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The U.S. EPA has proposed a Tier 3 rule to lower average NMOG+NOx emissions from new light duty vehicles by approximately 80% from 2017 to 2025. Early in this time period, gasoline-fueled vehicles are expected to use technologies similar to California SULEV-II/PZEV certified models currently in limited production. These late model vehicles feature engine control systems that promote rapid catalyst light-off and are designed for ultra-high catalyst conversion efficiency. To enable the use of advanced catalyst coatings and materials, the EPA is also proposing to limit the sulfur content of gasoline to an annual average of 10 ppm while optionally maintaining the current maximum cap of 80 ppm. Fuel sulfur is known to poison precious metal-based catalysts, and the impact on emissions is well understood for older technology vehicles. However, there is a lack of test data on the sensitivity and reversibility of late model vehicle emissions to sulfur.

On-board emissions measurement for heavy-duty vehicles has taken on greater significance because new standards now address in-use emissions levels in the USA. Emissions compliance must be shown in a “Not-to-exceed” (NTE) zone that excludes engine operation at low power. An over-the-road 1996 Peterbilt tractor was instrumented with the West Virginia University Mobile Emissions Measurement System (MEMS). The researchers determined how often the truck entered the NTE, and the emissions from the vehicle, as it was driven over different routes and at different test weights (20,740 lb, 34,640 lb, 61,520 lb, and 79,700 lb) The MEMS interfaced with the truck ECU, while also measuring exhaust flowrate, and concentrations of carbon dioxide (CO2) and oxides of nitrogen (NOx) in the exhaust. The four test routes that were employed included varying terrain types in order to simulate a wide range of on-road driving conditions. One route (called the Bruceton route) included a sustained hill climb.

Selective NOX Recirculation (SNR) involves three main steps in NOX reduction. The first step adsorbs NOX from the exhaust stream, followed by periodic desorption from the aftertreatment medium. The final step passes the desorbed NOX gas into the intake air stream and feeds into the engine. A percentage of the NOX is expected to be decomposed during the combustion process. The motivation for this research was to clarify the reduction of NOX from large stationary engines. The objective of this paper is to report the NOX decomposition phenomenon during the combustion process from three test engines. The results will be used to develop an optimal system for the conversion of NOX with a NOX adsorbtion system. A 1993 Cummins L10G natural gas engine, a 1992 Detroit Diesel series 60 engine and a 13hp Honda gasoline engine were used in the experiments. Commercially available nitric oxide (NO) was injected into the engine intake to mimic the NOX stream from the desorption process.

Concern over health effects associated with diesel exhaust and debate over the influence of high number counts of particles in diesel exhaust prompted research to develop a methodology for diesel particulate matter (PM) characterization. As part of this program, a tractor truck with an electronically managed diesel engine and a dynamometer were installed in the Old Dominion University (ODU) Langley full-scale wind tunnel. This arrangement permitted repeat measurements of diesel exhaust under realistic and reproducible conditions and permitted examination of the steady exhaust plume at multiple points. Background particle size distribution was characterized using a Scanning Mobility Particle Sizer (SMPS). In addition, a remote sampling system consisting of a SMPS, PM filter arrangement, and carbon dioxide (CO2) analyzer, was attached to a roving gantry allowing for exhaust plume sampling in a three dimensional grid. Raw exhaust CO2 levels and truck performance data were also measured.

Few real-world data exist to describe the contribution of diesel vehicles to the emissions inventory, although it is widely acknowledged that diesel vehicles are a significant contributor to oxides of nitrogen (NOx) and particulate matter (PM) in Southern California. New data were acquired during the Gasoline/Diesel PM Split Study, designed to collect emissions data for source profiling of PM emissions from diesel- and gasoline-powered engines in the South Coast (Los Angeles) Air Basin in 2001. Regulated gases, PM and carbon dioxide (CO2) were measured from 34 diesel vehicles operating in the Southern California area. Two were transit buses, 16 were trucks over 33,000 lbs. in weight, 8 were 14,001 lbs. to 33,000 lbs. in weight and 8 were under 14,001 lbs. in weight. The vehicles were also grouped by model year for recruiting and data analysis.

