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Ammonia has received attention as an alternative hydrogen carrier and a potential fuel for thermal propulsion systems with a lower carbon footprint. One strategy for high power density in ammonia applications will be direct injection of liquid ammonia. Understanding the evaporation and mixing processes associated with this is important for model development. Additionally, as a prior step for developing new injectors, it is of interest to understand how a conventional gasoline direct injection (GDI) injector would behave when used for liquid ammonia without any modifications. Pure anhydrous ammonia, in its liquid form, was injected from a single hole GDI injector at a fuel pressure of 150 bar into an optically accessible constant volume chamber filled with nitrogen gas for ammonia spray measurements. The chamber conditions spanned a wide range of pressures from 3 − 15 bar at an increment of 1 bar or 2 bar between the test points.

Forthcoming worldwide emissions regulations will start regulating ammonia emissions from light duty vehicles. At present, most light duty vehicles are powered by gasoline spark ignition engines. Sources of ammonia emission from such engines can be in-cylinder reactions (i.e. combustion) or downstream reactions across aftertreatment devices, particularly three-way catalysts. The latter has been known to be a major source of ammonia emissions from gasoline vehicles and has been extensively investigated. The former (combustion), less so, and thus is the subject of this work. A two-zone thermodynamic spark ignition engine model with a comprehensive chemical kinetics framework (C3MechV3.3 mechanism), after being validated against experimental ammonia emissions data, is used to study ammonia formation during combustion.

Particulate emissions from gasoline direct injection (GDI) engines continue to be a topic of substantial research interest. Forthcoming regulation both in the USA and the EU will further reduce their emission and drive innovation. Substantial research effort is spent undertaking experiments to understand, characterize, and research particle number (PN) emissions from engines and vehicles. Recent advances in computing power, data storage, and understanding of artificial intelligence algorithms now mean that these are becoming an important tool in engine research. In this work a random forest (RF) algorithm is used for the prediction of PN emissions from a highly boosted (up to 32 bar BMEP) GDI engine. Particle size, concentration, and the accumulation mode geometric standard deviation (GSD) are all predicted by the model. The results are analysed and an in depth study on parameter importance is carried out.

Accurate modelling for spray vapour fields is critical to enable adequate predictions of spray ignition and combustion characteristics of non-premixed reacting diesel sprays. Spray vapour characteristics are in turn controlled by liquid atomization and the KH-RT liquid jet break-up model is regularly used to predict this: with the KH model used for predicting primary break-up given its definition as a surface wave growth model, and the RT model used for predicting secondary break-up due to it being a drag based, stripping model. This paper investigates how the alteration of the switching position of the KH and RT sub-models within the KH-RT model impacts the resulting vapour field and ignition characteristics. The combustion prediction is handled by the implementation of a 54 species, 269 reaction skeletal mechanism utilising a Well Stirred Reactor model within the Star-CD CFD code.

The flows in-cylinder have a profound effect on the mixture preparation and subsequent combustion in all engines. These flows are highly three-dimensional in nature and information from multiple planes is required to characterise the flow dynamics. The flow measurements reported here are from three orthogonal planes in an optical access engine that is based on the Jaguar Land Rover AJ200 Gasoline Direct Injection (GDI) engine. Particle Image Velocimetry (PIV) measurements have been taken every 5°CA from the start of induction to the end of compression. Data have been obtained from 300 cycles for separate experiments measuring flows in the tumble plane, the swirl plane and the cross-tumble plane. Vector comparison metrics are used to quantitatively compare ensemble averaged PIV flow fields to Computational Fluid Dynamics (CFD) simulations across each plane in terms of both the velocity magnitude and direction.

This study looked into the application of active thermal coatings on the surfaces of the combustion chamber as a method of improving the thermal efficiency of internal combustion engines. The active thermal coating was applied to a production aluminium piston and its performance was compared against a reference aluminium piston on a single-cylinder diesel engine. The two pistons were tested over a wide range of speed/load conditions and the effects of EGR and combustion phasing on engine performance and tailpipe emissions were also investigated. A detailed energy balance approach was employed to study the thermal behaviour of the active thermal coating. In general, improvements in indicated specific fuel consumption were not statistically significant for the coated piston over the whole test matrix. Mean exhaust temperature showed a marginal increase with the coated piston of up to 6 °C.

The European Particle Measurement Program (PMP) defines the current standard for measurement of Particle Number (PN) emissions from vehicles in Europe. This specifies a 50% count efficiency (D50) at 23 nm and a 90% count efficiency (D90) at 41 nm. Particulate emissions from Gasoline Direct Injection (GDI) engines have been widely studied, but usually only in the context of PMP or similar sampling procedures. There is increasing interest in the smallest particles - i.e. smaller than 23 nm - which can be emitted from vehicles. The literature suggest that by moving D50 to 10 nm, PN emissions from GDI engines might increase by between 35 and 50% but there remains a lot of uncertainty.

