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Technical Paper

Three-Way Catalytic Reaction in an Electric Field for Exhaust Emission Control Application

2021-04-06
2021-01-0573
To prevent global warming, further reductions in carbon dioxide are required. It is therefore important to promote the spread of electric vehicles powered by internal combustion engines and electric vehicles without internal combustion engines. As a result, emissions from hybrid electric vehicles equipped with internal combustion engines should be further reduced. Interest in catalytic reactions in an electric field with a higher catalytic activity compared to conventional catalysts has increased because this technology consumes less energy than other electrical heating devices. This study was therefore undertaken to apply a catalytic reaction in an electric field to an exhaust emission control. First, the original experimental equipment was built with a high voltage system used to conduct catalytic activity tests.
Technical Paper

Effect of High RON Fuels on Engine Thermal Efficiency and Greenhouse Gas Emissions

2019-04-02
2019-01-0629
Historically, greenhouse gas (GHG) emissions standards for vehicles have focused on tailpipe emissions. However, sound environmental policy requires a more holistic well-to-wheels (WTW) assessment that includes both production of the fuel and its use in the vehicle. The present research explores the net change in WTW GHG emissions associated with moving from regular octane (RO) to high octane (HO) gasoline. It considers both potential increases in refinery emissions from producing HO fuel and potential reductions in vehicle emissions through the use of fuel-efficient engines optimized for such fuel. Three refinery configurations of varying complexity and reforming capacity were studied. A set of simulations covering different levels of HO gasoline production were run for each refinery configuration.
Technical Paper

Application of Models of Short Circuits and Blow-Outs of Spark Channels under High-Velocity Flow Conditions to Spark Ignition Simulation

2018-09-10
2018-01-1727
This report describes the implementation of the spark channel short circuit and blow-out submodels, which were described in the previous report, into a spark ignition model. The spark channel which is modeled by a particle series is elongated by moving individual spark particles along local gas flows. The equation of the spark channel resistance developed by Kim et al. is modified in order to describe the behavior of the current and the voltage in high flow velocity conditions and implemented into the electrical circuit model of the electrical inductive system of the spark plug. Input parameters of the circuit model are the following: initial discharge energy, inductance, internal resistance and capacitance of the spark plug, and the spark channel length obtained by the spark channel model. The instantaneous discharge current and the voltage are obtained as outputs of the circuit model.
Technical Paper

Critical Analysis of PM Index and Other Fuel Indices: Impact of Gasoline Fuel Volatility and Chemical Composition

2018-09-10
2018-01-1741
Among the challenges for the future facing the development of gasoline engines, one of the most important is the reduction of particles emissions. This study proposes a critical and objective evaluation of the influence of fuel characteristics on gasoline particles emission through the use of Fuel Particle Indices. For this, a selected fuel matrix composed of 22 fuels was built presenting different volatility and chemical composition (content in total aromatics, heavy cuts and ethanol). To represent the fuel sooting tendency, seven Fuel Particle Indices were selected based on a literature review, namely, Particulate Matter Index (PMI), Particulate Number index (PNI), Threshold Sooting index (TSI), Smoke point (SP), Oxygen Extended Sooting Index (OESI), Simplified index 1 and 2 (sPMI 1, sPMI 2). These indices were computed on the fuel matrix and compared on the basis of three main axes. First, the sensitivity to fuel variation.
Technical Paper

Effects of EGR Constituents and Fuel Composition on DISI Engine Knock: An Experimental and Modeling Study

2018-09-10
2018-01-1677
The use of exhaust gas recirculation (EGR) in spark ignition engines has been shown to have a number of beneficial effects under specific operating conditions. These include reducing pumping work under part load conditions, reducing NOx emissions and heat losses by lowering peak combustion temperatures, and by reducing the tendency for engine knock (caused by end-gas autoignition) under certain operating regimes. In this study, the effects of EGR addition on knocking combustion are investigated through a combined experimental and modeling approach. The problem is investigated by considering the effects of individual EGR constituents, such as CO2, N2, and H2O, on knock, both individually and combined, and with and without traces species, such as unburned hydrocarbons and NOx. The effects of engine compression ratio and fuel composition on the effectiveness of knock suppression with EGR addition were also investigated.
Journal Article