Blending of 20% biodiesel with petroleum diesel is well known to cause a significant reduction in PM emissions but also can cause NOx emissions to increase by 1 to 3 percent. This study has examined a number of approaches for NOx reduction for 20% biodiesel/petroleum diesel blends (B20). These approaches included blending with a nominally 10% aromatic diesel, zero aromatic Fisher-Tropsch (FT) diesel, and use of fuel additives. Biodiesel produced from soybean oil and from yellow grease was examined. Testing was conducted in at 1991 DDC Series 60 truck engine using the U.S. heavy-duty FTP. Emissions of NOx, PM, CO, and THC are reported. Relative to certification diesel the B20 fuels exhibited 20% lower PM emissions but 3.3 and 1% higher NOx emissions for soy and yellow grease based blends, respectively. The 10% aromatic fuel exhibited 12% lower PM and 6% lower NOx. FT diesel had the lowest emissions with a 33% reduction in PM and 16% lower NOx.

A recently completed program was developed to evaluate ultra-low sulfur diesel fuels and passive diesel particle filters (DPF) in several different truck and bus fleets operating in Southern California. The primary test fuels, ECD and ECD-1, are produced by ARCO, a BP company, and have less than 15 ppm sulfur content. A test fleet comprised of heavy-duty trucks and buses were retrofitted with one of two types of catalyzed diesel particle filters, and operated for one year. As part of this program, a chemical characterization study was performed in the spring of 2001 to compare the exhaust emissions using the test fuels with and without aftertreatment. A detailed speciation of volatile organic hydrocarbons (VOC), polycyclic aromatic hydrocarbons (PAH), nitro-PAH, carbonyls, polychlorodibenzo-p-dioxins (PCDD) and polychlorodibenzo-p-furans (PCDF), inorganic ions, elements, PM10, and PM2.5 in diesel exhaust was performed for a select set of vehicles.

The Fischer-Tropsch (FT) process can be used to synthesize diesel fuels from a variety of energy sources, including coal, natural gas and biomass. Diesel fuels produced from the FT process are essentially sulfur-free, have very low aromatic content, and have excellent ignition characteristics. Because of these favorable attributes, FT diesel fuels may offer environmental benefits over transportation fuels derived from crude oil. Previous tests have shown that FT diesel fuel can be used in unmodified engines and have been shown to lower regulated emissions. Whereas exhaust emissions reductions from these previous studies have been impressive, this paper demonstrates that far greater exhaust emissions reductions are possible if the diesel engine is optimized to exploit the properties of the FT fuels. A Power Stroke 7.3 liter turbocharged diesel engine has been modified for use with FT diesel.

Particulate emission control from diesel engines is one of the major concerns in the urban areas in California. Recently, regulations have been proposed for stringent PM emission requirements from both existing and new diesel engines. As a result, particulate emission control from urban diesel engines using advanced particulate filter technology is being evaluated at several locations in California. Although ceramic based particle filters are well known for high PM reductions, the lack of effective and durable regeneration system has limited their applications. The continuously regenerated diesel particulate filter (CRDPF) technology discussed in this presentation, solves this problem by catalytically oxidizing NO present in the diesel exhaust to NO2 which is utilized to continuously combust the engine soot under the typical diesel engine operating condition.

Emissions from heavy-duty vehicles may be reduced through the introduction of clean diesel formulations, and through the use of catalyzed particulate matter filters that can enjoy increased longevity and performance if ultra-low sulfur diesel is used. Twenty over-the-road tractors with Detroit Diesel Series 60 engines were selected for this study. Five trucks were operated on California (CA) specification diesel (CARB), five were operated on ARCO (now BP Amoco) EC diesel (ECD), five were operated on ARCO ECD with a Johnson-Matthey Continuously Regenerating Technology (CRT) filter and five were operated on ARCO ECD with an Engelhard Diesel Particulate Filter (DPX). The truck emissions were characterized using a transportable chassis dynamometer, full-scale dilution tunnel, research grade gas analyzers and filters for particulate matter (PM) mass collection. Two test schedules, the 5 mile route and the city-suburban (heavy vehicle) route (CSR), were employed.