Chromium-molybdenum alloy steel pistons, which have been used in commercial vehicle applications for some time, have more recently been proposed as a means of improving thermal efficiency in light-duty applications. This work reports a comparison of the effects of geometrically similar aluminium and steel pistons on the combustion characteristics and energy flows on a single cylinder high-speed direct injection diesel research engine tested at two speed / load conditions (1500 rpm / 6.9 bar nIMEP and 2000 rpm/25.8 bar nIMEP) both with and without EGR. The results indicate that changing to an alloy steel piston can provide a significant benefit in brake thermal efficiency at part-load and a reduced (but non-negligible) benefit at the high-load condition and also a reduction in fuel consumption. These benefits were attributed primarily to a reduction in friction losses.

In-cylinder temperatures and their cyclic variations strongly influence many aspects of internal combustion engine operation, from chemical reaction rates determining the production of NOx and particulate matter to the tendency for auto-ignition leading to knock in spark ignition engines. Spatially resolved measurements of temperature can provide insights into such processes and enable validation of Computational Fluid Dynamics simulations used to model engine performance and guide engine design. This work uses a combination of Two-Colour Planar Laser Induced Fluorescence (TC-PLIF) and Laser Induced Grating Spectroscopy (LIGS) to measure the in-cylinder temperature distributions of a firing optically accessible spark ignition engine. TC-PLIF performs 2-D temperature measurements using fluorescence emission in two different wavelength bands but requires calibration under conditions of known temperature, pressure and composition.

Knowledge of fuel mass injected in an individual cycle is important for engine performance and modelling. Currently direct measurements of fuel flow to individual cylinders of an engine are not possible on-engine or in real-time due to a lack of available appropriate measurement techniques. The objective of this work was to undertake real-time Coriolis fuel flow measurement using GDI injectors on a rig observing fuel mass flow rate within individual fuel injections. This paper evaluates the potential of this technology - combining Coriolis Flow Meters (CFMs) with Prism signal processing together known as Fast Next Generation Coriolis (Fast NGC), and serves as a basis for future transitions on-engine applications. A rig-based feasibility study has been undertaken injecting gasoline through a GDI injector at 150 bar in both single shot mode and at a simulated engine speeds of 1788 and 2978 rpm. The results show that these injections can, in principle, be observed.

Knowledge of fuel mass injected in an individual cycle is important for engine performance and modeling. At the moment, such measurements are not possible on engine or in real time. In this article, a new method using Coriolis flow meters (CFMs) and a new, patented, signal processing technique, known as the Prism, are introduced. CFMs are extensively used for flow measurement both in the automotive industry and further afield and, when coupled with the Prism, have the potential to make these challenging high-speed measurements. A rig-based feasibility study was conducted injecting very small quantities of diesel (3 mg) at pressures of up to 1000 bar at simulated engine speeds of up to 4000 rpm. The results show that these small quantities can in principle be measured. The results also reveal a previously unknown behavior of CFMs when measuring very low flow rates at high speed.

A new reflected shock tube facility, the Cold Driven Shock Tube (CDST), has been designed, built and commissioned at the University of Oxford for investigating IC engine fuel spray physics and chemistry. Fuel spray and chemical kinetics research requires its test gas to be at engine representative pressures and temperatures. A reflected shock tube generates these extreme conditions in the test gas for short durations (order milliseconds) by transiently compressing it through a reflected shock process. The CDST has been designed for a nominal test condition of 6 MPa, 900 K slug of air (300 mm long) for a steady test duration of 3 ms. The facility is capable of studying reacting mixtures at higher pressures (up to 150 bar) than other current facilities, whilst still having comparable size (100 mm diameter) and optical access to interrogate the fuel spray with high speed imaging and laser diagnostics.

Diesel engine designers often use swirl flaps to increase air motion in cylinder at low engine speeds, where lower piston velocities reduce natural in-cylinder swirl. Such in-cylinder motion reduces smoke and CO emissions by improved fuel-air mixing. However, swirl flaps, acting like a throttle on a gasoline engine, create an additional pressure drop in the inlet manifold and thereby increase pumping work and fuel consumption. In addition, by increasing the fuel-air mixing in cylinder the combustion duration is shortened and the combustion temperature is increased; this has the effect of increasing NOx emissions. Typically, EGR rates are correspondingly increased to mitigate this effect. Late inlet valve closure, which reduces an engine’s effective compression ratio, has been shown to provide an alternative method of reducing NOx emissions.

