Search Results

The growing demand for transportation fuels and the global emphasis on reducing greenhouse gas (GHG) emissions have led to increased interest in analyzing transport GHG emissions from the life-cycle perspective. Methanol, a potentially carbon-neutral fuel synthesized from CO2 and H2, has emerged as a promising candidate. This paper conducts a comprehensive life-cycle analysis (LCA) of the GHG emissions associated with the methanol production process, utilizing data inventory from China in 2019. To simulate the synthesis and distillation process of methanol, Aspen Plus is employed, using parameters obtained from actual plants. GHG emissions are then calculated using the GREET model, incorporating updated industry statistics and research findings. The CO2 necessary for methanol production is captured from factory flue gas.

Despite the legislation targets set by several governments of a full electrification of new light-duty vehicle fleets by 2035, the development of innovative, environmental-friendly Internal Combustion Engines (ICEs) is still crucial to be on track toward the complete decarbonization of on road-mobility of the future. In such a framework, the PHOENICE (PHev towards zerO EmissioNs & ultimate ICE efficiency) project aims at developing a C SUV-class plug-in hybrid (P0/P4) vehicle demonstrator capable to achieve a -10% fuel consumption reduction with respect to current EU6 vehicle while complying with upcoming EU7 pollutant emissions limits. Such ambitious targets will require the optimization of the whole engine system, exploiting the possible synergies among the combustion, the aftertreatment and the exhaust waste heat recovery systems.

Ethanol fuel blends with gasoline for spark ignition (SI) internal combustion engines are widely used on account of their advantages in terms of fuel economy and emissions reduction potential. The focus of this paper is to study the effects of these blends on combustion characteristics such as in-cylinder pressure profiles, gas-phase emissions (e.g., unburned hydrocarbons, NOx) and particulates (e.g., particulate matter and particle number) using both measurement campaigns and digital engineering workflows. Nineteen load-speed operating points in a 1L 3-cylinder GDI SI engine were measured and modelled. The measurements for in-cylinder pressure and emissions were repeated at each operating point for three types of fuel: gasoline (E0, 0% by volume of ethanol blend), E10 (10 % by volume of ethanol blend) and E20 (20% by volume of ethanol blend).

A heavy-duty diesel engine (ETH-LAV single cylinder MTU396 heavy duty research engine) was simulated by RANS and advanced reacting flow models to gain insight into its soot and NOx emissions. Due to symmetry, a section of the engine containing a single injector-hole was simulated. Dodecane was used as a surrogate to emulate the evaporation properties of diesel and a 22-step reaction mechanism for n-heptane was used to describe combustion. The Conditional Moment Closure (CMC) method was used as the combustion model in two ways. In a more conventional modelling approach, CMC was fully interfaced with the CFD and a two-equation model was employed for determining soot while the extended Zeldovich mechanism was used for NOx. In a second approach called the Imperfectly Stirred Reactor (ISR) method, the CMC equation was integrated over space and the previous RANS-CMC solution was further analysed in a post-processing step with the focus on soot.

This paper investigates the energy efficiency and emissions benefits possible with connected and autonomous vehicles (CAVs). Such benefits could be instrumental in decarbonising the transport sector. The impact of CAV technology on operation, usage and specification of vehicles for optimised energy efficiency is considered. Energy consumption reductions of 55% – 66% are identified for a fully autonomous road transport system versus the present. 46% is possible for a CAV on today’s roads. Smoothing effects and reduced stoppage in the drive cycle achieve a 31% reduction in travel time if speed limits are not reduced. CAV powertrain optimised for different scenarios requires just 10 kW – 40 kW maximum power whilst the vehicle mass is reduced by up to 40% relative to current cars. Urban-optimised powertrain, with only 10 kW – 15 kW maximum power, allows energy consumption reductions of over 71%.

Future emissions regulations proposed for the Asian automotive industry (BS VI regulations for India and NS VI regulations for China) are strict and similar to EU VI regulations. As a result, they will require both advanced NOx control as well as advanced Particulate Matter (PM) control. This will drive implementation of full Catalyzed Diesel Particulate Filter (cDPF) and simultaneous NOx control using Selective Catalytic Reduction (SCR) technologies. In this work, we present the performance of various Diesel Oxidation Catalyst (DOC), cDPF, SCR and Ammonia slip catalyst (ASC) systems utilizing the World Harmonized Transient Cycle (WHTC). Aftertreatment Systems (ATS) required for both active and passive filter regeneration applications will be discussed. The sensitivity of key design parameters like catalyst technology, PGM loading, catalyst sizing to meet the regulation limits has been investigated.

