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Even though substantial improvements have been made for the lean NOx trap (LNT) catalyst in recent years, the durability still remains problematic because of the sulfur poisoning and sintering of the precious metals at high operating temperatures. Hence, commercial LNT catalysts were aged and tested in order to investigate their performance and activity degradation compared to the fresh catalyst, and establish a proper correlation between the aging methods used. The target of this study is to provide useful information for regeneration strategies and optimize the catalyst management for better performance and durability. With this goal in mind, two different aging procedures were implemented in this investigation. A catalyst was vehicle-aged in the vehicle chassis dynamometer for 100000 km, thus exposed to real conditions. Whereas, an accelerated aging method was used by subjecting a fresh LNT catalyst at 800 °C for 24 hours in an oven under controlled conditions.

This paper describes the experimental study of a tumble-flap mounted in the intake port of a single-cylinder spark-ignited gasoline engine. The research question addressed was whether an optimal tumble level could be found for the combustion system under investigation. Indicated fuel consumption was measured for a number of part-load operating points with the tumble-flap either open or closed. The experimental results were subjected to an energy balance analysis to understand which portion of the fuel energy was converted to work and how much was lost by incomplete combustion, heat losses to walls and to the exhaust gases, as well as to pumping losses. Closing the tumble-flap resulted in reduced fuel consumption only in a small area of the operating map: only at low-speed, low-load operation, a benefit could be obtained.

Passive selective catalyst reduction (SCR) systems can be used as aftertreatment systems for lean burn spark ignition (SI)-engines. Their operation is based on the interaction between the engine, an ammonia formation catalyst (AFC), and an SCR catalyst. Under rich conditions the AFC forms ammonia, which is stored in the SCR catalyst. Under lean conditions, the SCR catalyst reduces the engine out NOx using the stored NH3. This study compared the ammonia production and response times of a standard three way catalyst (TWC) and a Pd/Al2O3 catalyst under realistic engine operating conditions. In addition, the relationships between selected engine operating parameters and ammonia formation over a TWC were investigated, considering the influence of both the chosen load point and the engine settings.

An experimental study of EGR and turbocharging concepts has been performed on an experimental 2.0-litre 4-cylinder turbocharged Euro6 light-duty diesel engine. The purpose of the study was to investigate the emissions and fuel consumption trade-off for different concept combinations. The impact of low-pressure and high-pressure EGR was studied in terms of engine-out emissions and fuel consumption. Moreover, the influence of single-stage and two-stage turbocharging was investigated in combination with the EGR systems, and how the engine efficiency could be further improved after engine calibration optimization. During low load engine operation where throttling may be required to achieve the desired low-pressure EGR rate, the difference in fuel consumption impact was studied for exhaust throttling and intake throttling, respectively. The cooling impact on high-pressure EGR was compared in terms of emissions and fuel consumption.

Heat loss is one of the greatest energy losses in engines. More than half of the heat is lost to cooling media and exhaust losses, and they thus dominate the internal combustion engine energy balance. Complex processes affect heat loss to the cylinder walls, including gas motion, spray-wall interaction and turbulence levels. The aim of this work was to experimentally compare the heat transfer characteristics of a stepped-bowl piston geometry to a conventional re-entrant diesel bowl studied previously and here used as the baseline geometry. The stepped-bowl geometry features a low surface-to-volume ratio compared to the baseline bowl, which is considered beneficial for low heat losses. Speed, load, injection pressure, swirl level, EGR rate and air/fuel ratio (λ) were varied in a multi-cylinder light duty engine operated in conventional diesel combustion (CDC) mode.

The objective of this study was to investigate which of the artificial aging cycles available in the automotive industry that causes major deactivation of three-way catalysts (TWCs) and can be used to obtain an aged catalyst similar to the road aged converter (160 000km). Standard bench cycle (SBC) aging with secondary air injection (SAI) covered aging with various mass flows - a flow from three cylinders into one catalyst system and a flow from three cylinders into two parallel connected catalysts. For rapid catalyst bench aging, secondary air injection is a very efficient tool to create exotherms. Furthermore, the effect on catalytic activity of SAI aging with poisons from oil and fuel dopants (P, Ca, Zn) was investigated. The catalysts were thoroughly characterized in light-off and oxygen storage capacity measurements, emission conversion as a function of lambda and load variation was determined.

Passenger cars equipped with diesel engines will meet challenging emission legislation for the coming decade, with introduction of Euro6 and Euro7, which comprises reduced NOX emissions and possibly new driving cycles including off-cycle limits. The technology measures to meet these legislative limits comprise a broad spectrum of engine and aftertreatment, i.e., engine measures such as improved fuel injection with respect to mass and timing, improved exhaust gas recirculation, improved warm-up and reduced friction, as well as aftertreatment measures such as selective catalytic reduction and lean NOX trap in combination with diesel particulate filter, and the thereby associated engine control. The resulting technology matrix is therefore large, and calls for a multidisciplinary simulation approach for appropriate selection and optimization of technology and control with the objectives and constraints of emissions, fuel consumption, performance and cost.

