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Journal Article

Experimental and Numerical Study on the Effect of Nitric Oxide on Autoignition and Knock in a Direct-Injection Spark-Ignition Engine

2022-08-30
2022-01-1005
Nitric Oxide (NO) can significantly influence the autoignition reactivity and this can affect knock limits in conventional stoichiometric SI engines. Previous studies also revealed that the role of NO changes with fuel type. Fuels with high RON (Research Octane Number) and high Octane Sensitivity (S = RON - MON (Motor Octane Number)) exhibited monotonically retarding knock-limited combustion phasing (KL-CA50) with increasing NO. In contrast, for a high-RON, low-S fuel, the addition of NO initially resulted in a strongly retarded KL-CA50 but beyond the certain amount of NO, KL-CA50 advanced again. The current study focuses on same high-RON, low-S Alkylate fuel to better understand the mechanisms responsible for the reversal in the effect of NO on KL-CA50 beyond a certain amount of NO.
Journal Article

Advanced Emission Controls and E-fuels on a Gasoline Car for Zero-Impact Emissions

2022-08-30
2022-01-1014
The electrified internal combustion engine can contribute to further improving air quality and reducing impact on climate change. A previous publication looked into ultra-low initial cold-start emissions with the implementation of a state-of-the-art emission control system on a gasoline vehicle with market E10 gasoline. This paper reports additional investigations on different drop-in sustainable renewable fuels, including e-fuels. The gasoline demonstrator vehicle is equipped with a 48V mild-hybrid powertrain with a 1.5 L direct injection engine. The innovative emission control system consists of an electrically pre-heated catalyst (EHC) and first three-way catalyst (TWC) in close-coupled position, in combination with an underfloor catalysed gasoline particulate filter (cGPF), second TWC and ammonia slip catalyst (ASC). Pollutant emission tests are conducted on a challenging chassis dyno test for cold-start emissions at 23 °C and -10 °C.
Technical Paper

Research of Fuel Components to Enhance Engine Thermal Efficiency Part I: Concepts for Fuel Molecule Candidate

2019-12-19
2019-01-2255
As part of efforts to address climate change and improve energy security, researchers have improved the thermal efficiency of engines by expanding the lean combustion limit. To further expand the lean combustion limit, the authors focused not only on engine technology but the chemical reactivity of various fuel molecules. Furan and anisole were among the fuel molecules selected, based on the idea that promising candidates should enhance the flame propagation speed and have good knocking resistance. Engine testing showed that the lean limit can be expanded by using fuels with the right molecular structures, resulting in higher thermal efficiency.
Journal Article

On the Role of Nitric Oxide for the Knock-Mitigation Effectiveness of EGR in a DISI Engine Operated with Various Gasoline Fuels

2019-12-19
2019-01-2150
The knock-suppression effectiveness of exhaust-gas recirculation (EGR) can vary between implementations that take EGR gases after the three-way catalyst and those that use pre-catalyst EGR gases. A main difference between pre-and post-catalyst EGR gases is the level of trace species like NO, UHC, CO and H2. To quantify the role of NO, this experiment-based study employs NO-seeding in the intake tract for select combinations of fuel types and compression ratios, using simulated post-catalyst EGR gases as the diluent. The four investigated gasoline fuels share a common RON of 98, but vary in octane sensitivity and composition. To enable probing effects of near-zero NO levels, a skip-firing operating strategy is developed whereby the residual gases, which contain trace species like NO, are purged from the combustion chamber. Overall, the effects of NO-seeding on knock are consistent with the differences in knock limits for preand post-catalyst EGR gases.
Journal Article

Using Chemical Kinetics to Understand Effects of Fuel Type and Compression Ratio on Knock-Mitigation Effectiveness of Various EGR Constituents

2019-04-02
2019-01-1140
Exhaust gas recirculation (EGR) can be used to mitigate knock in SI engines. However, experiments have shown that the effectiveness of various EGR constituents to suppress knock varies with fuel type and compression ratio (CR). To understand some of the underlying mechanisms by which fuel composition, octane sensitivity (S), and CR affect the knock-mitigation effectiveness of EGR constituents, the current paper presents results from a chemical-kinetics modeling study. The numerical study was conducted with CHEMKIN, imposing experimentally acquired pressure traces on a closed reactor model. Simulated conditions include combinations of three RON-98 (Research Octane Number) fuels with two octane sensitivities and distinctive compositions, three EGR diluents, and two CRs (12:1 and 10:1). The experimental results point to the important role of thermal stratification in the end-gas to smooth peak heat-release rate (HRR) and prevent acoustic noise.
Technical Paper