The next generation advanced emission regulations have been proposed for the Indian heavy duty automotive industry for implementation from 2020. These BS VI emission regulations will require both advanced NOx control as well as advanced PM (Particulate Matter) control along with Particle Number limitations. This will require implementation of full DPF (Diesel Particulate Filter) and simultaneous NOx control using SCR technologies. DPF technologies have already been successfully implemented in Euro VI and US 10 HDD systems. These systems use low temperature NO2 based passive DPF regeneration as well as high temperature oxygen based active DPF regeneration. Effective DPF and DOC designs are essential to enable successful DPF regeneration (minimize soot loading in the DPF) while operating HDD vehicles under transient conditions. DOC designs are optimized to oxidize engine out NO into NO2, which helps with passive DPF regeneration.

The underbody of a truck is responsible for an appreciable portion of the vehicle’s aerodynamic drag, and thus its fuel consumption. This paper investigates experimentally the flow around side-skirts, a common underbody aerodynamic device which is known to be effective at reducing vehicle drag. A full, 1/10 scale European truck model is used. The chassis of the model is designed to represent one that would be found on a typical trailer, and is fully reconfigurable. Testing is carried out in a water towing tank, which allows the correct establishment of the ground flow and rotating wheels. Optical access into the underbody is possible through the clear working section of the facility. Stereoscopic and planar Particle Image Velocimetry (PIV) set-ups are used to provide both qualitative images of and quantitative information on the flow field.

Gasoline direct injection (GDI) engines have become very attractive in transportation due to several benefits over preceding engine technologies. However, GDI engines are associated with higher levels of particulate matter (PM) emissions, which is a major concern for human health. The aim of this work is to broaden the understanding of the effect of hydrogen combustion and the influence of the three way catalytic converter (TWC) on PM emission characteristics. The presence of hydrogen in GDI engines has been reported to reduce fuel consumption and improve the combustion process, making it possible to induce higher rates of EGR. A prototype exhaust fuel reformer build for on-board vehicle hydrogen-rich gas (reformate) production has been integrated within the engine operation and studied in this work.

In recent years magnetic resonance imaging (MRI) has been shown to be an attractive method for fluid flow visualization. In this work, we show how MRI velocimetry techniques can be used to non-invasively investigate and visualize the hydrodynamics of exhaust gas in a diesel particulate filter (DPF), both when clean and after loading with diesel engine exhaust particulate matter. The measurements have been used to directly measure the gas flow in the inlet and outlet channels of the DPF, both axial profiles along the length and profiles across the channel diameter. Further, from this information we show that it is possible to indirectly ascertain the superficial wall-flow gas velocity and the soot loading profiles along the filter channel length.

Microreactor, engine bench tests and modelling studies have been carried out to understand the influence of cold start (low temperatures) on the performance of NH3/urea-SCR automotive exhaust aftertreatment systems. Water storage experiments using Simultaneous Thermal Analysis (STA) coupled with numerical modelling demonstrated that the exo/endo-therms associated with water adsorption and desorption at temperatures below 150°C strongly influence the catalyst temperature. Appreciable amounts of NO and NO2 could be stored on the catalyst during reactor or engine testing in the absence of any NH3 (blank tests). Modelling studies at different inlet NO2/NOx ratios demonstrated some of the influences of these surface adsorbed species on the performance of the SCR system during cold start.

Wide Distillation Fuel (WDF) refers to the fuels with a distillation range from Initial Boiling Point (IBP) of gasoline to Final Boiling Point (FBP) of diesel. Polyoxymethylene Dimethyl Ethers (PODEn) have high oxygen content and cetane number, are promising green additive to diesel fuel. In this paper, WDF was prepared by blending diesel and gasoline at ratio of 1:1, by volume; the mass distribution of oligomers in the PODE3-4 product was 88.9% of PODE3 and 8.46% of PODE4. Diesel fuel (Diesel), WDF (G50D50) and WDF (80%)-PODE3-4 (20%) (G40D40P20) were tested in a light-duty single-cylinder diesel engine, combustion characteristic, fuel consumption and exhaust emissions were measured. The results showed that: at idling condition, G40D40P20 has better combustion stability, higher heat release rate, higher thermal efficiency compared with G50D50.

A study of Multiple Premixed Compression Ignition (MPCI) with mixtures of gasoline and diesel is performed on a light-duty single cylinder diesel engine. The engine is operated at a speed of 1600rpm with the same fuel mass per cycle. By keeping the same intake pressure and EGR ratio, the influence of different blending ratios in gasoline and diesel mixtures (90vol%, 80vol% and 70vol% gasoline) is investigated. Combustion and emission characteristics are compared by sweeping the first (−95 ∼ −35deg ATDC) and the second injection timing (−1 ∼ 9deg ATDC) with an injection split ratio of 80/20 and an injection pressure of 80MPa. The results show that compared with diesel combustion, the gasoline and diesel mixtures can reduce NOx and soot emissions simultaneously while maintaining or achieving even higher indicated thermal efficiency, but the HC and CO emissions are high for the mixtures.