The development and implementation of a new structure for data-driven models for NOX and soot emissions is described. The model structure is a linear regression model, where physically relevant input signals are used as regressors, and all the regression parameters are defined as grid-maps in the engine speed/injected fuel domain. The method of using grid-maps in the engine speed/injected fuel domain for all the regression parameters enables the models to be valid for changes in physical parameters that affect the emissions, without having to include these parameters as input signals to the models. This is possible for parameters that are dependent only on the engine speed and the amount of injected fuel. This means that models can handle changes for different parameters in the complete working range of the engine, without having to include all signals that actually effect the emissions into the models.

Direct gasoline injection combined with turbo charging and down sizing is a cost effective concept to meet future requirements for emission reduction as well as increased efficiency for passenger cars. It is well known that turbulence induced by in-cylinder air motion can influence efficiency. In this study, the intake-generated flow field was varied for a direct injected turbo charged concept, with the intent to evaluate if further increase in tumble potentially could lead to higher efficiency compared to the baseline. A single cylinder head with flow separating walls in the intake ports and different restriction plates was used to allow different levels of tumble to be experimentally evaluated in a single cylinder engine. The different levels of tumble were quantified by flow rig experiments.

Recently, catalyzed soot filters (CSF) for passenger vehicles have been introduced into the marketplace to comply with the European environmental requirements and future emission standards. The initial system consisted of one or two diesel oxidation catalysts (DOC) to meet the regulated HC and CO standards along with an under floor CSF to treat the particulate emissions. In order to meet the cold start requirements and to reduce system costs with a CSF only unit, converters are placed closer to the engine to minimize heat losses and more of the DOC functionality is integrated into the filter substrate. This work describes the development of such DOC-integrated CSF systems. One major challenge in the design of such systems is to ensure that there is sufficient catalyst functionality within the wall-flow substrate while maintaining an acceptable exhaust gas backpressure across the filter.

When developing gas exchange and combustion systems at Volvo Car Corporation, CFD (Computational Fluid Dynamics) is today a key tool. Three dimensional CFD is by tradition used to study one single component (e.g. manifolds and ports) at a time. Our experience is that this approach suffers from two main limitations; first that the boundary conditions (both upstream and downstream) are uncertain; and secondly that validation against experimental data is extremely difficult since any measured parameter will depend on the complete engine. Distribution of secondary gases and AFR (Air to Fuel ratio) are typical examples where traditional CFD methods fail. One proposed way to overcome these problems is to use 1D gas exchange models coupled with 3D CFD. The main problem with this approach is however the positioning and treatment of the boundaries between the models. Furthermore, the boundaries themselves will unconditionally cause disturbances in the pressure fields.

Gasoline engine oils contain a variety of additives including phosphorous-based compounds, for maintaining their characteristics. During the life of the vehicle, oil is consumed via piston ring blowby or leakage from valve stem guides. Phosphorous compounds from the consumed oil end up being deposited on the three way conversion catalysts resulting in a degradation of the conversion efficiencies of all three pollutants, hydrocarbons, carbon monoxide and nitrogen oxides. To simulate this deterioration in performance, an accelerated aging cycle has been developed which replicates the effect of the interaction between the phosphorous species and the washcoat components. This paper describes the poison aging protocol and the effect of aging temperature, poison level and duration of aging. In this paper, we will we also discuss some of the catalyst deactivation mechanisms and methods to simulate them using dynamometer-mounted engines.

Sulfur poisoning from engine fuel and lube is one of the most recognizable degradation mechanisms of a NOx adsorber catalyst system for diesel emission reduction. Even with the availability of 15 ppm sulfur diesel fuel, NOx adsorber will be deactivated without an effective sulfur management. Two general pathways are currently being explored for sulfur management: (1) the use of a disposable SOx trap that can be replaced or rejuvenated offline periodically, and (2) the use of diesel fuel injection in the exhaust and high temperature de-sulfation approach to remove the sulfur poisons to recover the NOx trapping efficiency. The major concern of the de-sulfation process is the many prolonged high temperature rich cycles that catalyst will encounter during its useful life. It is shown that NOx adsorber catalyst suffers some loss of its trapping capacity upon high temperature lean-rich exposure.

