the disk brake system of automobiles. In our previous study, the variation of friction coefficient μ was observed under wet condition. And it was experimentally found that μ becomes high when wear debris contains little moisture. Based on the result, in this paper, we propose a hypothesis that agglomerates composed of the wet wear debris induce the μ variation as the agglomerates are jammed in the gaps between the friction surfaces of a brake pad and a disk rotor. For supporting the hypothesis, firstly, we measure the friction property of the wet wear debris, and confirm that the capillary force under the pendular state is a factor contributing to the μ variation. After that, we simulate the wear debris behavior with or without the capillary force using the particle-based simulation. We prepare the simulation model for the friction surfaces which contribute to the friction force through the wear debris.
Technical Paper

Engine Oil Formulation Technology to Prevent Pre-ignition in Turbocharged Direct Injection Spark Ignition Engines

2015-09-01
2015-01-2027
Engine oil formulation is known to affect low speed pre-ignition (LSPI), which creates technical restrictions on downsized turbocharged engines. Calcium, which is used to ensure detergency and anti-rust performance, is reported to increase LSPI events. Therefore, new formulation technologies are needed to satisfy both LSPI prevention performance and other conventional performance areas. The authors focused on two approaches: enhancement of LSPI prevention performance by adding a booster component and substitution of calcium for a less reactive component to balance performance areas including LSPI prevention. We have verified the effectiveness of these approaches by increasing the dosage of molybdenum used as a friction modifier as well as replacing calcium detergent with a magnesium detergent. These formulation strategies can be applicable for future ILSAC GF-6 engine oil, where a specification for LSPI prevention performance is expected to be implemented.
Technical Paper

Mechanism of Turbocharger Coking in Gasoline Engines

2015-09-01
2015-01-2029
Turbocharged downsized gasoline engines have been widely used in the market as one of the measures to improve fuel economy. Coking phenomena in the lubricating circuit of the turbocharger unit is a well-known issue that may affect turbocharger efficiency and durability. Laboratory rig test such as ASTM D6335 (TEOST 33C) has been used to predict this phenomenon as a part of engine oil performance requirements. On the other hand, laboratory tests sometimes have difficulty reproducing the actual mechanism of coking caused by engine oil degradation. Accumulation of insoluble material is one of the important gasoline engine oil degradation modes. The influence of temperature and insoluble concentration were investigated based on actual used engine oils collected in the field.
Technical Paper

Development of Advanced Three-Way Catalyst with Improved NOx Conversion

2015-04-14
2015-01-1005
Countries and regions around the world are tightening emissions regulations in reaction to the increasing awareness of environmental conservation. At the same time, growing concerns about the depletion of raw materials as vehicle ownership continues to increase is prompting automakers to look for ways of decreasing the use of platinum-group metals (PGMs) in the exhaust systems. This research has developed a new catalyst with strong robustness against fluctuations in the exhaust gas and excellent nitrogen oxide (NOx) conversion performance. This catalyst incorporates rhodium (Rh) clusters with a particle size of several nanometers, and stabilized CeO2-ZrO2 solid-solution (CZ) with a pyrochlore crystal structure as a high-volume oxygen storage capacity (OSC) material with a slow O2 storage rate.
Technical Paper

Combustion Development to Achieve Engine Thermal Efficiency of 40% for Hybrid Vehicles

2015-04-14
2015-01-1254
In recent years, enhancing engine thermal efficiency is strongly required. Since the maximum engine thermal efficiency is especially important for HVs, the technologies for improving engine thermal efficiency have been developed. The current gasoline engines for hybrid vehicles have Atkinson cycle with high expansion ratio and cooled exhaust gas recirculation (EGR) system. These technologies contribute to raise the brake engine thermal efficiency to more than 38%.In the near future the consumers demand will push the limit to 40% thermal efficiency. To enhance engine thermal efficiency, it is essential to improve the engine anti-knock quality and to decrease the engine cooling heat loss. To comply with improving the anti-knock quality and decreasing the cooling heat loss, it is known that the cooled EGR is an effective way.
Journal Article

Pre-Ignition of Gasoline-Air Mixture Triggered by a Lubricant Oil Droplet

2014-10-13
2014-01-2627
This paper presents the effects of a lubricant oil droplet on the start of combustion of a fuel-air mixture. Lubricant oil is thought to be a major source of low-speed pre-ignition in highly boosted spark ignition engines. However, the phenomenon has not yet been fully understood because its unpredictability and the complexity of the mixture in the engine cylinder make analysis difficult. In this study, a single oil droplet in a combustion cylinder was considered as a means of simplifying the phenomenon. The conditions under which a single oil droplet ignites earlier than the fuel-air mixture were investigated. Tests were conducted by using a rapid compression expansion machine. A single oil droplet was introduced into the cylinder through an injector developed for this study. The ignition and the flame propagation were observed through an optical window, using a high-speed video camera.
Journal Article

Engine Oil Development for Preventing Pre-Ignition in Turbocharged Gasoline Engine

2014-10-13
2014-01-2785
Gasoline engine downsizing combined with a turbocharger is one of the more effective approaches to improve fuel efficiency without sacrificing power performance. The benefit comes from lower pumping loss, lower mechanical friction due to ‘downsizing’ of the engine displacement and ‘down-speeding’ of the engine by using higher transmission gear ratios which is allowed by the higher engine torque at lower engine speeds. However abnormal combustion referred to as Low-Speed Pre-ignition (LSPI) is known to be able to occur in low-speed and high-torque conditions. It is a potential restriction to maximize the engine performance and its benefit, therefore prevention of LSPI is strongly desired for long-term durability of engine performance. According to recent technical reports, auto-ignition of an engine oil droplet in a combustion chamber is believed to be one of major contributing factors of LSPI and its formulations have a significant effect on LSPI frequency.
Technical Paper

Development of NSR and DiAir System to Achieve Clean Emissions under Transient Cycle

2014-10-13
2014-01-2809
In this paper, a control strategy to switch NSR (NOx storage and reduction) function from standard DeNOx by rich combustion to DiAir (Diesel NOx After-treatment by Adsorbed Intermediate Reductants) and additional advantages to use HCI (Hydrocarbon Injector) during desulfation were introduced. Investigations under a transient cycle suggest that NOx conversion with DiAir is strongly affected by preliminary NOx storage condition in the NSR catalyst. To avoid NOx breakthrough just after starting HC dosing for DiAir, a rich operation to reduce stored NOx was shown to be important and high NOx conversion could be maintained using this control strategy under a transient cycle. Furthermore, by combining HCI and in-cylinder post injection, usage of rich condition for NSR DeSOx can be expand to wider engine speed and load area.
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