Experimental research were carried out on a compression ignition engine with compression ratio of 17.5 with direct-run Naphtha. Exhaust recirculation ratio sweeps were carried out with three injection strategies. Premixed charge compression ignition, partially premixed combustion and low temperature combustion modes were realized and compared with each other. The first injection strategy is single injection. The injection timing is scanned to form partially premixed combustion and low temperature combustion. The second injection strategy features a large early first injection with fixed timing to form premixed charge and a small second injection near top dead center, which was scanned. The third injection strategy is similar to the traditional diesel injection strategy, which has a small pilot injection with fixed interval before the main injection. Results show that all injection strategies could realize both low NOx and low particulate matter emissions simultaneously.

This paper will review several different emission control systems for heavy duty diesel (HDD) applications aimed at future legislations. The focus will be on the (DOC+CSF+SCR+ASC) configuration. As of today, various SCR technologies are used on commercial vehicles around the globe. Moving beyond EuroVI/US10 emission levels, both fuel consumption savings and higher catalyst system efficiency are required. Therefore, significant system optimization has to be considered. Examples of this include: catalyst development, optimized thermal management, advanced urea dosing calibrations, and optimized SCR inlet NO:NO2 ratios. The aim of this paper is to provide a thorough system screening using a range of advanced SCR technologies, where the pros and cons from a system perspective will be discussed. Further optimization of selected systems will also be reviewed. The results suggest that current legislation requirements can be met for all SCR catalysts under investigation.

A combined experimental and modeling study was carried out to investigate the effects of Pt:Pd ratio on the performance of diesel oxidation catalysts (DOC) for heavy-duty applications1 (PGM<50 g/ft3). In the first part of this work, transient light-off and steady-state experiments were performed over a series of hydrothermally aged DOCs with different Pt:Pd ratios and PGM loadings. It was found that n-decane and NO oxidation activities increased monotonically as the Pt:Pd ratio was increased while the oxidation of unsaturated hydrocarbons (HC) (C3H6 and C7H8) first increased with an increase in Pt:Pd ratio and then plateaued at higher Pt content. In contrast, the CO oxidation exhibited opposite trend, with the catalyst containing low Pt (high Pd) level being more active. The presence of HC lowered the outlet NO2/NOx ratio by reducing the NO2 generated via NO oxidation back to NO. The negative effect of HCs on NO2/NOx ratio increased in the order: C3H6

This paper presents a two-part study on the effect of Pt:Pd ratio (at a constant total Pt+Pd loading of 120 g ft−3) on the catalytic performance of a Diesel Oxidation Catalyst (DOC) intended for light-duty applications, covering ratios across the full range from 100% Pd to 100% Pt. (Work on a heavy-duty DOC is presented in SAE 2015-01-1052). The first part of this paper presents a reactor study on the effect of Pt:Pd ratio on the catalytic activity of key reactions occurring individually over the DOC, including the oxidation of CO, C3H6, n-C10H22, CH4 and NO. For some reactions, activity increases continuously with Pt content (oxidation of n-C10H22 and NO); in contrast the activity for CH4 oxidation increases with decreasing Pt content (increasing Pd content), while CO and C3H6 oxidation exhibit more complicated dependencies. The second part presents the development of a one-dimensional model capable of predicting the effect of Pt:Pd ratio on DOC performance.

On page 1103, the published paper omitted important text before and after figure 6.

Parameter tuning was performed against data from a full scale engine rig with a Diesel Oxidation Catalysts (DOC). Several different catalyst configurations were used with varying Pt loading, washcoat thickness and volume. To illustrate the interplay between kinetics and mass transport, engine operating points were chosen with a wide variation in variables (inlet conditions) and both transient and stationary operation was used. A catalyst model was developed where the catalyst washcoat was discretized as tanks in series both radially and axially. Three different model configurations were used for parameter tuning, evaluating three different approaches to modeling of internal transport resistance. It was concluded that for a catalyst model with internal transport resistance the best fit could be achieved if some parameters affecting the internal mass transport were tuned in addition to the kinetic parameters.

Selective Catalytic Reduction (SCR) catalysts have been demonstrated as an effective solution for controlling NOx emissions from diesel engines. There is a drive to reduce the overall packaging volume of the aftertreatment system for these applications. In addition, more active SCR catalysts will be needed as the applications become more challenging: e.g. lower temperatures and higher engine out NOx, for fuel consumption improvements. One approach to meet the challenges of reduced volume and/or higher NOx reduction is to increase the active site density of the SCR catalyst by coating higher amount of SCR catalyst on high porosity substrates (HPS). This approach could enable the reduction of the overall packaging volume while maintaining similar NOx conversion as compared to 2010/2013 systems, or improve the NOx reduction performance for equivalent volume and NH3 slip.