Effects of High Boiling Point Fuel Additives on Deposits in a Direct Injection Gasoline Engine

2017-10-08
2017-01-2299
The effects of high boiling point fuel additives on deposits were investigated in a commercial turbocharged direct injection gasoline engine. It is known that high boiling point substances have a negative effect on deposits. The distillation end points of blended fuels containing these additives may be approximately 15°C higher than the base fuel (end point: 175°C). Three additives with boiling points between 190 and 196°C were examined: 4-tert-Butyltoluene (TBT), N-Methyl Aniline (NMA), and 2-Methyl-1,5-pentanediamine (MPD). Aromatics and anilines, which may be added to gasoline to increase its octane number, might have a negative effect on deposits. TBT has a benzene ring. NMA has a benzene ring and an amino group. MPD, which has no benzene ring and two amino groups, was selected for comparison with the former two additives.
Technical Paper

The New Toyota Inline 4-Cylinder 2.5L Gasoline Engine

2017-03-28
2017-01-1021
In order to adapt to energy security and the changes of global-scale environment, further improvement of fuel economy and adaptation to each country’s severer exhaust gas emission regulation are required in an automotive engine. To achieve higher power performance with lower fuel consumption, the engine’s basic internal design such as an engine block and cylinder head were changed and the combustion speed was dramatically increased. Consequently, stroke-bore ratio and valve layout were optimized. Also, both flow coefficient and intake tumble ratio port were improved by adopting a laser cladded valve seat. In addition, several new technologies were adopted. The Atkinson cycle using a new Electrical VVT (Variable Valve Timing) and new combustion technology adopting new multi-hole type Direct fuel Injector (DI) improved engine power and fuel economy and reduced exhaust emissions.
Technical Paper

Development of High Accuracy Rear A/F Sensor

2017-03-28
2017-01-0949
New 2A/F systems different from usual A/F-O2 systems are being developed to cope with strict regulation of exhaust gas. In the 2A/F systems, 2A/F sensors are equipped in front and rear of a three-way catalyst. The A/F-O2 systems are ideas which use a rear O2 to detect exhaust gas leaked from three-way catalyst early and feed back. On the other hand, the 2A/F systems are ideas which use a rear A/F sensor to detect nearly stoichiometric gas discharged from the three-way catalyst accurately, and to prevent leakage of exhaust gas from the three-way catalyst. Therefore, accurate detection of nearly stoichiometric gas by the rear A/F sensor is the most importrant for the 2A/F systems. In general, the A/F sensors can be classified into two types, so called, one-cell type and two-cell type. Because the one-cell type A/F sensors don’t have hysteresis, they have potential for higher accuracy.
Journal Article

Development of Ignition Technology for Dilute Combustion Engines

2017-03-28
2017-01-0676
In recent years, from a viewpoint of global warming and energy issues, the need to improve vehicle fuel economy to reduce CO2 emission has become apparent. One of the ways to improve this is to enhance engine thermal efficiency, and for that, automakers have been developing the technologies of high compression ratio and dilute combustion such as exhaust gas recirculation (EGR), and lean combustion. Since excessive dilute combustion causes the failure of flame propagation, combustion promotion by intensifying in-cylinder turbulence has been indispensable. However, instability of flame kernel formation by gas flow fluctuation between combustion cycles is becoming an issue. Therefore, achieving stable flame kernel formation and propagation under a high dilute condition is important technology.
Journal Article

Friction Coefficient Variation Mechanism under Wet Condition in Disk Brake (Variation Mechanism Contributing Wet Wear Debris)

2016-09-18
2016-01-1943
This paper deals with friction under wet condition in the disk brake system of automobiles. In our previous study, the variation of friction coefficient μ was observed under wet condition. And it was experimentally found that μ becomes high when wear debris contains little moisture. Based on the result, in this paper, we propose a hypothesis that agglomerates composed of the wet wear debris induce the μ variation as the agglomerates are jammed in the gaps between the friction surfaces of a brake pad and a disk rotor. For supporting the hypothesis, firstly, we measure the friction property of the wet wear debris, and confirm that the capillary force under the pendular state is a factor contributing to the μ variation. After that, we simulate the wear debris behavior with or without the capillary force using the particle-based simulation. We prepare the simulation model for the friction surfaces which contribute to the friction force through the wear debris.
Technical Paper