ARCO has developed diesel fuel called Emission Control Diesel (EC-D) that results in substantially lower exhaust emissions compared to a typical California diesel fuel. EC-D has ultra-low sulfur content, low aromatics, and has a high cetane number. EC-D is produced from typical crude oil using a conventional refining process. Initial engine laboratory tests and vehicle tests indicated that EC-D reduced regulated emissions while maintaining fuel economy, compared to a typical California diesel fuel. Ultra-low sulfur diesel fuels such as EC-D may enable the widespread use of passive catalyzed particulate filters for both new and existing diesel engines. The use of catalyzed particulate filters could allow large reductions of particulate matter emitted from vehicles. A one-year technology validation program is being run to evaluate EC-D and catalyzed particulate filters using diesel vehicles operating in Southern California.

Synthetic diesel fuel can be made from a variety of feedstocks, including coal, natural gas and biomass. Synthetic diesel fuels can have very low sulfur and aromatic content, and excellent autoignition characteristics. Moreover, synthetic diesel fuels may also be economically competitive with California diesel fuel if produced in large volumes. Previous engine laboratory and field tests using a heavy-duty chassis dynamometer indicate that synthetic diesel fuel made using the Fischer-Tropsch (F-T) catalytic conversion process is a promising alternative fuel because it can be used in unmodified diesel engines, and can reduce exhaust emissions substantially. The objective of this study was a preliminary assessment of the emissions from older model transit operated on Mossgas synthetic diesel fuel. The study compared emissions from transit buses operating on Federal no. 2 Diesel fuel, Mossgas synthetic diesel (MGSD), and a 50/50 blend of the two fuels.

Emissions of six 32 passenger transit buses were characterized using one of the West Virginia University (WVU) Transportable Heavy Duty Emissions Testing Laboratories, and the fixed base chassis dynamometer at the Colorado Institute for Fuels and High Altitude Engine Research (CIFER). Three of the buses were powered with 1997 ISB 5.9 liter Cummins diesel engines, and three were powered with the 1997 5.9 liter Cummins natural gas (NG) counterpart. The NG engines were LEV certified. Objectives were to contrast the emissions performance of the diesel and NG units, and to compare results from the two laboratories. Both laboratories found that oxides of nitrogen and particulate matter (PM) emissions were substantially lower for the natural gas buses than for the diesel buses. It was observed that by varying the rapidity of pedal movement during accelerations in the Central Business District cycle (CBD), CO and PM emissions from the diesel buses could be varied by a factor of three or more.

Alternative compression ignition engine fuels are of interest both to reduce emissions and to reduce U.S. petroleum fuel demand. A Malaysian Fischer-Tropsch gas-to-liquid fuel was compared with California #2 diesel by characterizing emissions from over the road Class 8 tractors with Caterpillar 3176 engines, using a chassis dynamometer and full scale dilution tunnel. The 5-Mile route was employed as the test schedule, with a test weight of 42,000 lb. Levels of oxides of nitrogen (NOx) were reduced by an average of 12% and particulate matter (PM) by 25% for the Fischer-Tropsch fuel over the California diesel fuel. Another distillate fuel produced catalytically from Fischer-Tropsch products originally derived from natural gas by Mossgas was also compared with 49-state #2 diesel by characterizing emissions from Detroit Diesel 6V-92 powered transit buses, three of them equipped with catalytic converters and rebuilt engines, and three without.

The effects of fuel composition on emissions levels from compression ignition engines can be profound, and this understanding has led to mandated reductions in both sulfur and aromatic content of automotive diesel fuels. A Navistar T444E (V8, 7.3 liter) engine was installed on an engine dynamometer and subjected to transient emissions measurement using a variety of fuels, namely federal low sulfur pump diesel; California pump diesel; Malaysian Fischer-Tropsch fuel with very low sulfur and aromatic content; various blends of soy-derived biodiesel; a Fischer-Tropsch fuel with very low sulfur and 10% aromatics; and the same Fischer-Tropsch fuel with 10% isobutanol by volume. The biodiesel blends showed their ability to reduce particulate matter, but at the expense of increasing oxides of nitrogen (NOx), following the simple argument that cetane enhancement led to earlier ignition. However, the Fischer-Tropsch fuels showed their ability to reduce all of the regulated emissions.