Effects of EGR Constituents and Fuel Composition on DISI Engine Knock: An Experimental and Modeling Study

2018-09-10
2018-01-1677
The use of exhaust gas recirculation (EGR) in spark ignition engines has been shown to have a number of beneficial effects under specific operating conditions. These include reducing pumping work under part load conditions, reducing NOx emissions and heat losses by lowering peak combustion temperatures, and by reducing the tendency for engine knock (caused by end-gas autoignition) under certain operating regimes. In this study, the effects of EGR addition on knocking combustion are investigated through a combined experimental and modeling approach. The problem is investigated by considering the effects of individual EGR constituents, such as CO2, N2, and H2O, on knock, both individually and combined, and with and without traces species, such as unburned hydrocarbons and NOx. The effects of engine compression ratio and fuel composition on the effectiveness of knock suppression with EGR addition were also investigated.
Journal Article

Effects of High Boiling Point Fuel Additives on Deposits in a Direct Injection Gasoline Engine

2017-10-08
2017-01-2299
The effects of high boiling point fuel additives on deposits were investigated in a commercial turbocharged direct injection gasoline engine. It is known that high boiling point substances have a negative effect on deposits. The distillation end points of blended fuels containing these additives may be approximately 15°C higher than the base fuel (end point: 175°C). Three additives with boiling points between 190 and 196°C were examined: 4-tert-Butyltoluene (TBT), N-Methyl Aniline (NMA), and 2-Methyl-1,5-pentanediamine (MPD). Aromatics and anilines, which may be added to gasoline to increase its octane number, might have a negative effect on deposits. TBT has a benzene ring. NMA has a benzene ring and an amino group. MPD, which has no benzene ring and two amino groups, was selected for comparison with the former two additives.
Technical Paper

Effect of Octane Number on the Performance of Euro 5 and Euro 6 Gasoline Passenger Cars

2017-03-28
2017-01-0811
Research Octane Number (RON) and Motor Octane Number (MON) are used to describe gasoline combustion which describe antiknock performance under different conditions. Recent literature suggests that MON is less important than RON in modern cars and a relaxation in the MON specification could improve vehicle performance. At the same time, for the same octane number change, increasing RON appears to provide more benefit to engine power and acceleration than reducing MON. Some workers have advocated the use of an octane index (OI) which incorporates both parameters instead of either RON or MON to give an indication of gasoline knock resistance. Previous Concawe work investigated the effect of RON and MON on the power and acceleration performance of two Euro 4 gasoline passenger cars during an especially-designed acceleration test cycle.
Journal Article

Influence of Different Fuel Properties and Gasoline - Ethanol Blends on Low-Speed Pre-Ignition in Turbocharged Direct Injection Spark Ignition Engines

2016-04-05
2016-01-0719
In recent years a new combustion phenomenon called Low-Speed Pre-Ignition (LSPI) occurred, which is the most important limiting factor to exploit further downsizing potential due to the associated peak pressures and thus the huge damage potential. In the past there were already several triggers for pre-ignitions identified, whereat engine oil seems to have an important influence. Other studies have reported that detached oil droplets from the piston crevice volume lead to auto-ignition prior to spark ignition. However, wall wetting and subsequently oil dilution and changes in the oil properties by impinging fuel on the cylinder wall seem to have a significant influence in terms of accumulation and detachment of oil-fuel droplets in the combustion chamber. For this reason, the influence of test fuels with different volatility were investigated in order to verify their influence on wall wetting, detachment and pre-ignition tendency.
Technical Paper

The Effect of Combustion Knock on the Instantaneous Heat Flux in Spark Ignition Engines

2016-04-05
2016-01-0700
Knocking combustion places a major limit on the performance and efficiency of spark ignition engines. Spontaneous ignition of the unburned air-fuel mixture ahead of the flame front leads to a rapid release of energy, which produces pressure waves that cause the engine structure to vibrate at its natural frequencies and produce an audible ‘pinging’ sound. In extreme cases of knock, increased temperatures and pressures in the cylinder can cause severe engine damage. Damage is thought to be caused by thermal strain effects that are directly related to the heat flux. Since it will be the maximum values that are potentially the most damaging, then the heat flux needs to be measured on a cycle-by-cycle basis. Previous work has correlated heat flux with the pressure fluctuations on an average basis, but the work here shows a correlation on a cycle-by-cycle basis. The in-cylinder pressure and surface temperature were measured using a pressure transducer and eroding-type thermocouple.
Technical Paper