Development of Advanced Three-Way Catalyst with Improved NOx Conversion

2015-04-14
2015-01-1005
Countries and regions around the world are tightening emissions regulations in reaction to the increasing awareness of environmental conservation. At the same time, growing concerns about the depletion of raw materials as vehicle ownership continues to increase is prompting automakers to look for ways of decreasing the use of platinum-group metals (PGMs) in the exhaust systems. This research has developed a new catalyst with strong robustness against fluctuations in the exhaust gas and excellent nitrogen oxide (NOx) conversion performance. This catalyst incorporates rhodium (Rh) clusters with a particle size of several nanometers, and stabilized CeO2-ZrO2 solid-solution (CZ) with a pyrochlore crystal structure as a high-volume oxygen storage capacity (OSC) material with a slow O2 storage rate.
Technical Paper

Combustion Development to Achieve Engine Thermal Efficiency of 40% for Hybrid Vehicles

2015-04-14
2015-01-1254
In recent years, enhancing engine thermal efficiency is strongly required. Since the maximum engine thermal efficiency is especially important for HVs, the technologies for improving engine thermal efficiency have been developed. The current gasoline engines for hybrid vehicles have Atkinson cycle with high expansion ratio and cooled exhaust gas recirculation (EGR) system. These technologies contribute to raise the brake engine thermal efficiency to more than 38%.In the near future the consumers demand will push the limit to 40% thermal efficiency. To enhance engine thermal efficiency, it is essential to improve the engine anti-knock quality and to decrease the engine cooling heat loss. To comply with improving the anti-knock quality and decreasing the cooling heat loss, it is known that the cooled EGR is an effective way.
Journal Article

Experimental Study of the Impact of Diesel/Biodiesel Blends Oxidation on the Fuel Injection System

2014-10-13
2014-01-2767
The stability of Diesel/Biodiesel blends can play an important role in deposits formation inside the fuel injection system (FIS). The impact of the stability of FAME/Diesel fuel blends on lacquer deposits formation and on the behavior and reliability of the FIS was investigated using blends of Rapeseed and Soybean methyl esters (RME, SME) and conventional Diesel fuel (volume fractions of RME and SME range from 0 to 20%v/v). Fuels were aged under accelerated conditions and tested on an injection test rig according to an operating cycle developed to provoke injector needle blocking. The soaking duration was found to affect injector fouling. A relationship between the injector fouling tendency and the fuel stability was established. Under current test condition, injectors fouling increased with fuel oxidation measured with Total-Acid-Number.
Journal Article

Engine Oil Development for Preventing Pre-Ignition in Turbocharged Gasoline Engine

2014-10-13
2014-01-2785
Gasoline engine downsizing combined with a turbocharger is one of the more effective approaches to improve fuel efficiency without sacrificing power performance. The benefit comes from lower pumping loss, lower mechanical friction due to ‘downsizing’ of the engine displacement and ‘down-speeding’ of the engine by using higher transmission gear ratios which is allowed by the higher engine torque at lower engine speeds. However abnormal combustion referred to as Low-Speed Pre-ignition (LSPI) is known to be able to occur in low-speed and high-torque conditions. It is a potential restriction to maximize the engine performance and its benefit, therefore prevention of LSPI is strongly desired for long-term durability of engine performance. According to recent technical reports, auto-ignition of an engine oil droplet in a combustion chamber is believed to be one of major contributing factors of LSPI and its formulations have a significant effect on LSPI frequency.
Technical Paper

Numerical Modeling of the Contamination of Engine Oil by Fuel Combustion Byproducts

2014-10-13
2014-01-2574
This paper focuses on the fuel contribution to crankcase engine oil degradation in gasoline fueled engines in view of insoluble formation. The polymerization of degraded fuel is responsible for the formation of insoluble which is considered as a possible cause of low temperature sludge in severe vehicle operating conditions. The main objective of the study is to understand the mechanism of formation of partially oxidized compounds from fuel during the combustion process, before their accumulation in the crankcase oil. A numerical method has been established to calculate the formation of partially oxidized compounds in spark ignition engines directly, by using 3D CFD. To further enable the possibility of running a large number of simulations with a realistic turn-around time, a coupled approach of 3D CFD (with simplified chemical mechanism) and 0D Kinetics (with full chemical mechanism) is proposed here.
Journal Article