Dedicated natural gas engines suffer the disadvantages of limited vehicle range and relatively few refueling stations. A vehicle capable of operating on either gasoline or natural gas allows alternative fuel usage without sacrificing vehicle range and mobility. However, the bi-fuel engine must be made to provide equal performance on both fuels. Although bi-fuel conversions have existed for a number of years, historically natural gas performance is degraded relative to gasoline due to reduced volumetric efficiency and lower power density of CNG. Much of the performance losses associated with CNG can be overcome by increasing the compression ratio. However, in a bi-fuel application, high compression ratios can result in severe engine knock during gasoline operation. Variable intake valve timing, increased exhaust gas recirculation and retarded ignition timing were explored as a means of controlling knock during gasoline operation of a bi-fuel engine.

The Fischer-Tropsch (F-T) catalytic conversion process can be used to synthesize diesel fuels from a variety of feedstocks, including coal, natural gas and biomass. Synthetic diesel fuels can have very low sulfur and aromatic content, and excellent autoignition characteristics. Moreover, Fischer-Tropsch diesel fuels may also be economically competitive with California diesel fuel if produced in large volumes. An overview of Fischer-Tropsch diesel fuel production and engine emissions testing is presented. Previous engine laboratory tests indicate that F-T diesel is a promising alternative fuel because it can be used in unmodified diesel engines, and substantial exhaust emissions reductions can be realized. The authors have performed preliminary tests to assess the real-world performance of F-T diesel fuels in heavy-duty trucks. Seven White-GMC Class 8 trucks equipped with Caterpillar 10.3 liter engines were tested using F-T diesel fuel.

New York City Department of Sanitation has operated natural gas fueled refuse haulers in a pilot study: a major goal of this study was to compare the emissions from these natural gas vehicles with their diesel counterparts. The vehicles were tandem axle trucks with GVW (gross vehicle weight) rating of 69,897 pounds. The primary use of these vehicles was for street collection and transporting the collected refuse to a landfill. West Virginia University Transportable Heavy Duty Emissions Testing Laboratories have been engaged in monitoring the tailpipe emissions from these trucks for seven-years. In the later years of testing the hydrocarbons were speciated for non-methane and methane components. Six of these vehicles employed the older technology (mechanical mixer) Cummins L-10 lean burn natural gas engines.

Heavy duty engine emissions represent a significant portion of the mobile source emissions inventory, especially with respect to oxides of nitrogen (NOx) emissions. West Virginia University (WVU) has developed an extensive database of continuous transient gaseous emission levels from a wide range of heavy duty diesel vehicles in field operation. This database was built using the WVU Transportable Heavy Duty Vehicle Emission Testing Laboratories. Transient driving cycles used to generate the continuous data were the Central Business District cycle (CBD), 5-peak WVU test cycle, WVU 5-mile route, and the New York City Bus cycle (NYCB). This paper discusses continuous emissions data from a transit bus and a tractor truck, each of them powered by a Detroit Diesel 6V-92 engine. Simple correlational models were developed to relate instantaneous emissions to instantaneous power at the drivewheels.

Lean-burn natural gas engines offer attractively low particulate matter emissions and enjoy higher efficiencies than their stoichiometric counterparts. However, even though oxides of nitrogen emissions can be reduced through operation at lambda ratios of greater than 1.3, catalysts cannot reduce the oxides of nitrogen emissions in the oxidizing exhaust environment. Exhaust Gas Recirculation (EGR) offers the potential to reduce engine out oxides of nitrogen emissions by reducing the flame temperature and oxygen partial pressure that encourages their formation during the combustion process. A comparative study involving a change in the nature of primary diluent (air replaced by EGR) in the intake of a Hercules, 3.7 liter, lean-burn natural gas engine has been undertaken in this research. The Hercules engine was equipped with a General Motors electronically controlled EGR valve for low EGR rates, and a slide valve, constructed in house, for high EGR rates.