Influence of Different Oil Properties on Low-Speed Pre-Ignition in Turbocharged Direct Injection Spark Ignition Engines

2016-04-05
2016-01-0718
In recent years concern has arisen over a new combustion anomaly, which was not commonly associated with naturally aspirated engines. This phenomenon referred to as Low-Speed Pre-Ignition (LSPI), which often leads to potentially damaging peak cylinder pressures, is the most important factor limiting further downsizing and the potential CO2 benefits that it could bring. Previous studies have identified several potential triggers for pre-ignition where engine oil seems to have an important influence. Many studies [1], [2] have reported that detached oil droplets from the piston crevice volume lead to auto-ignition prior to spark ignition. Furthermore, wall wetting and subsequently oil dilution [3] and changes in the oil properties by impinging fuel on the cylinder wall seem to have a significant influence in terms of accumulation and detachment of oil-fuel droplets in the combustion chamber.
Technical Paper

Effect of Octane on the Performance of Two Gasoline Direct Injection Passenger Cars

2015-04-14
2015-01-0767
The performance aspect of gasoline combustion has traditionally been measured using Research Octane Number (RON) and Motor Octane Number (MON) which describe antiknock performance under different conditions. Recent literature suggests that MON is less important than RON in modern cars and a relaxation in the MON specification could improve vehicle performance, while also helping refiners in the production of gasoline. At the same time, for the same octane number change, increasing RON appears to provide more benefit to engine power and acceleration than reducing MON. It has also been suggested that there could be fuel efficiency benefits (on a tank to wheels basis) for specially adapted engines, for example, operating at higher compression ratio, on very high RON (100+). Other workers have advocated the use of an octane index (OI) which incorporates both RON and MON to give an indication of octane quality.
Journal Article

Pre-Ignition of Gasoline-Air Mixture Triggered by a Lubricant Oil Droplet

2014-10-13
2014-01-2627
This paper presents the effects of a lubricant oil droplet on the start of combustion of a fuel-air mixture. Lubricant oil is thought to be a major source of low-speed pre-ignition in highly boosted spark ignition engines. However, the phenomenon has not yet been fully understood because its unpredictability and the complexity of the mixture in the engine cylinder make analysis difficult. In this study, a single oil droplet in a combustion cylinder was considered as a means of simplifying the phenomenon. The conditions under which a single oil droplet ignites earlier than the fuel-air mixture were investigated. Tests were conducted by using a rapid compression expansion machine. A single oil droplet was introduced into the cylinder through an injector developed for this study. The ignition and the flame propagation were observed through an optical window, using a high-speed video camera.
Technical Paper

CO2 Emission Reduction Synergies of Advanced Engine Design and Fuel Octane Number

2014-10-13
2014-01-2610
Engine downsizing is a key approach employed by many vehicle manufacturers to help meet fleet average CO2 emissions targets. With gasoline engines in particular reducing engine swept volume while increasing specific output via technologies such as turbocharging, direct injection (DI) and variable valve timing can significantly reduce frictional and pumping losses in engine operating areas commonly encountered in legislative drive cycles. These engines have increased susceptibility to abnormal combustion phenomena such as knock due to the high brake mean effective pressures which they generate. This ultimately limits fuel efficiency benefits by demanding use of a lower geometric compression ratio and sub-optimal late combustion phasing at the higher specific loads experienced by these engines.
Journal Article

Measuring the Impact of Engine Oils and Fuels on Low-Speed Pre-Ignition in Downsized Engines

2014-04-01
2014-01-1219
One of the limits on the maximum fuel efficiency benefit to be gained from turbocharged, downsized gasoline engines is the occurrence of low speed pre-ignition (LSPI). LSPI may lead to high pressures and extreme knock (megaknock or superknock) which can cause severe engine damage. Though the mechanism leading to megaknock is not completely resolved, LSPI is thought to arise from local auto-ignition of areas in the cylinder which are rich in low ignition delay “contaminants” such as engine oil and/or heavy ends of gasoline. These contaminants are introduced to the combustion chamber at various points in the engine cycle (e.g. entering from the top land crevice during blow-down or washed from the cylinder walls during DI wall impingement). This paper describes a method for testing the propensity of different contaminants to cause a local pre-ignition in a gasoline engine. During one cycle, a small amount of contaminant is injected into one cylinder of a 4 cylinder engine.
Technical Paper