Thermal Analysis of the Exhaust Line Focused on the Cool-Down Process

2014-04-01
2014-01-0655
At the engine restart, when the temperature of the catalytic converter is low, additional fuel consumption would be required to warm up the catalyst for controlling exhaust emission.The aim of this study is to find a thermally optimal way to reduce fuel consumption for the catalyst warm up at the engine restart, by improving the thermal retention of the catalytic converter in the cool down process after the previous trip. To make analysis of the thermal flow around the catalytic converter, a 2-D thermal flow model was constructed using the thermal network method. This model simulates the following processes: 1) heat conduction between the substrate and the stainless steel case, 2) heat convection between the stainless steel case and the ambient air, 3) heat convection between the substrate and the gas inside the substrate, 4) heat generation due to chemical reactions.
Journal Article

New Combustion Concept for Turbocharged Gasoline Direct-Injection Engines

2014-04-01
2014-01-1210
The advantages of gasoline direct-injection are intake air cooling due to fuel vaporization which reduces knocking, additional degrees of freedom in designing a stratified injection mixture, and capability for retarded ignition timing which shortens catalyst light-off time. Stratified mixture combustion designs often require complicated piston shapes which disturb the fluid flow in the cylinder, leading to power reduction, especially in turbocharged gasoline direct-injection engines. Our research replaced the conventional shell-type shallow cavity piston with a dog dish-type curved piston that includes a small lip to facilitate stratification and minimize flow disturbance. As a result, stable stratified combustion and increased power were both achieved.
Journal Article

Study of Low-Speed Pre-Ignition in Boosted Spark Ignition Engine

2014-04-01
2014-01-1218
This paper analyzes low-speed pre-ignition (LSPI), a sudden pre-ignition phenomenon that occurs in downsized boosted gasoline engines in low engine speed high-load operation regions. This research visualized the in-cylinder state before the start of LSPI combustion and observed the behavior of particles, which are thought to be the ignition source. The research also analyzed pre-ignition by injecting deposit flakes and other combustible particulate substances into the combustion chamber. The analysis found that these particles require at least two combustion cycles to reach a glowing state that forms an ignition source. As a result, deposits peeling from combustion chamber walls were identified as a new mechanism causing pre-ignition. Additionally, results also suggested that the well-known phenomenon in which the LSPI frequency rises in accordance with greater oil dilution may also be explained by an increase in deposit generation.
Journal Article

Onboard Gasoline Separation for Improved Vehicle Efficiency

2014-04-01
2014-01-1200
ExxonMobil, Corning and Toyota have collaborated on an Onboard Separation System (OBS) to improve gasoline engine efficiency and performance. OBS is a membrane based process that separates gasoline into higher and lower octane fractions, allowing optimal use of fuel components based on engine requirements. The novel polymer-ceramic composite monolith membrane has been demonstrated to be stable to E10 gasoline, while typically providing 20% yield of ∼100 RON product when using RUL 92 RON gasoline. The OBS system makes use of wasted exhaust energy to effect the fuel separation and provides a simple and reliable means for managing the separated fuels that has been demonstrated using several generations of dual fuel test vehicles. Potential applications include downsizing to increase fuel economy by ∼10% while maintaining performance, and with turbocharging to improve knock resistance.
Technical Paper

A Solid Particle Number Measurement System Including Nanoparticles Smaller than 23 Nanometers

2014-04-01
2014-01-1604
The particle number (PN) emission regulation has been implemented since 2011 in Europe. PN measurement procedure defined in ECE regulation No. 83 requires detecting only solid particles by eliminating volatile particles, the concentrations of which are highly influenced by dilution conditions, using a volatile particle remover (VPR). To measure PN concentration after the VPR, a particle number counter (PNC) which has detection threshold at a particle size of 23 nm is used, because most solid particles generated by automotive engines are considered to be larger than 23 nm. On the other hand, several studies have reported the existence of solid and volatile particles smaller than 23 nm in engine exhaust. This paper describes investigation into a measurement method for ultrafine PNCs with thresholds of below 23 nm and evaluation of the VPR performance for the particles in this size range. The detection efficiency of an ultrafine PNC was verified by following the ECE regulation procedure.
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