The application of SCR deNOx aftertreatment was studied on two about 12 liter class heavy-duty diesel engines within a consortium project. Basically, the system consists of a dosage system for aqueous urea injection and a vanadia based SCR catalyst, without an upstream or downstream oxidation catalyst. The urea injection system for a DAF and a Renault V.I. (Véhicules Industriels) diesel engine was calibrated on the engine test bench taking into account dynamic effects of the catalyst. For both engine applications NOx reduction was 81% to 84% over the ESC and 72% over the ETC. CO emission increased up to 27%. PM emission is reduced by 4 to 23% and HC emission is reduced by more than 80%. These results are achieved with standard diesel fuel with about 350 ppm sulfur. The test engines and SCR deNOx systems were built into a DAF FT95 truck and a Renault V.I. Magnum truck.

The emission capability of an exhaust system tuned for improved engine performance from an in-line four-cylinder engine has been investigated. The exhaust system comprises two close-coupled catalysts; each located in separate exhaust streams and has been termed the 4-2 close-coupled catalysts (CCC) -1 system. It has been shown that, given equivalent total catalyst volume, this system configuration results in compromised high exhaust flow rate emissions performance compared with a single catalyst (4-1semi-CCC) system. This emissions performance deficit has been attributed to the effect of engine frequency flow pulsations, which result in relatively high peak space velocities in the 4-2CCC-1 system despite the mean space velocity being consistent. Engine-based AFR Bias Sweep tests suggest that hydrocarbon emissions are most strongly affected by this phenomenon. At lower exhaust flow rates, the difference in performance between the two systems is negligible.

The aim of this paper is to investigate the potential of Lean NOx technology for diesel emission control. In this work, the focus is on the precious metal (low temperature) catalyst. Engelhard optimized the catalyst for cells per square inch (cpsi) and Platinum loading. Effect of various parameters, including, reductant type, catalyst volume, space velocity range and injector locations were investigated both analytically and experimentally at Cummins in search for the optimum system design. Both steady state and transient tests were conducted in this work. The precious metal catalysts have a narrow temperature window, however, with the use of proper reductant and an efficient control strategy (to minimize fuel penalty) cycle conversion efficiencies as high as 40% may be obtained for FTP-75. The analysis tool developed to aid the system design is capable of predicting effects of catalyst temperature, NOx concentration, O2 concentration, space velocity etc. on NOx conversion efficiency.

The integration of advanced emission control technologies including advanced three-way catalysts and advanced, high cell density, ultra-thin wall substrates with advanced gasoline powertrains and advanced engine controls is necessary to achieve near-zero tailpipe emission requirements like California's SULEV or PZEV light-duty certification categories. The first gasoline vehicles meeting these near-zero regulations have been introduced in California in 2001. Advanced three-way catalysts targeted for these near-zero regulations feature layered architectures, thermally stable oxygen storage components, and segregated precious metal impregnation strategies. Engine calibration strategies focused on tight stoichiometric air/fuel control and fast catalyst heat-up immediately after engine start are important enablers to achieve near-zero hydrocarbon and NOx emissions.

Classical approaches to pollution control have been to develop benign, non-polluting processes or to abate emissions at the tailpipe or stack before release to the atmosphere. A new technology called PremAir® Catalyst Systems1 takes a different approach and reduces ambient, ground level ozone directly. This technology takes advantage of the huge volumes of air which are processed daily by both mobile and stationary heat exchange devices. For mobile applications, the new system involves placing a catalytic coating on a vehicle's radiator or air conditioning condenser. For stationary applications, the catalytic coating typically is applied to an insert, which is attached to the air conditioning condenser. In either case, the catalyst converts ozone to oxygen as ozone containing ambient air passes over the coated radiator or condenser surfaces.

A catalyst system, consisting of two different catalyst technologies within a single canister, was developed for MDV2 (Medium-Duty Vehicles, Class 2) to meet ULEV targets. The catalyst volume versus engine displacement is less than 50%. Three approaches taken: substrate study, PM loading study and new catalyst technology development are illustrated here. The most promising system features new catalyst technologies coated on high cell density substrates.

Many studies suggest that lean-NOx SCR proceeds via oxidation of NO to NO2 by oxygen, followed by the reaction of the NO2 with hydrocarbons. On catalysts that are not very effective in catalyzing the equilibration of NO+O2 and NO2, the rate of N2 formation is substantially higher when the input NOx is NO2 instead of NO. The apparent bifunctional mechanism in the SCR of NOx has prompted the use of mechanically mixed catalyst components, in which one component is used to accelerate the oxidation of NO to NO2, and another component catalyzes the reaction between NO2 and the hydrocarbon. Catalysts that previously were regarded as inactive for NOx reduction could therefore become efficient when mixed with an oxidation catalyst. Preconverting NO to NO2 opens the opportunity for a wider range of SCR catalysts and perhaps improves the durability of these catalysts. This paper describes the use of a non-thermal plasma as an efficient means for selective partial oxidation of NO to NO2.