The increased efficiency and specific output with Gasoline Direct Injection (GDI) engines are well known, but so too are the higher levels of Particulate Matter emissions compared with Port Fuel Injection (PFI) engines. To minimise Particulate Matter emissions, then it is necessary to understand and control the mixture preparation process, and important insights into GDI engine mixture preparation and combustion can be obtained from optical access engines. Such data is also crucial for validating models that predict flows, sprays and air fuel ratio distributions. The purpose of this paper is to review a number of optical techniques; the interpretation of the results is engine specific so will not be covered here. Mie scattering can be used for semi-quantitative measurements of the fuel spray and this can be followed with Planar Laser Induced Fluorescence (PLIF) for determining the air fuel ratio and temperature distributions.

Modern diesel cars, fitted with state-of-the-art aftertreatment systems, have the capability to emit extremely low levels of pollutant species at the tailpipe. However, diesel aftertreatment systems can represent a significant cost, packaging and maintenance requirement. Reducing engine-out emissions in order to reduce the scale of the aftertreatment system is therefore a high priority research topic. Engine-out emissions from diesel engines are, to a significant degree, dependent on the detail of fuel/air interactions that occur in-cylinder, both during the injection and combustion events and also due to the induced air motion in and around the bowl prior to injection. In this paper the effect of two different piston bowl shapes are investigated.

Engine optimization requires a good understanding of the in-cylinder heat transfer since it affects the power output, engine efficiency and emissions of the engine. However little is known about the convective heat transfer inside the combustion chamber due to its complexity. To aid the understanding of the heat transfer phenomena in a Spark Ignition (SI) engine, accurate measurements of the local instantaneous heat flux are wanted. An improved understanding will lead to better heat transfer modelling, which will improve the accuracy of current simulation software. In this research, prototype thin film gauge (TFG) heat flux sensors are used to capture the transient in-cylinder heat flux within a Cooperative Fuel Research (CFR) engine. A two-zone temperature model is linked with the heat flux data. This allows the distinction between the convection coefficient in the unburned and burned zone.

Model M15 gasoline fuels have been created from pure fuel components, to give independent control of volatility, the heavy end content and the aromatic content, in order to understand the effect of the fuel properties on Gasoline Direct Injection (GDI) fuel spray behaviour and the subsequent particulate number emissions. Each fuel was imaged at a range of fuel temperatures in a spray rig and in a motored optical engine, to cover the full range from non-flashing sprays through to flare flashing sprays. The spray axial penetration (and potential piston and liner impingement), and spray evaporation rate were extracted from the images. Firing engine tests with the fuels with the same fuel temperatures were performed and exhaust particulate number spectra captured using a DMS500 Mark II Particle Spectrometer.

To optimize internal combustion engines (ICEs), a good understanding of engine operation is essential. The heat transfer from the working gases to the combustion chamber walls plays an important role, not only for the performance, but also for the emissions of the engine. Besides, thermal management of ICEs is becoming more and more important as an additional tool for optimizing efficiency and emission aftertreatment. In contrast little is known about the convective heat transfer inside the combustion chamber due to the complexity of the working processes. Heat transfer measurements inside the combustion chamber pose a challenge in instrumentation due to the harsh environment. Additionally, the heat loss in a spark ignition (SI) engine shows a high temporal and spatial variation. This poses certain requirements on the heat flux sensor. In this paper we examine the heat transfer in a production SI ICE through the use of Thin Film Gauge (TFG) heat flux sensors.

Knocking combustion places a major limit on the performance and efficiency of spark ignition engines. Spontaneous ignition of the unburned air-fuel mixture ahead of the flame front leads to a rapid release of energy, which produces pressure waves that cause the engine structure to vibrate at its natural frequencies and produce an audible ‘pinging’ sound. In extreme cases of knock, increased temperatures and pressures in the cylinder can cause severe engine damage. Damage is thought to be caused by thermal strain effects that are directly related to the heat flux. Since it will be the maximum values that are potentially the most damaging, then the heat flux needs to be measured on a cycle-by-cycle basis. Previous work has correlated heat flux with the pressure fluctuations on an average basis, but the work here shows a correlation on a cycle-by-cycle basis. The in-cylinder pressure and surface temperature were measured using a pressure transducer and eroding-type thermocouple.

A model for the evaporation of a multi-component fuel droplet is presented that takes account of temperature dependent fuel and vapour properties, evolving droplet internal temperature distribution and composition, and enhancement to heat and mass transfer due to droplet motion. The effect on the internal droplet mixing of non-ideal fluid diffusion is accounted for. Activity coefficients for vapour-liquid equilibrium and diffusion coefficients are determined using the UNIFAC method. Both well-mixed droplet evaporation (assuming infinite liquid mass diffusivity) and liquid diffusion-controlled droplet evaporation (iteratively solving the multi-component diffusion equation) have been considered. Well-mixed droplet evaporation may be applicable with slow evaporation, for example early gasoline direct injection; diffusion-controlled droplet evaporation must be considered when faster evaporation is encountered, for example when injection is later, or when the fuel mixture is non-ideal.