Lubricant Induced Pre-Ignition in an Optical SI Engine

2014-04-01
2014-01-1222
This work was concerned with study of lubricant introduced directly into the combustion chamber and its effect on pre-ignition and combustion in an optically accessed single-cylinder spark ignition engine. The research engine had been designed to incorporate full bore overhead optical access capable of withstanding peak in-cylinder pressures of up to 150bar. An experiment was designed where a fully formulated synthetic lubricant was deliberately introduced through a specially modified direct fuel injector to target the exhaust area of the bore. Optical imaging was performed via natural light emission, with the events recorded at 6000 frames per second. Two port injected fuels were evaluated including a baseline commercial grade gasoline and low octane gasoline/n-heptane blend. The images revealed the location of deflagration sites consistently initiating from the lubricant itself.
Technical Paper

Impact of Lubricant Composition on Low-speed Pre-Ignition

2014-04-01
2014-01-1213
One of the limits on the maximum fuel efficiency benefit to be gained from turbocharged, downsized gasoline engines is the occurrence of pre-ignitions at low engine speed. These pre-ignitions may lead to high pressures and extreme knock (megaknock or superknock) which can cause severe engine damage. Though the mechanism leading to megaknock is not completely resolved, pre-ignitions are thought to arise from local autoignition of areas in the cylinder which are rich in low ignition delay “contaminants” such as engine oil and/or heavy ends of gasoline. These contaminants are introduced to the combustion chamber at various points in the engine cycle (e.g. entering from the top land crevice during blow-down or washed from the cylinder walls during DI wall impingement).
Journal Article

The Performance of a Modern Vehicle on a Variety of Alcohol-Gasoline Fuel Blends

2012-04-16
2012-01-1272
An unmodified, conventionally fuelled, 2009 Class D vehicle with a 2.0L turbocharged gasoline direct injection engine was operated on a range of gasoline, gasoline-ethanol and gasoline-butanol fuel blends over NEDC drive cycles and WOT power curves on a chassis dynamometer. Engine performance, engine management system parameters and vehicle out emissions were recorded to investigate the response of a current state-of-the-art technology vehicle to various alcohol fuel blends. The vehicle fired on all fuels and was capable of adapting its long term fuelling trim to cope with the increased fuel flow demand for alcohol fuels up to E85. Over the NEDC tests, the volumetric fuel consumption was very strongly related to the calorific content of the fuel. CO and NOx emissions were largely unaffected for the mid alcohol blends, but CO emissions decreased and NOx emissions increased significantly for the high alcohol fuels. THC emissions were largely unaffected.
Technical Paper

Effect of Fuel Components on Engine Abnormal Combustion

2012-04-16
2012-01-1276
These days, improving fuel economy is essential from the view point of energy security and global warming. Engine technologies, such as high compression engines and turbocharged engines, have already been introduced into the market. Furthermore new technologies like lean boosted engines are now being developed. However, these engines are susceptible to abnormal combustion like knocking, auto-ignition, and pre-ignition at low or high engine speeds, because these engines are run at higher combustion pressures and temperatures compared to naturally aspirated engines. It is well known that fuels have some affect on combustion characteristics. This paper examines the effects of fuel characteristics on various types of abnormal combustion. The results show that temperature and pressure have a direct impact on abnormal combustion.
Technical Paper

Engine Thermal Control for Improving the Engine Thermal Efficiency and Anti-Knocking Quality

2012-04-16
2012-01-0377
In recent years, improving the engine thermal efficiency is strongly required. To enhance the engine thermal efficiency, it is important to improve the engine anti-knock quality. Technologies for modifying engine cooling have been developed to improve anti-knocking quality of engines. However, excessive improvement of engine cooling leads to an increase in cooling heat loss. Therefore, it is necessary to clarify the effects of the temperature of each part of the engine such as engine head-cylinder, cylinder-liner, and piston on knocking and cooling heat loss. In this paper, computer aided engineering (CAE) is used to predict the effects of each part of the engine on engine knocking and cooling heat loss. Firstly, the amount of heat energy that air-fuel mixture receives from engine cylinder-head, cylinder-liner, and piston is calculated during the intake stroke. The result shows that the cylinder-liner contributes largest heat energy to air-fuel mixture, especially the exhaust side.
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